(E)-octa-3,7-dien-1-ol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-octa-3,7-dien-1-ol
• 英文别名: 7-Octadien-1-ol；(3E)-octa-3,7-dien-1-ol
• 化学式: C₈H₁₄O
• 分子量: 126.199
• InChiKey: KDPNQUKYJYHMHN-AATRIKPKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  反式肉桂醛 、 (E)-octa-3,7-dien-1-ol 在 三甲基氯硅烷 、 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以54%的产率得到
  参考文献：
  名称：

  Lewis Acid Promoted Prins Cyclization Using Non-Conjugated Diene Alcohol: Sequential Reactions Terminated by Fluoride Ion

  摘要：

  The sequential cyclization involving Prins cyclization was successfully demonstrated, in which the various aldehydes bearing the alkyl or aromatic substituent were reacted with the alcohol bearing the non-conjugated diene moiety in the presence of 2 equiv. of BF3 center dot Et2O and 4 mol% of TMSC1 at -40 degrees C to afford the corresponding fluorinated bicyclic compounds in moderate to good yields.

  DOI：

  10.3987/com-18-13940
• 作为产物：
  描述：

  4-戊烯醛 、 (3-hydroxypropyl)triphenylphosphonium iodide 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 生成 (E)-octa-3,7-dien-1-ol 、 (Z)-octa-3,7-dien-1-ol
  参考文献：
  名称：

  Lewis Acid Promoted Prins Cyclization Using Non-Conjugated Diene Alcohol: Sequential Reactions Terminated by Fluoride Ion

  摘要：

  The sequential cyclization involving Prins cyclization was successfully demonstrated, in which the various aldehydes bearing the alkyl or aromatic substituent were reacted with the alcohol bearing the non-conjugated diene moiety in the presence of 2 equiv. of BF3 center dot Et2O and 4 mol% of TMSC1 at -40 degrees C to afford the corresponding fluorinated bicyclic compounds in moderate to good yields.

  DOI：

  10.3987/com-18-13940

文献信息

• Emulsion composition of modified polypropylene
  申请人：Ozaki Hiroyuki

  公开号：US20070004847A1

  公开（公告）日：2007-01-04

  An emulsion composition of a modified polypropylene. It can have exceedingly improved emulsion stability because the modified polypropylene used has extremely high solubility in solvents and is easily emulsifiable. The modified-polypropylene emulsion composition comprises water and a modified polypropylene dispersed and emulsified therein, and is characterized in that the modified polypropylene has a racemic diad content [r] of 0.12 to 0.88 and has hydrophilic functional groups in a number of 0.5 or larger on the average per molecular chain of the polypropylene.

  一种改性聚丙烯的乳液组合物。它可以具有极大改善的乳液稳定性，因为所使用的改性聚丙烯在溶剂中具有极高的溶解度，并且易于乳化。改性聚丙烯乳液组合物包括水和分散和乳化其中的改性聚丙烯，其特征在于改性聚丙烯的嘧啶二聚物含量[r]为0.12至0.88，并且在聚丙烯的每条分子链上平均有0.5个或更多的亲水性功能基团。
• Process for the preparation of an aldehyde
  申请人：DSM N.V.

  公开号：EP0839787A1

  公开（公告）日：1998-05-06

  Process for the preparation of an aldehyde through hydroformylation of an unsaturated organic compound in the presence of a catalyst system comprising rhodium or iridium and a multidentate organic phosphite ligand, wherein a monodentate phosphine is present. The process according to the invention can advantageously be carried out for the preparation of methyl-5-formylvalerate, which is an intermediate product in the preparation of ε-caprolactam or adipic acid, which are in turn raw materials for the preparation of nylon-6 and nylon-6,6, respectively.

  在由铑或铱和多价有机亚磷酸酯配体组成的催化剂体系存在下，通过不饱和有机化合物的氢甲酰化制备醛的工艺，其中存在单价膦。 5-甲酰基戊酸甲酯是制备ε-己内酰胺或己二酸的中间产物，而ε-己内酰胺或己二酸又分别是制备尼龙-6 和尼龙-6,6 的原料。
• EMULSION COMPOSITION OF MODIFIED POLYPROPYLENE
  申请人：Tonen Chemical Corporation

  公开号：EP1642931A1

  公开（公告）日：2006-04-05

  An emulsion composition of a modified polypropylene. It can have exceedingly improved emulsion stability because the modified polypropylene used has extremely high solubility in solvents and is easily emulsifiable. The modified-polypropylene emulsion composition comprises water and a modified polypropylene dispersed and emulsified therein, and is characterized in that the modified polypropylene has a racemic diad content [r] of 0.12 to 0.88 and has hydrophilic functional groups in a number of 0.5 or larger on the average per molecular chain of the polypropylene.

  一种改性聚丙烯乳液组合物。由于所使用的改性聚丙烯在溶剂中具有极高的溶解度，且易于乳化，因此可以极大地提高乳液稳定性。改性聚丙烯乳液组合物包括水和分散并乳化在其中的改性聚丙烯，其特征在于改性聚丙烯的外消旋二元含量[r]为 0.12 至 0.88，并且聚丙烯的平均每条分子链上的亲水官能团数量为 0.5 或更多。
• Carbostyril derivatives
  申请人：OTSUKA PHARMACEUTICAL CO., LTD.

  公开号：EP0382185B1

  公开（公告）日：1994-06-15
• LAROCK, RICHARD C.;STOLZ-DUNN, SANDRA K., SYNLETT,(1990) N, C. 341-343
  作者：LAROCK, RICHARD C.、STOLZ-DUNN, SANDRA K.

  DOI：——

  日期：——