dihexyltartaric acid

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羟基酸及其衍生物
• 英文名称: dihexyltartaric acid
• 英文别名: 2,3-Dihexyl-2,3-dihydroxybutanedioic acid
• 化学式: C₁₆H₃₀O₆
• 分子量: 318.411
• InChiKey: LUVSZKNQKSCFQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  22
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  115
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-氧代辛酸 以 水 为溶剂， 生成 dihexyltartaric acid 、 methylhexyltartaric acid 、 丙酮酸
  参考文献：
  名称：

  Photoinitiated Synthesis of Self-Assembled Vesicles

  摘要：

  The aqueous photochemistry of 2-oxooctanoic acid (a single-tailed surfactant) results in the synthesis of a double-tailed surfactant product followed by spontaneous self-assembly into vesicles. The photochemical mechanism is detailed here, and the reaction products are identified using mass spectrometry. Then, the self-assembled vesicles are characterized using dynamic light scattering, fluorescence microscopy, and NMR. Further, their stability over time and in the presence of MgCl2 salt is demonstrated. This work contributes to membrane evolution through the provision of a prebiotic route for the synthesis of plausible membrane components and subsequent self-assembly of a primitive enclosure.

  DOI：

  10.1021/ja5006256

文献信息

• Tartaric acid diesters as biogradable surfactants
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP1142963A1

  公开（公告）日：2001-10-10

  This invention provides water-based compositions which are essentially free of hydrocarbon solvents, particularly coating, ink, fountain solution, adhesive and agricultural compositions, manifesting reduced equilibrium and dynamic surface tension by the incorporation of a surface tension reducing amount of certain tartrate diester compounds of the structure where R1 and R2 are C4 to C6 alkyl groups.

  本发明提供了基本上不含烃类溶剂的水基组合物，特别是涂料、油墨、润版液、粘合剂和农用组合物，通过加入一定量的可降低表面张力的某些酒石酸二酯化合物，可降低平衡和动态表面张力，其结构为 其中 R1 和 R2 为 C4 至 C6 烷基。
• Tartaric acid diesters as biodegradable surfactants
  申请人：——

  公开号：US20030008943A1

  公开（公告）日：2003-01-09

  This invention provides water-based compositions which are essentially free of hydrocarbon solvents, particularly coating, ink, fountain solution, adhesive and agricultural compositions, manifesting reduced equilibrium and dynamic surface tension by the incorporation of a surface tension reducing amount of certain tartrate diester compounds of the structure 1 where R 1 and R 2 are C4 to C6 alkyl groups.

  本发明提供了基本上不含烃类溶剂的水基组合物，特别是涂料、油墨、润版液、粘合剂和农用组合物，通过加入一定量的降低表面张力的结构式酒石酸二酯化合物，可以降低平衡和动态表面张力。 1 其中 R 1 和 R 2 为 C4 至 C6 烷基。
• Use of tartaric acid diesters as biodegradable surfactants
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP1142963B1

  公开（公告）日：2006-03-15
• US6423376B1
  申请人：——

  公开号：US6423376B1

  公开（公告）日：2002-07-23
• US6544591B2
  申请人：——

  公开号：US6544591B2

  公开（公告）日：2003-04-08