9,9-bis(9-phenylcarbazol-3-yl)fluorene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9,9-bis(9-phenylcarbazol-3-yl)fluorene
• 英文别名: 9-Phenyl-3-[9-(9-phenylcarbazol-3-yl)fluoren-9-yl]carbazole
• 化学式: C₄₉H₃₂N₂
• 分子量: 648.806
• InChiKey: PJLSCOVTSZWPAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.8
• 重原子数：
  51
• 可旋转键数：
  4
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.02
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9,9-bis(9-phenylcarbazol-3-yl)fluorene 、 9-苯基-9-芴醇 在 四磷十氧化物 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以92%的产率得到9,9-bis[3-(9-phenylfluoren-9-yl)-9-phenylcarbazol-6-yl]fluorene
  参考文献：
  名称：

  新型咔唑/芴杂化物：用于蓝色磷光OLED的主体材料。

  摘要：

  [反应：见正文]通过咔唑环的弗瑞德-克来夫斯型取代有效地合成了一系列咔唑/芴（CBZm-Fn）杂化物。这些化合物是用于OLED应用的热和形态稳定的主体材料。当使用CBZ1-F2作为主体和FIrpic作为客体时，可以获得高效的蓝色磷光OLED。

  DOI：

  10.1021/ol060884c
• 作为产物：
  描述：

  9-芴酮 、 N-苯基咔唑 在 四磷十氧化物 作用下， 以 二氯甲烷 为溶剂， 以73%的产率得到9,9-bis(9-phenylcarbazol-3-yl)fluorene
  参考文献：
  名称：

  新型咔唑/芴杂化物：用于蓝色磷光OLED的主体材料。

  摘要：

  [反应：见正文]通过咔唑环的弗瑞德-克来夫斯型取代有效地合成了一系列咔唑/芴（CBZm-Fn）杂化物。这些化合物是用于OLED应用的热和形态稳定的主体材料。当使用CBZ1-F2作为主体和FIrpic作为客体时，可以获得高效的蓝色磷光OLED。

  DOI：

  10.1021/ol060884c

文献信息

• ORGANIC LIGHT-EMITTING DIODE LUMINAIRES
  申请人：Lecloux Daniel David

  公开号：US20110260141A1

  公开（公告）日：2011-10-27

  There is provided an organic light-emitting diode luminaire. The luminaire includes a first electrode, a second electrode, and an electroluminescent layer therebetween. The electroluminescent layer includes: a first electroluminescent material having an emission color that is blue; and a second electroluminescent material having an emission color that is red-orange. The additive mixing of the emitted colors results in an overall emission of white light.
• ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC ELECTROLUMINESCENT LIGHTING DEVICE AND ORGANIC ELECTROLUMINESCENT DISPLAY DEVICE
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20150076483A1

  公开（公告）日：2015-03-19

  An organic electroluminescent element comprising: an anode; a cathode; a luminescent layer provided between the anode and the cathode; and a hole injecting and transporting layer provided between the anode and the cathode and adjacent to the luminescent layer, wherein at least the luminescent layer is formed by a wet film forming method, and contains a charge transporting material and a luminescent material, in which the charge transporting material contains a hole transporting material and an electron transporting material each having a specific partial structure, and the luminescent material contains at least three kinds of materials and has an emission spectrum having at least two kinds of emission maximums.
• US9379361B2
  申请人：——

  公开号：US9379361B2

  公开（公告）日：2016-06-28
• [EN] ORGANIC LIGHT-EMITTING DIODE LUMINAIRES<br/>[FR] PANNEAUX LUMINEUX À DIODES ÉLECTROLUMINESCENTES ORGANIQUES
  申请人：DU PONT

  公开号：WO2011059722A2

  公开（公告）日：2011-05-19

  There is provided an organic light-emitting diode luminaire. The luminaire includes a first electrode, a second electrode, and an electroluminescent layer therebetween. The electroluminescent layer includes: a first electroluminescent material having an emission color that is blue; and a second electroluminescent material having an emission color that is red orange. The additive mixing of the emitted colors results in an overall emission of white light.
• [EN] ORGANIC LIGHT-EMITTING DIODE LUMINAIRES<br/>[FR] LUMINAIRES À DIODES ÉLECTROLUMINESCENTES ORGANIQUES
  申请人：DU PONT

  公开号：WO2011059724A2

  公开（公告）日：2011-05-19

  There is provided an organic light-emitting diode luminaire. The luminaire includes a first electrode, a second electrode, and an electroluminescent layer there between. The electroluminescent layer includes: a first electroluminescent material having an emission color that is blue; and a second electroluminescent material having an emission color that is yellow. The additive mixing of the emitted colors results in an overall emission of white light.