[(1,2-bis(diisopropylphosphino)ethane)2Ni2]

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: [(1,2-bis(diisopropylphosphino)ethane)2Ni2]
• 英文别名: [(dippe)2Ni2]
• 化学式: 2C₁₄H₃₂P₂*2Ni
• 分子量: 642.091
• InChiKey: AAXBBHIZBPTDKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.58
• 重原子数：
  17.0
• 可旋转键数：
  7.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  [(1,2-bis(diisopropylphosphino)ethane)Ni(η2-adamantylcyanide)] 以 四氢呋喃 为溶剂， 生成 Ni(dippe)2 、 [(1,2-bis(diisopropylphosphino)ethane)2Ni2]
  参考文献：
  名称：

  Cleavage of Carbon−Carbon Bonds in Alkyl Cyanides Using Nickel(0)

  摘要：

  The reaction of the complex [(dippe)NiH](2) (1) with a variety of alkyl cyanides afforded nickel(0) compounds of the type [(dippe)Ni(eta(2)-RCN)], where R, = Me, Et, Pr, Pr-i, Bu-t, cyclopropyl, cyclobutyl, adamantyl (2-9, respectively). When compounds 2-9 were warmed to yield oxidative addition products, the thermal reaction proceeded only in the case of 2 to produce [(dippe)Ni(Me)(CN)](10). Photochemical activation did produce oxidative addition products from compounds 2-8, which rapidly evolved to the beta-elimination products of the organic moiety in most cases and to the formation of [(dippe)Ni(CN)(2)] (11). Reaction of 1 with acetonitrile in the presence of BPh3 gives [(dippe)Ni(eta(2)-MeCNBPh3)](12), which does not undergo thermal C-CN cleavage upon heating. X-ray crystal structures are reported for 10-12.

  DOI：

  10.1021/om049700t

文献信息

• Cleavage of Carbon−Carbon Bonds in Alkyl Cyanides Using Nickel(0)
  作者：Juventino J. García、Alma Arévalo、Nicole M. Brunkan、William D. Jones

  DOI：10.1021/om049700t

  日期：2004.8.1

  The reaction of the complex [(dippe)NiH](2) (1) with a variety of alkyl cyanides afforded nickel(0) compounds of the type [(dippe)Ni(eta(2)-RCN)], where R, = Me, Et, Pr, Pr-i, Bu-t, cyclopropyl, cyclobutyl, adamantyl (2-9, respectively). When compounds 2-9 were warmed to yield oxidative addition products, the thermal reaction proceeded only in the case of 2 to produce [(dippe)Ni(Me)(CN)](10). Photochemical activation did produce oxidative addition products from compounds 2-8, which rapidly evolved to the beta-elimination products of the organic moiety in most cases and to the formation of [(dippe)Ni(CN)(2)] (11). Reaction of 1 with acetonitrile in the presence of BPh3 gives [(dippe)Ni(eta(2)-MeCNBPh3)](12), which does not undergo thermal C-CN cleavage upon heating. X-ray crystal structures are reported for 10-12.