3-tert-Butoxy-2-undecanone

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-tert-Butoxy-2-undecanone
• 英文别名: 3-[(2-Methylpropan-2-yl)oxy]undecan-2-one
• 化学式: C₁₅H₃₀O₂
• 分子量: 242.402
• InChiKey: BBRQHAWIQQCOHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-tert-Butoxy-2-undecanone 以98%的产率得到
  参考文献：
  名称：

  Sakaguchi Satoshi, Watase Seiji, Katayama Yuji, Sakata Yasuyuki, Nishiyam+, J. Org. Chem, 59 (1994) N 19, S 5681-5686

  摘要：

  DOI：
• 作为产物：
  描述：

  十一碳-1,2-二烯 以9%的产率得到
  参考文献：
  名称：

  Sakaguchi Satoshi, Watase Seiji, Katayama Yuji, Sakata Yasuyuki, Nishiyam+, J. Org. Chem, 59 (1994) N 19, S 5681-5686

  摘要：

  DOI：

文献信息

• Oxidation of Allenes and Alkynes with Hydrogen Peroxide Catalyzed by Cetylpyridinium Peroxotungstophosphate (PCWP)
  作者：Satoshi Sakaguchi、Seiji Watase、Yuji Katayama、Yasuyuki Sakata、Yutaka Nishiyama、Yasutaka Ishii

  DOI：10.1021/jo00098a028

  日期：1994.9

  The oxidation of allenes and alkynes with hydrogen peroxide catalyzed by peroxotungstophosphate (PCWP) was examined. A variety of allenes were first converted into the corresponding alpha-ethoxy ketones upon treatment with 35% H2O2 under the influence of PCWP in a mixed solvent consisting of ethanol and dichloromethane. When the reaction was carried out using tert-butyl alcohol as a solvent, approximately a 1:1 regioisomeric mixture of alpha-hydroxy ketones was obtained along with a small amount of alpha-tert-butoxy ketone. Oxidation of internal alkynes such as 4-octyne by the PCWP-H2O2 system under phase-transfer conditions using chloroform produced alpha,beta-epoxy ketones in good yields. The same reaction in a mixed solvent of ethanol and chloroform gave alpha,beta-unsaturated ketones rather than alpha,beta-epoxy ketones. Plausible reaction paths are proposed for the oxidation of allenes and alkynes by the PCWP-H2O2 system.
• Sakaguchi Satoshi, Watase Seiji, Katayama Yuji, Sakata Yasuyuki, Nishiyam+, J. Org. Chem, 59 (1994) N 19, S 5681-5686
  作者：Sakaguchi Satoshi, Watase Seiji, Katayama Yuji, Sakata Yasuyuki, Nishiyam+

  DOI：——

  日期：——