乙氧基甲氧基甲氧基甲氧基乙烷 | 4431-82-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 乙氧基甲氧基甲氧基甲氧基乙烷
• 英文名称: POME₃
• 英文别名: bis-ethoxymethoxy-methane；Formaldehyd-bis-aethoxymethylacetal；Tris-methylenglykol-diaethylaether；Bis-aethoxymethoxy-methan；3,5,7,9-Tetraoxaundecan；Diethoxy-trioxymethylen；3,5,7,9-Tetraoxaundecane；ethoxymethoxymethoxymethoxyethane
• CAS: 4431-82-7
• 化学式: C₇H₁₆O₄
• 分子量: 164.202
• InChiKey: BCJWVBNBMCOBEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  11
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 二乙氧基甲烷 在 硫酸 作用下， 100.0 ℃ 、686.42 kPa 条件下， 生成 1-(ethoxymethoxymethoxy)ethane 、 乙氧基甲氧基甲氧基甲氧基乙烷
  参考文献：
  名称：

  Preparation of polyformals

  摘要：

  公开号：

  US02449469A1

文献信息

• AQUEOUS COMPOSITION BASED ON POLYOXYMETHYLENE DIALKYL ETHERS (POM) AND THEIR USE FOR THE PRESERVATION AND/OR EMBALMING OF THE HUMAN OR ANIMAL BODY
  申请人：ARKEMA FRANCE

  公开号：US20200305414A1

  公开（公告）日：2020-10-01

  The invention relates to a composition comprising: a) a mixture of polyoxymethylene dialkyl ethers (POM) having a restricted specific molecular distribution b) at least one biocidal agent c) at least one pro-penetrating agent d) at least one dye e) optionally, another additive and water as diluent. It also relates to a non-therapeutic method of preserving and/or embalming a dead human or animal body using the composition, such as the use of this composition for anatomopathological purposes.

  该发明涉及一种组合物，包括：a) 具有受限特定分子分布的聚甲醛二烷基醚（POM）混合物b) 至少一种生物杀菌剂c) 至少一种促进渗透的剂d) 至少一种染料e) 可选地，另一种添加剂以及作为稀释剂的水。它还涉及一种非治疗方法，用该组合物保存和/或防腐死去的人类或动物尸体，例如将该组合物用于解剖病理学目的。
• Brønsted-acidic ionic liquids as efficient catalysts for the synthesis of polyoxymethylene dialkyl ethers
  作者：Heyuan Song、Meirong Kang、Fuxiang Jin、Guoqin Wang、Zhen Li、Jing Chen

  DOI：10.1016/s1872-2067(17)62816-x

  日期：2017.5

  Abstract Acetalation of formaldehyde (HCHO) with dialkyl formal or aliphatic alcohol to prepare polyoxymethylene dialkyl ethers (RO(CH2O)nR, n ≥ 1) catalyzed by Bronsted-acidic ionic liquids has been developed. The correlation between the structure and acidity activity of various ionic liquids was studied. Among the ionic liquids investigated, 1-(4-sulfonic acid)butyl-3-methylimidazolium hydrogen sulfate

  摘要 已开发出在布朗斯台德酸性离子液体的催化下，甲醛 (HCHO) 与二烷基缩甲醛或脂肪醇的乙酰化反应制备聚甲醛二烷基醚 (RO(CH2O)nR，n ≥ 1)。研究了各种离子液体的结构与酸度活性之间的相关性。在所研究的离子液体中，1-(4-磺酸)丁基-3-甲基咪唑硫酸氢盐([MIMBs]HSO4)在二乙氧基甲烷(DEM1)与三恶烷的反应中表现出最好的催化性能。以[MIMBs]HSO4为催化剂，研究了离子液体负载量、DEM1与HCHO摩尔比、反应温度、压力、时间和反应物来源对催化反应的影响。在 n([MIMBs]HSO4):n(DEM1):n(HCHO) = 1:80:80、140 °C、4 h 的最佳条件下，HCHO 的转化率和 DEM2-8 的选择性分别为 92.6% 和 95.1%。[MIMBs]HSO4 催化剂可以很容易地分离和重复使用。提出了 [MIMBs]HSO4 催化性能的可行机制。
• GB603872
  申请人：——

  公开号：——

  公开（公告）日：——
• ACETAL METATHESIS POLYMERIZATION
  申请人：UNVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

  公开号：US20140024801A1

  公开（公告）日：2014-01-23

  A method of preparing a polyacetal comprising polymerization of a mixture comprising a plurality of at least one bis-acetal monomer in the presence of an acid catalyst that promotes the metathesis of the acetal units. The bis-acetal can be formed from an acid catalyzed exchange between a mono-acetal monomer with a diol. The formation of the bis-acetal and the polyacetal can be carried out simultaneously. The diol can be isolated from a biorenewable source and the ultimate polyacetal is a degradable or biodegradable polymer.
• MULTILAYER CURABLE RESIN FILM, PREPREG, LAMINATE, CURED PRODUCT, COMPOSITE, AND MULTILAYER CIRCUIT BOARD
  申请人：ZEON CORPORATION

  公开号：US20170223843A1

  公开（公告）日：2017-08-03

  A multilayer curable resin film comprising a first resin layer comprising a first curable resin composition including a polyphenylene ether oligomer (A1) with an end modified by an aromatic vinyl group and a curing agent (A2) and a second resin layer comprising a second curable resin composition including an alicyclic olefin polymer (B1) and a curing agent (B2), a prepreg comprised of this including a fiber substrate, and a laminate, cured product, composite, and multilayer circuit board obtained using these are provided.