1H,1'H-biimdazole-4,4'-dicarboxylic acid

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1H,1'H-biimdazole-4,4'-dicarboxylic acid
• 英文别名: 2-(5-carboxy-1H-imidazol-2-yl)-1H-imidazole-5-carboxylic acid
• 化学式: C₈H₆N₄O₄
• 分子量: 222.16
• InChiKey: VPQSUQCHNPDMTC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  132
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  盐酸 、 molybdophosphoric acid hydrate 、 1H,1'H-biimdazole-4,4'-dicarboxylic acid 、 copper(II) nitrate trihydrate 以 水 为溶剂， 反应 72.75h， 以18%的产率得到
  参考文献：
  名称：

  Using imdazole-2-carboxylic and biimdazole-4,4′-dicarboxylic acid to construct Keggin-based mono-nuclear Ag+ subunit and double Cl-capped tri-nuclear Cu+ clusters

  摘要：

  Three metal-organic complexes (MOCs) based on Keggin-type polyoxometalate anions and two organic ligands 1H-Imdazole-2-carboxylic acid (L-1) and 1H, 1'H-Biimdazole-4,4'-dicarboxylic acid (L-2), [Ag-2(L-1)(4)] [HPMo12O40]center dot 3H(2)O (1), [Ag-2(L-1)(4)][HPW12O40]center dot H2O (2) and [(Cu6Cl4)-Cl-I(L-2)(6)][H3PMo12O40]center dot 2NO(3) (3), have been synthesized under hydrothermal conditions and structurally characterized by single crystal X-ray diffraction analyses, elemental analyses and IR spectra. Complexes 1 and 2 are isostructural and contain a supramolecular chain with a -ABAB- style. The adjacent one dimensional (1D) chains through hydrogen bonding interactions form a 2D supramolecular layer. In complex 3, there exist double Cl-capped tri-nuclear Cu+ clusters. Furthermore, the photocatalytic and fluorescent properties of complexes 1-3 and electrochemical behavior of complexes 2 and 3 were investigated. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2015.10.005

文献信息

• Using imdazole-2-carboxylic and biimdazole-4,4′-dicarboxylic acid to construct Keggin-based mono-nuclear Ag+ subunit and double Cl-capped tri-nuclear Cu+ clusters
  作者：Ai-Xiang Tian、Xue Hou、Jun Ying、Guo-Cheng Liu、Ya-Li Ning、Tian-Jiao Li、Xiu-Li Wang

  DOI：10.1016/j.ica.2015.10.005

  日期：2016.1

  Three metal-organic complexes (MOCs) based on Keggin-type polyoxometalate anions and two organic ligands 1H-Imdazole-2-carboxylic acid (L-1) and 1H, 1'H-Biimdazole-4,4'-dicarboxylic acid (L-2), [Ag-2(L-1)(4)] [HPMo12O40]center dot 3H(2)O (1), [Ag-2(L-1)(4)][HPW12O40]center dot H2O (2) and [(Cu6Cl4)-Cl-I(L-2)(6)][H3PMo12O40]center dot 2NO(3) (3), have been synthesized under hydrothermal conditions and structurally characterized by single crystal X-ray diffraction analyses, elemental analyses and IR spectra. Complexes 1 and 2 are isostructural and contain a supramolecular chain with a -ABAB- style. The adjacent one dimensional (1D) chains through hydrogen bonding interactions form a 2D supramolecular layer. In complex 3, there exist double Cl-capped tri-nuclear Cu+ clusters. Furthermore, the photocatalytic and fluorescent properties of complexes 1-3 and electrochemical behavior of complexes 2 and 3 were investigated. (C) 2015 Elsevier B.V. All rights reserved.