(3S,6S)-2-(hydroxymethyl)-6-[(3S,6R)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxane-3,4,5-triol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (3S,6S)-2-(hydroxymethyl)-6-[(3S,6R)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxane-3,4,5-triol
• 化学式: C₁₂H₂₂O₁₁
• 分子量: 342.3
• InChiKey: GUBGYTABKSRVRQ-YHPGEDCPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4.7
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  190
• 氢给体数：
  8
• 氢受体数：
  11

文献信息

• Method for synthesizing oligosaccharides and glycosylation
  申请人：Buchholz Klaus

  公开号：US20090076258A1

  公开（公告）日：2009-03-19

  The invention relates to an enzymatic method for synthesizing oligosaccharides, whereby one saccharide group of a sucrose analogue each is transferred onto an acceptor molecule, for example for glycosylating a hydroxyl compound, a saccharide, peptide, or a drug. According to the inventive method, an enzymatic synthesis of β-D-fructofuranosyl-a-D-aldopyranoside is carried out in a first step, and in a second step one of the saccharide groups is enzymatically transferred onto the acceptor molecule.

  该发明涉及一种酶法合成寡糖的方法，其中蔗糖类似物的一个糖基被转移至一个受体分子，例如用于糖基化一个羟基化合物、糖类、肽或药物。根据该创新方法，首先进行β-D-果糖呋喃糖苷-a-D-醛糖苷的酶合成，然后在第二步，将其中一个糖基酶法转移至受体分子。
• HYBRID COMPOUNDS BASED ON POLYOL(S) AND AT LEAST ONE OTHER MOLECULAR ENTITY, POLYMERIC OR NON-POLYMERIC, IN PARTICULAR OF THE POLYORGANOSILOXANE TYPE, PROCESS FOR THE PREPARATION THEREOF, AND APPLICATIONS THEREOF
  申请人：Fleury Etienne

  公开号：US20100048738A1

  公开（公告）日：2010-02-25

  The invention relates to novel hybrid compounds comprising at least one polyon entity (Po)—for example oligomer or polymer—in which at least one of the hydroxyl functions of Po is substituted by at least one entity A that can be of a variable nature, for example polymer (e.g. polyorganosiloxane-POS), hydrocarbonated or mineral. The bond Ro between the entity Po and the entity A is obtained by means of “click chemistry” and corresponds to formula (II.1) or (II.2), Z representing —CH— or —N—. A is an entity selected from the group comprising the various polyols of Po, polyorganosiloxanes (POS), polyalkylene glycols, polyamides, polyesters, polystyrenes, alkyls, alkenyls, alkynyls, aryls, and combinations thereof, in addition to mineral materials such as silica and the combinations thereof. Said hybrid components can be used as emulsifiers, especially for cosmetics.

  该发明涉及一种新型混合化合物，包括至少一个聚合物实体（Po）- 例如寡聚物或聚合物- 其中Po的至少一个羟基功能被至少一个实体A取代，该实体A可以是多种不同性质的，例如聚合物（例如聚有机硅氧烷-POS）、烃化合物或矿物质。实体Po和实体A之间的键Ro是通过“点击化学”获得的，对应于式（II.1）或（II.2），其中Z代表—CH—或—N—。实体A是从包括各种Po的多元醇、聚有机硅氧烷（POS）、聚烷基乙二醇、聚酰胺、聚酯、聚苯乙烯、烷基、烯基、炔基、芳基以及其组合物在内的群体中选择的实体，此外还包括矿物材料，如硅胶及其组合物。这些混合组分可用作乳化剂，尤其适用于化妆品。
• SYNTHETIC CATALYSTS FOR CARBOHYDRATE PROCESSING
  申请人：Iowa State University Research Foundation, Inc.

  公开号：US20220016612A1

  公开（公告）日：2022-01-20

  The disclosure relates to molecularly-imprinted cross-linked micelles that can selectively hydrolyze carbohydrates.

  该披露涉及分子印迹交联微胶束，可以选择性地水解碳水化合物。
• POLYMERE GREFFE COMPRENANT UN SQUELETTE POLYORGANOSILOXANE ET DES MOTIFS GLYCOSIDE
  申请人：RHODIA CHIMIE

  公开号：EP1742988B1

  公开（公告）日：2007-08-29
• HYBRID COMPOUNDS BASED ON SILICONES, AND AT LEAST ONE OTHER MOLECULAR ENTITY, POLYMER OR OTHERWISE, ESPECIALLY OF THE POLYOL TYPE, METHOD FOR THE PREPARATION THEREOF, AND APPLICATIONS OF THE SAME
  申请人：Fleury Etienne

  公开号：US20090253609A1

  公开（公告）日：2009-10-08

  The invention relates to novel hybrid compounds comprising at least one silicone entity (Sil) in which at least one of the silicons of Sil is substituted by at least one unit—Ro-B, B being an entity of a variable nature, for example polymer, hydrocarbonated or mineral, selected from a group comprising polyols (e.g. saccharides), silicones, polyalkylene glycols, polyamides, polyesters, polystyrenes, alkyls, alkenyls, alkynyls or aryls, in addition to mineral materials such as silica and the combinations thereof. The bond Ro between the entity Sil and the entity B is obtained by means of “click chemistry” and corresponds to formula (II.1) or (II.2), Z representing a carbon atom or a nitrogen atom. Said hybrid components can be used as emulsifiers, especially for cosmetics.