(sodium α-D-glucopyranosyluronate)-(1->4)-D-glucopyranose

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (sodium α-D-glucopyranosyluronate)-(1->4)-D-glucopyranose
• 英文别名: sodium;(2S,3S,4S,5R,6S)-3,4,5-trihydroxy-6-[(2R,3S,4R,5R)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxane-2-carboxylate
• 化学式: C₁₂H₁₉O₁₂*Na
• 分子量: 378.265
• InChiKey: HTYURTJUVASLSK-WZSFTPDYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -9.64
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  209
• 氢给体数：
  7
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  5-carboxy-cyclomaltoheptaose methyl ester 、 D-葡萄糖 在 cyclodextrin glucanotransferase 、 amyloglucosidase 作用下， 以 水 为溶剂， 反应 48.0h， 以96%的产率得到(sodium α-D-glucopyranosyluronate)-(1->4)-D-glucopyranose
  参考文献：
  名称：

  Chemoenzymatic synthesis of 6ω-modified maltooligosaccharides from cyclodextrin derivatives

  摘要：

  Regioselectively substituted maltooligosaccharides were prepared by enzymatic transformation of modified cyclodextrins by using simultaneously two different enzymes: cyclodextrin glucanotransferase (CGTase) and amyloglucosidase. Oligosaccharides were obtained in very good yields and their structures were identified by ID and 2D NMR spectroscopy. These results provided new information about the specificity of the catalytic sites of CGTase and amyloglucosidase. They also offered new ways for the synthesis of regioselectively modified maltooligosaccharides. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2005.06.005