1,2,5-Trimethylcyclohexan-1-ol | 88138-86-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,2,5-Trimethylcyclohexan-1-ol
• CAS: 88138-86-7
• 化学式: C₉H₁₈O
• 分子量: 142.24
• InChiKey: FCZWEWBNRGMFBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• METHOD FOR PRODUCING CARBOXYLIC ACID
  申请人：National Institute of Advanced Industrial Science and Technology

  公开号：EP1544190A1

  公开（公告）日：2005-06-22

  The present invention provides a safe, convenient and efficient method for producing carboxylic acid by a reaction of alicyclic alcohol with an aqueous hydrogen peroxide to thereby obtain carboxylic acid in high yield from alicyclic alcohol or alicyclic ketone under mild reaction conditions, wherein the reaction operation is simple and easy, a step for removing solvent after completion of the reaction is not necessary and influence and toxicity upon the environment and human body are markedly small. In order to provide it, an oily alicyclic alcohol is allowed to react with an aqueous hydrogen peroxide in the presence of a catalyst containing a metal compound belonging to Group 6 of the Periodic Table in a heterogeneous solution system.

  本发明提供了一种安全、方便、高效的生产羧酸的方法，该方法通过脂环醇与过氧化氢水溶液反应，从而在温和的反应条件下，从脂环醇或脂环酮中高产率地获得羧酸，反应操作简单易行，反应完成后无需去除溶剂的步骤，对环境和人体的影响和毒性明显较小。为了实现这一目标，需要在一个异相溶液体系中，在含有元素周期表第 6 族金属化合物的催化剂存在下，使油性脂环醇与过氧化氢水溶液发生反应。
• (ALKYLPHENYL)ALKYLCYCLOHEXANE AND METHOD FOR PRODUCING (ALKYLPHENYL)ALKYLCYCLOHEXANE OR ALKYLBIPHENYL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1908743A1

  公开（公告）日：2008-04-09

  The invention provides a method for producing an (alkylphenyl)alkylcyclohexane, including a step of condensing an alkylbenzene with an alkylcyclohexene or an alkylcyclohexanol in the presence of an acid catalyst, and (alkylphenyl)alkylcyclohexane represented by formula (8). The (alkylphenyl)alkylcyclohexane produced through the production method can be transformed into an alkylbiphenyl, a biphenylpolycarboxylic acid, or a biphenylpolycarboxylic anhydride. Through the production method, an (alkylphenyl)alkylcyclohexane and an alkylbiphenyl of interest can be readily and selectively produced. (wherein R1 represents a C1-C4 alkyl group; R2 represents a C1-C4 alkyl group; m is an integer of 0 to 2; n' is an integer of 2 to 5; other conditions are the same as defined in claim 18.)

  本发明提供了一种生产(烷基苯基)烷基环己烷的方法，包括在酸催化剂存在下将烷基苯与烷基环己烯或烷基环己醇缩合的步骤，以及式(8)代表的(烷基苯基)烷基环己烷。通过该生产方法生产的（烷基苯）烷基环己烷可转化为烷基联苯、联苯聚羧酸或联苯聚羧酸酐。通过该生产方法，可以很容易地、有选择地生产出一种（烷基苯）烷基环己烷和一种烷基联苯。 (其中 R1 代表 C1-C4 烷基；R2 代表 C1-C4 烷基；m 为 0 至 2 的整数；n'为 2 至 5 的整数；其他条件与权利要求 18 中定义的相同)。
• Method for producing carboxylic acid
  申请人：Sato Kazuhiko

  公开号：US20050215817A1

  公开（公告）日：2005-09-29

  The present invention provides a safe, convenient and efficient method for producing carboxylic acid by a reaction of alicyclic alcohol with an aqueous hydrogen peroxide to thereby obtain carboxylic acid in high yield from alicyclic alcohol or alicyclic ketone under mild reaction conditions, wherein the reaction operation is simple and easy, a step for removing solvent after completion of the reaction is not necessary and influence and toxicity upon the environment and human body are markedly small. In order to provide it, an oily alicyclic alcohol is allowed to react with an aqueous hydrogen peroxide in the presence of a catalyst containing a metal compound belonging to Group 6 of the Periodic Table in a heterogeneous solution system.

  本发明提供了一种安全、方便、高效的生产羧酸的方法，该方法通过脂环醇与过氧化氢水溶液反应，从而在温和的反应条件下，从脂环醇或脂环酮中高产率地获得羧酸，反应操作简单易行，反应完成后无需去除溶剂的步骤，对环境和人体的影响和毒性明显较小。为了实现这一目标，需要在一个异相溶液体系中，在含有元素周期表第 6 族金属化合物的催化剂存在下，使油性脂环醇与过氧化氢水溶液发生反应。
• METHOD FOR PRODUCING CARBOXYLIC ACIDS
  申请人：National Institute of Advanced Industrial Science and Technology

  公开号：EP1544190B1

  公开（公告）日：2011-08-31
• (ALKYLPHENYL) ALKYLCYCLOHEXANE AND METHOD FOR PRODUCING (ALKYLPHENYL) ALKYLCYCLOHEXANE OR ALKYLBIPHENYL
  申请人：Kanbara Yutaka

  公开号：US20090299111A1

  公开（公告）日：2009-12-03

  The invention provides a method for producing an (alkylphenyl)alkylcyclohexane, including a step of condensing an alkylbenzene with an alkylcyclohexene or an alkylcyclohexanol in the presence of an acid catalyst, and (alkylphenyl)alkylcyclohexane represented by formula (8). The (alkylphenyl)alkylcyclohexane produced through the production method can be transformed into an alkylbiphenyl, a biphenylpolycarboxylic acid, or a biphenylpolycarboxylic anhydride. Through the production method, an (alkylphenyl)alkylcyclohexane and an alkylbiphenyl of interest can be readily and selectively produced. (wherein R 1 represents a C1-C4 alkyl group; R 2 represents a C1-C4 alkyl group; m is an integer of 0 to 2; n′ is an integer of 2 to 5; other conditions are the same as defined in claim 18 .)