phenanthrene-1,6-diol | 858856-61-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: phenanthrene-1,6-diol
• 英文别名: 1.6-Dioxy-phenanthren；Phenanthren-1,6-diol；1,6-Dihydroxyphenanthrene
• CAS: 858856-61-8
• 化学式: C₁₄H₁₀O₂
• 分子量: 210.232
• InChiKey: CQQWUPCMKUICIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  phenanthrene-1,6-diol 在 铬酸 、 溶剂黄146 作用下， 生成 1,6-diacetoxy-phenanthrene-9,10-dione
  参考文献：
  名称：

  Fieser, Journal of the American Chemical Society, 1929, vol. 51, p. 2468

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 硫酸 作用下， 生成 3,6-dihydroxyphenanthrene 、 phenanthrene-1,6-diol
  参考文献：
  名称：

  Fieser, Journal of the American Chemical Society, 1929, vol. 51, p. 2468

  摘要：

  DOI：

文献信息

• COMPOSITION FOR FORMING LIQUID CRYSTAL LAYER, LIQUID CRYSTAL DISPLAY DEVICE, AND METHOD FOR PRODUCING LIQUID CRYSTAL DISPLAY DEVICE
  申请人：Mizusaki Masanobu

  公开号：US20130135570A1

  公开（公告）日：2013-05-30

  The present invention provides a composition for forming a liquid crystal layer from which a liquid crystal display device hardly generating image sticking can be obtained. The composition for forming a liquid crystal layer according to the present invention contains a liquid crystal material and one or two or more monomers, wherein at least one of the monomers is a phenanthrene derivative represented by the following chemical formula (1): the following chemical formula (2): or the following chemical formula (3): wherein R 1 and R 2 are identical or different, and each denote an -Sp-P group, a hydrogen atom, a halogen atom, a —CN group, a —NO 2 group, a —NCO group, a —NCS group, an —OCN group, a —SCN group, a —SF 5 group, or a straight-chain or branched-chain alkyl group having 1 to 12 carbon atoms; at least one of R 1 and R 2 denotes an -Sp-P group; P denotes a polymerizable group; Sp denotes a straight-chain, branched-chain or cyclic alkylene group or alkyleneoxy group having 1 to 6 carbon atoms, or a direct bond of both groups interposing Sp; a hydrogen atom which R 1 and R 2 have may be replaced by a fluorine atom or a chlorine atom; and a —CH 2 — group which R 1 and R 2 have, unless oxygen atoms, sulfur atoms and nitrogen atoms are mutually adjacent, may be substituted with an —O— group, a —S— group, a —NH— group, a —CO— group, a —COO— group, a —OCO— group, an —O—COO— group, a —OCH 2 — group, a —CH 2 O— group, a —SCH 2 — group, a —CH 2 S— group, a —N(CH 3 )— group, a —N(C 2 H 5 )— group, a —N(C 3 H 7 )— group, a —N(C 4 H 5 )— group, a —CF 2 O— group, a —OCF 2 — group, a —CF 2 S— group, a —SCF 2 — group, a —N(CF 3 )— group, a —CH 2 CH 2 — group, a —CF 2 CH 2 — group, a —CH 2 CF 2 — group, a —CF 2 CF 2 — group, a —CH═CH— group, a —CF═CF— group, a —C≡C— group, a —CH═CH—COO— group, or a —OCO—CH═CH— group.

  本发明提供了一种用于形成液晶层的组合物，从中可以获得几乎不产生图像粘连的液晶显示器件。根据本发明的形成液晶层的组合物含有液晶材料和一种或两种或更多单体，其中至少一种单体是由以下化学式（1）表示的菲蒽衍生物，以下化学式（2）或以下化学式（3）：其中R1和R2相同或不同，每个表示一个-Sp-P基团、氢原子、卤素原子、-CN基团、-NO2基团、-NCO基团、-NCS基团、-OCN基团、-SCN基团、-SF5基团或1至12个碳原子的直链或支链烷基；其中至少一个R1和R2表示一个-Sp-P基团；P表示可聚合基团；Sp表示1至6个碳原子的直链、支链或环烷基或烷氧基，或者是介于Sp之间的两个基团的直接键；R1和R2的氢原子可以被氟原子或氯原子取代；除非氧原子、硫原子和氮原子相互相邻，否则R1和R2具有的-CH2-基团可以被- O-基团、-S-基团、-NH-基团、-CO-基团、-COO-基团、-OCO-基团、-O-COO-基团、-OCH2-基团、-CH2O-基团、-SCH2-基团、-CH2S-基团、-N（CH3）-基团、-N（C2H5）-基团、-N（C3H7）-基团、-N（C4H5）-基团、-CF2O-基团、-OCF2-基团、-CF2S-基团、-SCF2-基团、-N（CF3）-基团、-CH2CH2-基团、-CF2CH2-基团、-CH2CF2-基团、-CF2CF2-基团、-CH═CH-基团、-CF═CF-基团、-C≡C-基团、-CH═CH-COO-基团或-OCO-CH═CH-基团所取代。
• Method of preventing polymer-scale formation
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0320227A2

  公开（公告）日：1989-06-14

  A method of preventing polymer scales from sticking in a polymerization vessel during the polymerization of a monomer having an ethylenically double bond, wherein said polymerization is carried out in a polymerization vessel of which the inner wall and other parts with which said monomer comes into contact during polymerization are previously first coated with (a) a coating solution comprising a cationic dye and the resulting coating is then coated with (b) a coating solution comprising at least one component selected from the group consisting of anionic polymeric compounds, amphoteric polymeric compounds and hydroxyl group-containing organic compounds. Polymer scale formation can be effectively prevented.

  一种在具有乙烯双键的单体聚合过程中防止聚合物鳞片粘附在聚合容器中的方法，其中所述聚合在聚合容器中进行，聚合容器的内壁和在聚合过程中与所述单体接触的其他部分之前先涂有(a)由阳离子染料组成的涂层溶液，然后在所得涂层上涂有(b)由至少一种从阴离子聚合物化合物、两性聚合物化合物和含羟基有机化合物组成的组中选出的组分组成的涂层溶液。可有效防止聚合物结垢。
• METHODS AND SYSTEMS OF GRAFT POLYMERIZATION ON A FUNCTIONALIZED SUBSTRATE
  申请人：Spevacek John A.

  公开号：US20140296366A1

  公开（公告）日：2014-10-02

  Graft polymerization is fullfiled on a functionalized substrate. The functionalized substrate is prepared from a disulfide bond-containing feedstock and has been prepared for polymerization through the introduction of one or more polyfunctional monomers containing a disulfide bond breaking material functional group.
• US4933399A
  申请人：——

  公开号：US4933399A

  公开（公告）日：1990-06-12
• US9267009B2
  申请人：——

  公开号：US9267009B2

  公开（公告）日：2016-02-23