1,1,2,3-tetrakis(4-hydroxyphenyl)propane

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 1,1,2,3-tetrakis(4-hydroxyphenyl)propane
• 英文别名: 4-[2,3,3-Tris(4-hydroxyphenyl)propyl]phenol
• 化学式: C₂₇H₂₄O₄
• 分子量: 412.485
• InChiKey: GPNMDKAGAKASTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  compound-p-cumylphenol 、 1,3-二氯丙酮 、 苯酚 生成 1,1,2,3-tetrakis(4-hydroxyphenyl)propane
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Aromatic polycarbonate and production method thereof
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0600447A2

  公开（公告）日：1994-06-08

  A method for preparing an aromatic polycarbonate having less content of a low molecular weight oligomer which comprises the steps of : (A) conducting an interfacial polymerization reaction in a reaction system comprising at least one aromatic dihydroxy compound, a carbonate precursor, an alkali metal or alkaline earth metal base, water and an organic solvent in the absence of an endcapping agent, and (B) conducting an interfacial polymerization reaction with the addition of an endcapping agent after at least one of the following parameters reaches a predetermined value : (1) a weight-average molecular weight of a prepolymer obtained in step A, (2) a residual amount of the aromatic dihydroxy compound which is contained in the reaction mixture obtained in step A, (3) an amount ratio of a bishaloformate compound to a prepolymer wherein the bishaloformate compound is a bishaloformate derivative of a dihydroxy compound and is contained in the reaction mixture obtained in step A.

  一种制备低分子量低聚物含量较少的芳香族聚碳酸酯的方法，包括以下步骤： ： (A) 在反应体系中进行界面聚合反应，该反应体系包括至少一种芳香族二羟基化 合物、碳酸盐前体、碱金属或碱土金属碱、水和有机溶剂，在没有封端剂的情 况下，以及 (B) 在下列参数中的至少一个参数达到预定值后，加入终结封端剂进行界面聚合反应： (1) 在步骤 A 中获得的预聚物的重量平均分子量、 (2) 在步骤 A 中得到的反应混合物中含有的芳香族二羟基化合物的残留量、 (3) 双羟烷基甲酸酯化合物与预聚物的量比，其中双羟烷基甲酸酯化合物是二羟基化合物的双羟烷基甲酸酯衍生物，包含在步骤 A 中得到的反应混合物中。
• Aromatic polycarbonate resin, electrophotographic photoconductor, process cartridge, and electrophotographic image forming method and apparatus
  申请人：RICOH COMPANY, LTD.

  公开号：US20020098430A1

  公开（公告）日：2002-07-25

  An electrophotographic photoconductor has an electroconductive support, and a photoconductive layer formed thereon containing as an effective component an aromatic polycarbonate resin having a structural unit of formula (2) and a structural unit with charge transporting properties, each of the structural units being contained in an amount of 5 wt. % or more of the total weight of the polycarbonate resin. There is disclosed an aromatic polycarbonate resin having a structural unit of formula (1) and the structural unit of formula (2), with the relationship between the composition ratios being 0

  一种电子照相光电导体具有一个导电支架，以及在其上形成的光电导体层，该光电导体层含有作为有效成分的芳香族聚碳酸酯树脂，该芳香族聚碳酸酯树脂具有式（2）的结构单元和具有电荷传输特性的结构单元，每个结构单元的含量占聚碳酸酯树脂总重量的5重量％或更多。本发明公开了一种具有式（1）结构单元和式（2）结构单元的芳香族聚碳酸酯树脂，当结构单元（1）的组成比为 k，结构单元（2）的组成比为 j 时，组成比之间的关系为 0树脂。式(1)至(3)已在说明书中说明。
• Diphenol compound, aromatic polycarbonate and electrophotoconductive photoconductor
  申请人：——

  公开号：US20020147278A1

  公开（公告）日：2002-10-10

  An electrophotographic photoconductor having an electroconductive support, and a photoconductive layer formed thereon and containing an aromatic polycarbonate resin having a structural unit of formula (3) shown in the specification. The polycarbonate resin is produced from a diphenol compound of the formula (1) shown in the specification.

  一种电子照相光电导体，具有导电支架和在其上形成的光电导体层，并含有芳香族聚碳酸酯树脂，其结构单元如说明书所示的式 (3)。该聚碳酸酯树脂由说明书所示式（1）的二酚化合物制得。
• Aromatic block polycarbonate resin, diphenol compound for preparation of the polycarbonate resin, electro-photographic photoconductor, electro-photographic image forming apparatus and process, and process cartridge
  申请人：RICOH COMPANY, LTD.

  公开号：US20040002574A1

  公开（公告）日：2004-01-01

  An aromatic block polycarbonate resin is prepared by polymerizing a diphenol compound of formula (2) or (4), a diol compound of formula (1) or (5), and a halogenated carbonyl compound. The diphenol compound of formula (4) is produced by polymerizing the diphenol compound of formula (2) and a halogenated carbonyl compound by solution or interfacial polymerization. An electrophotographic photoconductor has an electroconductive support and a photoconductive layer formed thereon containing the above-mentioned aromatic block polycarbonate resin. An electrophotographic image forming method or apparatus employs the above-mentioned photoconductor. A process cartridge holds therein the photoconductor and at least one of the electrophotographic image forming units.
• US4415724A
  申请人：——

  公开号：US4415724A

  公开（公告）日：1983-11-15