4-hydroxyphenyl β-D-xylopyranosyl-(1->4)-β-D-xylopyranoside

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-hydroxyphenyl β-D-xylopyranosyl-(1->4)-β-D-xylopyranoside
• 英文别名: hydroquinone 4-O-(β-xylopyranosyl)-β-xylopyranoside；hydroquinone β-xylobioside；4-hydroxyphenyl β-xylobioside；β-(Xyl)2-HQ；(2S,3R,4S,5R)-2-[(3R,4R,5R,6S)-4,5-dihydroxy-6-(4-hydroxyphenoxy)oxan-3-yl]oxyoxane-3,4,5-triol
• 化学式: C₁₆H₂₂O₁₀
• 分子量: 374.345
• InChiKey: AGNLLHLDEZEZPT-DDJMUGOQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.1
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  158
• 氢给体数：
  6
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  对苯二酚 、 alkaline earth salt of/the/ methylsulfuric acid 反应 3.0h， 生成 (2S,3R,4S,5R)-2-(4-羟基苯氧基)四氢吡喃-3,4,5-三醇 、 4-hydroxyphenyl β-D-xylopyranosyl-(1->4)-β-D-xylopyranoside
  参考文献：
  名称：

  Enzymatic Synthesis of Hydroquinoneβ-Xyloside from Xylooligosaccharides

  摘要：

  β-Xylosidase of Aspergillus pulverulentus catalyzes a transxylosylation reaction from xylooligosaccharides to acceptor hydroquinone. Two transfer products were purified and their structures were examined. These were identified as hydroquinone β-(1→4)-xyloside and hydroquinone 4-O-(β-xylosyl)-β-xyloside. The hydrolysis of these glycosides apparently took place accompanying the synthesis of the transfer products.

  DOI：

  10.1271/bbb.58.1311

文献信息

• Enzymatic Synthesis of Hydroquinone<i>β</i>-Xyloside from Xylooligosaccharides
  作者：Joko Sulistyo、Yoshi Kamiyama、Hirotaka Ito、Tsuneo Yasui

  DOI：10.1271/bbb.58.1311

  日期：1994.1

  β-Xylosidase of Aspergillus pulverulentus catalyzes a transxylosylation reaction from xylooligosaccharides to acceptor hydroquinone. Two transfer products were purified and their structures were examined. These were identified as hydroquinone β-(1→4)-xyloside and hydroquinone 4-O-(β-xylosyl)-β-xyloside. The hydrolysis of these glycosides apparently took place accompanying the synthesis of the transfer products.