5-butoxybicyclo[2.2.1]hept-2-ene | 22094-90-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-butoxybicyclo[2.2.1]hept-2-ene
• 英文别名: 2-Butyloxy-bicyclo<2.2.1>hept-5-en；5-Butoxy-2-norbornene
• CAS: 22094-90-2
• 化学式: C₁₁H₁₈O
• 分子量: 166.263
• InChiKey: BKKJBUGUSRGLHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-butoxybicyclo[2.2.1]hept-2-ene 反应 2.0h， 以92%的产率得到exo-5-butoxybicyclo[2.2.1]hept-2-ene
  参考文献：
  名称：

  Synthesis of 5-butoxybicyclo[2.2.1]heptan-2-yl acrylate and methacrylate

  摘要：

  DOI：

  10.1134/s107042801206022x
• 作为产物：
  描述：

  二聚环戊二烯 、 乙烯基正丁醚 以to form the Diels-Alder product of 5-butoxy-2-norbornene的产率得到5-butoxybicyclo[2.2.1]hept-2-ene
  参考文献：
  名称：

  In mold addition polymerization of norbornene-type monomers using group 10 metal complexes

  摘要：

  本发明揭示了一种用于大量加成聚合或多环烯烃的催化剂系统和工艺，例如诺博烯，甲基诺博烯，乙基诺博烯，丁基诺博烯或己基诺博烯，1,2,3,4,4a,5,8,8a-八氢-1,4:5,8-二甲基萘，5,5'-(1,2-乙二基)双环[2.2.1]庚-2-烯和1,4,4a,4b,5,8,8a,8b-八氢-1,4:5,8-二甲基联苯。该催化剂包括有机镍或有机钯过渡金属前催化剂和活化剂化合物。聚合可以在反应注塑成型工艺中进行，从而产生具有高玻璃化转变温度的热塑性和热固性成型聚合物制品。

  公开号：

  US20030120006A1

文献信息

• Mold addition polymerization of norbornene-type monomers using group 10 metal complexes
  申请人：The B. F. Goodrich Company

  公开号：US06350832B1

  公开（公告）日：2002-02-26

  A catalyst system and a process for the bulk addition polymerization or of polycyclic olefins, such as norbornene, methylnorbornene, ethylnorbornene, butylnorbornene or hexylnorbornene, 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonapthalene, 5,5′-(1,2-ethanediyl)bisbicyclo[2.2.1]hept-2-ene, and 1,4,4a,4b,5,8,8a,8b-octahydro-1,4:5,8-dimethanobiphenylene are disclosed. The catalyst includes an organonickel or organopalladium transition metal procatalyst and an activator compound. Polymerization can be carried out in a reaction injection molding process to yield thermoplastic and thermoset molded polymeric articles possessing high glass transition temperatures.

  本发明公开了一种催化剂体系和一种用于大量加成聚合或多环烯烃的方法，例如诺博烯，甲基诺博烯，乙基诺博烯，丁基诺博烯或己基诺博烯，1,2,3,4,4a,5,8,8a-八氢-1,4:5,8-二甲基萘，5,5′-(1,2-乙二基)双环[2.2.1]庚-2-烯，以及1,4,4a,4b,5,8,8a,8b-八氢-1,4:5,8-二甲基联苯。催化剂包括有机镍或有机钯过渡金属前催化剂和活化剂化合物。聚合可以在反应注塑成型过程中进行，以产生具有高玻璃转移温度的热塑性和热固性模塑聚合物制品。
• Metathesis polymerization of cycloolefins
  申请人：HERCULES INCORPORATED

  公开号：EP0251033A2

  公开（公告）日：1988-01-07

  A polymer prepared by metathesis polymerizing at least one compound represented by the formula wherein m is 0 or 1 and R, and R2 respectively represent hydrogen atom or an alkyl group containing up to three carbon atoms provided that both R1 and R2 are not hydrogen atom at the same time, or a mixture of said compound with at least one other metathesis polymerizable comonomer, a useful molded article, processes for preparing the polymer and the article and a polymerizable composition therefor.

  一种聚合物，由至少一种如下式所代表的化合物通过偏析聚合反应制备而成 其中 m 为 0 或 1，R1 和 R2 分别代表氢原子或最多含有三个碳原子的烷基，但 R1 和 R2 不能同时为氢原子，或上述化合物与至少一种其他可进行元合成聚合的共聚单体的混合物。
• A process and composition for metathesis polymerization of cycloolefins
  申请人：HERCULES INCORPORATED

  公开号：EP0263425A1

  公开（公告）日：1988-04-13

  A process for producing a molded article by introducing a reactive liquid mixture which comprises a cycloalkene containing dicylopentadiene, a norbornene-type monomer containing at least one N-substituted 5-membered cyclic amide group and a metathesis polymerization catalyst system and which has moderated metathesis polymerizability into a mold in which the liquid mixture is metathesis polymerized, and a multi-part polymerizable composition for producing the molded article.

  一种生产模塑制品的工艺，其方法是将一种反应性液体混合物（其中包括含有二戊二烯的环烷烃、含有至少一个 N-取代的 5 元环状酰胺基团的降冰片烯类单体和一种偏聚催化剂体系）和一种具有适度偏聚聚合性的液体混合物引入模具中，在模具中对液体混合物进行偏聚聚合，以及一种用于生产模塑制品的多组分可聚合组合物。
• OPHTHALMIC LENS, CELL OR ORGAN CULTURE SUBSTRATE, CONTAINER FOR BIOLOGICAL MATERIAL AND TRANSPARENT GEL PRODUCED BY POLYMERIZATION OF CYCLIC SILOXANE COMPOUND AND PROCESS FOR PRODUCTION THEREOF
  申请人：Menicon Co., Ltd.

  公开号：EP1902737A1

  公开（公告）日：2008-03-26

  The present invention is to provide an ophthalmic lens, a culture substrate material for cells or organs, a container for living things and a transparent gel wherein wettability and tackiness are excellent and no surface treatment is required. The ophthalmic lens, the culture substrate material for cells and organs and the transparent gel is obtained by polymerizing a cyclic siloxane compound shown by the following formula (A) (wherein Ra or Rb is a hydrogen atom or a monovalent hydrocarbon group which may be substituted by a fluorine atom, and they are same or different with each other, Rc is a C1 to C6 alkyl group or a phenyl group, X is an organic group containing an unsaturated aliphatic bond, and n is an integer of 1 to 10).

  本发明旨在提供一种眼科镜片、细胞或器官培养基质材料、生物容器和透明凝胶，其润湿性和粘性极佳，且无需进行表面处理。眼科透镜、细胞和器官培养基质材料以及透明凝胶是通过聚合下式（A）所示的环状硅氧烷化合物而得到的 (其中 Ra 或 Rb 是氢原子或可被氟原子取代的一价烃基，它们彼此相同或不同，Rc 是 C1 至 C6 烷基或苯基，X 是含有不饱和脂肪族键的有机基团，n 是 1 至 10 的整数）。
• RESIN MATERIAL FOR FORMING UNDERLAYER FILM, RESIST UNDERLAYER FILM, METHOD FOR PRODUCING RESIST UNDERLAYER FILM, AND LAYERED PRODUCT
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3693793A1

  公开（公告）日：2020-08-12

  Provided is a resin material for forming an underlayer film which is used to form a resist underlayer film used in a multi-layer resist process, the resin material including a cyclic olefin polymer (I), in which a temperature at an intersection between a storage modulus (G') curve and a loss modulus (G") curve in a solid viscoelasticity of the resin material for forming an underlayer film which is as measured under conditions of a measurement temperature range of 30°C to 300°C, a heating rate of 3°C/min, and a frequency of 1 Hz in a nitrogen atmosphere in a shear mode using a rheometer is higher than or equal to 40°C and lower than or equal to 200°.

  本发明提供了一种用于形成底层膜的树脂材料，该底层膜可用于形成多层光刻胶工艺中使用的光刻胶底层膜，该树脂材料包括环烯烃聚合物 (I)、其中，用于形成底层膜的树脂材料的固体粘弹性中的存储模量（G'）曲线和损失模量（G"）曲线的交点温度高于或等于 40°C，且低于或等于 200°C；该固体粘弹性是在测量温度范围为 30°C 至 300°C、加热速率为 3°C/min 和频率为 1 Hz 的条件下，在氮气环境中使用流变仪以剪切模式测得的。