[60]fullerene

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: [60]fullerene
• 英文别名: fullerene C60；fullerene；3.1 knocarbyne；Buckminsterfullerene；methane
• 化学式: C₆₀
• 分子量: 720.66
• InChiKey: KPKXDVZAXZWVEY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.82
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [60]fullerene 生成 甲烷
  参考文献：
  名称：

  Amorphization of C60 fullerite by applying pressure in the GPa range using a scanning tunneling microscope: Observation of transitions and aging

  摘要：

  Fullerene molecules of a few monolayers thick C-60(111) film on Au(111) supported on mica, have been exposed to a pressure of approximate to 20 GPa by using the tip of a scanning tunneling microscope (STM) operated at 40 nA and 4 mV. Subsequent imaging at 0.7 nA and - 11 mV shows that this pressure has induced a transformation of C-60 fullerite into an amorphous structure with a nearest neighbour distance of 0.28 nm. The time evolution of this structure within approximate to 90 min reveals formation of nanocrystalline domains, their transformation into square eight-membered closed ring structures, and the breaking-up of these rings initially zig-zag, and then finally straight chains. Assignment of pentagon and hexagon carbon rings to the observed arrangements of protrusions is a possible explanation. Pair distribution and angular distribution functions are calculated based on the position of the protrusions extracted from the images. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0022-3697(97)00062-0
• 作为产物：
  描述：

  富勒烯 以 solid 为溶剂， 生成 [60]fullerene
  参考文献：
  名称：

  C2m-X-C2n富勒烯二聚体的高选择性和简单合成

  摘要：

  富勒烯的能量辐射诱导的二聚反应被发现是一种简单且高选择性的合成 C2m-X-C2n (m = n 或 m ≠ n) 型分子而不形成其他产物的方法。利用新方法制备并表征了 C70-C-C70、C60-C-C70、C60-C-C60 和 C70-O-C70。该方法能够通过将 X（不同原子）引入反应体系来合成新的 C2m-X-C2n 分子。高能辐射为富勒烯分子之间的共价键桥创造了反应位点，最初仅通过范德华力弱结合。这一观察结果可能为富勒烯聚合物科学开辟一个新的主题和可行的方法。

  DOI：

  10.1021/ja048232b

文献信息

• Synthesis of fullerenes via the thermal plasma dissociation of hydrocarbons
  作者：Theodora Alexakis、Peter G. Tsantrizos、Youla S. Tsantrizos、Jean-Luc Meunier

  DOI：10.1063/1.118962

  日期：1997.4.21

  plasma process is described for the synthesis of fullerenes via the dissociation of hydrocarbons. The plasma reactor is equipped with a nontransferred dc plasma torch which was used to dissociate hydrocarbons. The hydrocarbons investigated include CH4, C2H2, CBrF3, CCl2F2, and C2Cl4. The best results are obtained with C2Cl4. The collection temperature of the fullerene soot in the process was found to

  描述了通过烃的离解合成富勒烯的热等离子体工艺。等离子体反应器配备有用于解离碳氢化合物的非转移直流等离子体炬。研究的碳氢化合物包括 CH4、C2H2、CBrF3、CCl2F2 和 C2Cl4。最好的结果是用 C2Cl4 获得的。发现过程中富勒烯烟灰的收集温度对富勒烯的收集率起着关键作用。
• Structure and superconductivity in alkali- ammonia complex fullerides
  作者：Y. Iwasa、H. Shimoda、Y. Miyamoto、T. Mitani、Y. Maniwa、O. Zhou、T.T.M. Palstra

  DOI：10.1016/s0022-3697(97)00054-1

  日期：1997.11

  Abstract Alkali ammonia complex fullendes form a rich variety of compounds with unique structural and electronic properties. Intercalation of NH3 into K3C60 produces orthorhombic NH3C60, which undergoes a metal-insulator transition instead of superconductivity that is expected to occur at around 30 K from the empirical relation betweenTc and the lattice parameter. Synthesis in liquid ammonia yields new

  摘要 碱氨络合物富烯化合物形成丰富多样的化合物，具有独特的结构和电子特性。NH3 插入 K3C60 产生正交 NH3C60，它经历金属-绝缘体转变而不是超导，根据 Tc 和晶格参数之间的经验关系，预计在 30 K 左右发生超导。在液氨中合成产生新的超导富勒 (NH3)xNaA2C60 (0.5
• High resolution 13C NMR investigation of A6C60 (A=K, Rb, Cs) and Ba3C60
  作者：L. Hajji、F. Rachdi、C. Goze、M. Mehring、J.E. Fischer

  DOI：10.1016/0038-1098(96)00442-5

  日期：1996.11

  Abstract We report the result of 13 C nuclear magnetic resonance (NMR) measurements on A 6 C 60 ( A =K, Rb, Cs) and Ba 3 C 60 . By using high-resolution magic angle spinning, we were able to identify an isotropic line around 156 ppm for all investigated compounds. NMR spectra of the saturated alkali compounds are quite similar. The corresponding isotropic lines show three narrow components consistent

  摘要 我们报告了对 A 6 C 60 (A =K, Rb, Cs) 和 Ba 3 C 60 的 13 C 核磁共振 (NMR) 测量结果。通过使用高分辨率魔角旋转，我们能够识别出所有研究化合物的 156 ppm 左右的各向同性线。饱和碱性化合物的核磁共振谱非常相似。相应的各向同性线显示三个窄组分，与定向排列的 C 60 分子一致，导致这些化合物中的三个非等价碳位点，如 X 射线研究报告的那样。Ba 3 C 60 各向同性谱线没有观察到谱线分裂。
• Two superconducting phases related to different stoichiometry of K-doped C60
  作者：W. Kempiński、J. Stankowski

  DOI：10.1016/0038-1098(95)00722-9

  日期：1996.3

  Abstract The evolution of superconductivity related to a different v value of C 60 v− radicals was examined by means of the MMMA method. Two different and well separated onset T c temperatures were found: T c (1) = (21 ± 0.5) K related to the presence of C 60 1− EPR signal and T c (2) = (18 ± 0.5) K related to C 60 3− in EPR spectrum.

  摘要 通过 MMMA 方法研究了与 C 60 v- 自由基的不同 v 值相关的超导性的演变。发现了两种不同且分离良好的起始 T c 温度：T c (1) = (21 ± 0.5) K 与 C 60 1− EPR 信号的存在相关，T c (2) = (18 ± 0.5) K 与EPR光谱中的C 60 3− 。
• Synthesis and Isolation of a Fullerene Carbocation (C₇₆<b>⁺</b>)
  作者：Robert D. Bolskar、Rajeev S. Mathur、Christopher A. Reed

  DOI：10.1021/ja962294n

  日期：1996.1.1

  Development of an `electron hole` oxidant, [Arsub 3}Nsup .+}][CBsub 11}Hsub 6}Brsub 6}sup -}], that is generally suited to the preparation of highly reactive cations and illustrates its use in the isolation of a Csub 76}sup +} salt, is reported. The choice of Csub 76} over Csub 60} or Csub 70} was made on the basis of electrochemical oxidation potentials: Edegree} = +0.81 V compared to

  开发“电子空穴”氧化剂 [Arsub 3}Nsup .+}][CBsub 11}Hsub 6}Brsub 6}sup -}]，通常适用于据报道，高活性阳离子的制备并说明其在分离 Csub 76}sup +} 盐中的用途。选择 Csub 76} 而不是 Csub 60} 或 Csub 70} 是基于电化学氧化电位：Edegree} = +0.81 V 与 Csub 60} 的 +1.26 V 相比​​，以及Csub 70} 为 +1.20 V（引用 Edegree} 与二茂铁/二茂铁对 = 0.00 V；SCE = -0.31 V）。16 个参考文献，4 个无花果。