N-Methyl-N-{(o-formylphenoxy)-1-ethyl}aniline

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: N-Methyl-N-{(o-formylphenoxy)-1-ethyl}aniline
• 英文别名: 2-[2-(N-methylanilino)ethoxy]benzaldehyde
• 化学式: C₁₆H₁₇NO₂
• 分子量: 255.316
• InChiKey: ABPHWXDWPIQJRB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  肌氨酸 、 足球烯 、 N-Methyl-N-{(o-formylphenoxy)-1-ethyl}aniline 以 甲苯 为溶剂， 反应 10.0h， 以45%的产率得到
  参考文献：
  名称：

  Orientation-Dependent Electron Transfer Processes in Fullerene−Aniline Dyads

  摘要：

  Newly synthesized ortho- and para-substituted fullerene-aniline dyads exhibit orientation-dependent electron transfer under photoexcitation. Minimum energy conformation based on molecular mechanics calculations yield folded conformations for ortho-substituted dyads and extended ones for the para-substituted dyads. H-1 NMR studies also provided evidence for the folding of the anilinic group in the case of ortho-substituted dyads, Through-space charge transfer processes in these dyads were investigated using steady state fluorescence and lifetime measurements. The decrease in the spatial distance between the donor and acceptor moieties of the ortho-substituted dyads facilitated an efficient electron transfer. The marked increase in the singlet excited state deactivation rate constants and quantum yields of charge separation observed in the case of the ortho-substituted dyads, in polar solvents, further support a topographically controlled electron transfer process.

  DOI：

  10.1021/jp992369k
• 作为产物：
  描述：

  邻甲基苄醇 、 N-(2-溴乙基)-N-甲基苯胺 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 12.0h， 以60%的产率得到N-Methyl-N-{(o-formylphenoxy)-1-ethyl}aniline
  参考文献：
  名称：

  Orientation-Dependent Electron Transfer Processes in Fullerene−Aniline Dyads

  摘要：

  Newly synthesized ortho- and para-substituted fullerene-aniline dyads exhibit orientation-dependent electron transfer under photoexcitation. Minimum energy conformation based on molecular mechanics calculations yield folded conformations for ortho-substituted dyads and extended ones for the para-substituted dyads. H-1 NMR studies also provided evidence for the folding of the anilinic group in the case of ortho-substituted dyads, Through-space charge transfer processes in these dyads were investigated using steady state fluorescence and lifetime measurements. The decrease in the spatial distance between the donor and acceptor moieties of the ortho-substituted dyads facilitated an efficient electron transfer. The marked increase in the singlet excited state deactivation rate constants and quantum yields of charge separation observed in the case of the ortho-substituted dyads, in polar solvents, further support a topographically controlled electron transfer process.

  DOI：

  10.1021/jp992369k

文献信息

• Orientation-Dependent Electron Transfer Processes in Fullerene−Aniline Dyads
  作者：K. George Thomas、V. Biju、D. M. Guldi、Prashant V. Kamat、M. V. George

  DOI：10.1021/jp992369k

  日期：1999.12.1

  Newly synthesized ortho- and para-substituted fullerene-aniline dyads exhibit orientation-dependent electron transfer under photoexcitation. Minimum energy conformation based on molecular mechanics calculations yield folded conformations for ortho-substituted dyads and extended ones for the para-substituted dyads. H-1 NMR studies also provided evidence for the folding of the anilinic group in the case of ortho-substituted dyads, Through-space charge transfer processes in these dyads were investigated using steady state fluorescence and lifetime measurements. The decrease in the spatial distance between the donor and acceptor moieties of the ortho-substituted dyads facilitated an efficient electron transfer. The marked increase in the singlet excited state deactivation rate constants and quantum yields of charge separation observed in the case of the ortho-substituted dyads, in polar solvents, further support a topographically controlled electron transfer process.