N,N'-bis(2,6-diisopropylphenyl)-1,7-diphenoxyperylene-3,4,9,10-tetracarboxy diimide

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-bis(2,6-diisopropylphenyl)-1,7-diphenoxyperylene-3,4,9,10-tetracarboxy diimide
• 英文别名: 7,18-Bis[2,6-di(propan-2-yl)phenyl]-11,22-diphenoxy-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-6,8,17,19-tetrone；7,18-bis[2,6-di(propan-2-yl)phenyl]-11,22-diphenoxy-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-6,8,17,19-tetrone
• 化学式: C₆₀H₅₀N₂O₆
• 分子量: 895.067
• InChiKey: PYMNHZJKKPUVCU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.4
• 重原子数：
  68
• 可旋转键数：
  10
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  93.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-bis(2,6-diisopropylphenyl)-1,7-diphenoxyperylene-3,4,9,10-tetracarboxy diimide 在 硫酸 作用下， 反应 15.0h， 以94%的产率得到N,N′-bis(2,6-diisopropylphenyl)-1,7-di-[(4-sulfuric acid)phenoxy]perylene-3,4,9,10-tetracarboxy diimide
  参考文献：
  名称：

  迈向高荧光和水溶性per染料。

  摘要：

  提出了一种系统化的方法来制备高度荧光的水溶性per 3,4：9,10-四羧酸二酰亚胺发色团。首先通过将四个亲水性取代基连接到the染料的海湾区域上来引入水溶性。然后将带正电和带负电的基团应用于发色团，并系统地改变它们的数目和与芳香族支架的距离。为了抑制聚集，将生色团进一步分离在树突状壳内。此类结构特征的变化以及对所得光学性质的透彻研究促进了combining 3,4：9,10-四羧酸二酰亚胺的首次合成，结合了水溶性和荧光量子产率（FQYs）接近于1的特性，

  DOI：

  10.1002/chem.200400291
• 作为产物：
  描述：

  1,7-二溴-3,4,9,10-苝四羧基双酐 在 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 、 丙酸 为溶剂， 反应 25.0h， 生成 N,N'-bis(2,6-diisopropylphenyl)-1,7-diphenoxyperylene-3,4,9,10-tetracarboxy diimide
  参考文献：
  名称：

  荧光染料的合成，表征及其在提高小球藻生长速率中的应用

  摘要：

  太阳辐射从绿色到红色的光谱转换可以提高微藻的光合作用效率。这可以导致微藻生长的显着增加。合成了四种per基荧光染料，可将光的波长从绿色（500-570 nm）转换为橙红色（580-650 nm）。使用两种方法将这些染料应用于微藻培养系统：（1）光转换层，和（2）光转换介质。将染料溶解在乙醇或水中，以在微藻培养物和光源之间形成光转换层。在两种设置下的转换光下，普通绿藻与对照相比，培养物显示出脂质生产率最大增加了13.00％和17.15％，生物质生产率增加了31.65％和37.66％。总的来说，培养结果证实了改良光对微藻培养物的脂质和生物量生产力的有益影响。注意，两个生长参数在光转换介质中均实现了较高的性能，从而验证了该培养方法的有效性。

  DOI：

  10.1016/j.dyepig.2018.05.003

文献信息

• The synthesis and characterisation of the perylene acid dye inks for digital textile printing
  作者：Sol Choi、Kwan Hyun Cho、Jin Woong Namgoong、Jeong Yun Kim、Eui Sang Yoo、Woosung Lee、Jae Woong Jung、Jun Choi

  DOI：10.1016/j.dyepig.2018.12.002

  日期：2019.4

  Five perylene acid dyes were synthesized to manufacture water-based inks for the high-speed ink jet printing process, including digital textile printing. All the synthesized perylene dyes exhibited superior stability and optical properties compared to a commercially used azo dye. Their water solubility was efficiently enhanced by introducing bulky and hydrophilic substituents to ensure excellent long-term

  合成了五种per酸染料，以制造用于高速喷墨印刷工艺（包括数字纺织品印刷）的水性油墨。与市售的偶氮染料相比，所有合成的per染料均表现出优异的稳定性和光学性能。通过引入庞大和亲水的取代基可有效提高其水溶性，以确保在配制为水性油墨时具有出色的长期稳定性。带有这些per染料的水性油墨具有出色的印刷清晰度，其颜色不同于现有数字纺织印花油墨的基本颜色组成。当在商用喷墨印刷机中使用时，它们还表现出良好的喷射性能，并有助于进行良好控制的图案印刷。
• Compensation Film and Organic Dot for Compensation Film
  申请人：TORAY CHEMICAL KOREA INC.

  公开号：US20160272884A1

  公开（公告）日：2016-09-22

  The present invention relates to a novel organic dot for a compensation film and a compensation film using the same, and an organic dot of the present invention relates to a new material which not only can replace existing quantum dots (QDs), but also can improve color reproduction power regarding R (red) and G (green) and can enhance optical properties of materials such as LCD efficiency, color reproducibility and the like.

  本发明涉及一种用于补偿膜的新型有机点和使用该有机点的补偿膜，本发明的有机点涉及一种新材料，不仅可以取代现有的量子点（QDs），还可以改善对R（红色）和G（绿色）的色彩再现能力，并且可以增强LCD效率、色彩再现性等材料的光学性能。
• 발광색 변환 조성물, 발광색 변환 유닛 및 이를 이용한 백라이트 유닛
  申请人：Toray Chemical Korea Inc. 도레이케미칼 주식회사(119980034698) Corp. No ▼ 174811-0000151BRN ▼515-81-00097

  公开号：KR20160079375A

  公开（公告）日：2016-07-06

  본 발명은 발광색 변환 조성물 및 이를 이용한 발광색 변환 유닛에 관한 것으로서, 좀 더 구체적으로 설명하면, 카드뮴 등으로 인해 환경오염 문제가 대두되고 있는 양자점이 아닌, 단분자 형태의 2종의 유기닷을 사용한 발광색 변환 조성물, 이를 이용하여 제조한 발광색 변환 유닛에 관한 것이다.

  本发明涉及荧光颜色转换组合物及其用于荧光颜色转换单元，更具体地说，涉及使用两种单分子有机点而非因镉等造成环境污染问题的量子点的荧光颜色转换组合物，以及由此制备的荧光颜色转换单元。
• Synthesis and characterization of some perylene dyes for dye-based LCD color filters
  作者：Jun Choi、Chun Sakong、Jae-Hong Choi、Chun Yoon、Jae Pil Kim

  DOI：10.1016/j.dyepig.2010.11.006

  日期：2011.7

  Eight red perylene dyes were synthesized to improve the optical performance of LCD color filters. Among them, dyes with bulky functional substituents at the bay and terminal positions were highly soluble in cyclohexanone, the industrial solvent currently used in the pigment dispersion method. The spectral properties and thermal stability of the dye-based color filters with these dyes were examined by comparing them with pigment-based ones. The prepared color filters exhibited superior spectral properties due to the smaller particle size of the dyes, which led to less light scattering. However, their thermal stability varied with the dye structures, and only the dyes mono-substituted at the bay position had sufficient thermal stability. (C) 2010 Elsevier Ltd. All rights reserved.
• Synthesis and Optical Properties of Triphenylene-Based Dendritic Donor Perylene Diimide Acceptor Systems
  作者：Mahuya Bagui、Tanmoy Dutta、Sanjiban Chakraborty、Joseph S. Melinger、Haizhen Zhong、Andrew Keightley、Zhonghua Peng

  DOI：10.1021/jp1085334

  日期：2011.3.10

  A donor-acceptor charge transfer system based on two discotic mesogens has been synthesized. The donor is either a triphenylene (POG0) or a triphenylene-based conjugated dendron (POG1), while the acceptor is a perylene diimide (PDI) core. The donors are covalently linked to the bay positions of the PDI core through an ether linkage. In chloroform, due to the short donor-acceptor distance and the matching frontier orbital levels, photoinduced charge transfer from either the donor excitation or the acceptor excitation are both thermodynamically and kinetically favored, resulting in efficient quenching of both donor and acceptor fluorescence. In a less polar solvent, hexane, while charge transfer is still the dominant mechanism for decay of the excited electronic state of POG1, photo induced charge transfer is no longer energetically favorable for POG0 when the acceptor PDI core is excited, making the PDI core of POG0 weakly fluorescent in chloroform but strongly so in hexane. In solid film, POGO is highly aggregated through both PDI-PDI and triphenylene-triphenylene homotopic stacking. POG1, on the other hand, aggregates through triphenylene dendrons with limited PDI-PDI core stacking, presumably due to the steric hindrance caused by bulky triphenylene moieties which block the access to the PDI core. The efficient photoinduced charge transfer, coupled with the homotopic stacking that forms separated electron-transporting PDI-stacked columns and hole transporting triphenylene-stacked columns, suggests that the reported donor-acceptor systems based on dual-discotic mesogens are potentially new efficient photovoltaic materials.