2-(benzyl-methyl-amino)-1-(3-nitro-phenyl)-ethanone

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(benzyl-methyl-amino)-1-(3-nitro-phenyl)-ethanone
• 英文别名: 2-(Benzyl-methyl-amino)-1-(3-nitro-phenyl)-aethanon；2-[Benzyl(methyl)amino]-1-(3-nitrophenyl)ethanone
• 化学式: C₁₆H₁₆N₂O₃
• mdl: MFCD22121789
• 分子量: 284.315
• InChiKey: ZADCPLIIVUWMDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.187
• 拓扑面积：
  66.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-(benzyl-methyl-amino)-1-(3-nitro-phenyl)-ethanone 在 甲醇 、 镍 作用下， 生成 1-(3-amino-phenyl)-2-(benzyl-methyl-amino)-ethanone
  参考文献：
  名称：

  Comparison of sensory differences of stored Russet Burbank potatoes treated with CIPC and alternative sprout inhibitors

  摘要：

  The sensory properties of Russet Burbank potatoes treated with three naturally occurring volatile compounds, as alternatives to CIPC for sprout inhibition, were evaluated. Potatoes from the 1995 and 1996 crop years were treated with salicylaldehyde, 1,8-cineole, 1,4-dimethylnaphthalene, or CIPC prior to dormancy break during storage and stored for up to 16 wk. Sensory differences between potatoes treated with alternative sprout inhibitors and CIPC-treated or untreated potatoes and inhibitor concentration were determined at 2-wk intervals. Potatoes treated with 1,8-cineole or salicylaldehyde, but not I,4-dimethylnaphthalene, were significantly different from the untreated potatoes or potatoes treated with CIPC. Sensory detection threshold levels for the alternative inhibitors were measured in a model potato system. The residual levels of the sprout inhibitors were within the detection threshold range for 1,8-cineole (0.02-0.04 ppm), but not for salicylaldehyde (0.09-0.10 ppm) or 1,4-dimethylnaphthalene (0.80-1.40 ppm). The presence of the residual sprout inhibitors and/or the influence of sprout inhibitors on potato metabolism during storage contributed to observed differences in sensory quality of stored potatoes.

  DOI：

  10.1007/bf02874765
• 作为产物：
  描述：

  N-甲基苄胺 、 2-溴-3'-硝基苯乙酮 生成 2-(benzyl-methyl-amino)-1-(3-nitro-phenyl)-ethanone
  参考文献：
  名称：

  Comparison of sensory differences of stored Russet Burbank potatoes treated with CIPC and alternative sprout inhibitors

  摘要：

  The sensory properties of Russet Burbank potatoes treated with three naturally occurring volatile compounds, as alternatives to CIPC for sprout inhibition, were evaluated. Potatoes from the 1995 and 1996 crop years were treated with salicylaldehyde, 1,8-cineole, 1,4-dimethylnaphthalene, or CIPC prior to dormancy break during storage and stored for up to 16 wk. Sensory differences between potatoes treated with alternative sprout inhibitors and CIPC-treated or untreated potatoes and inhibitor concentration were determined at 2-wk intervals. Potatoes treated with 1,8-cineole or salicylaldehyde, but not I,4-dimethylnaphthalene, were significantly different from the untreated potatoes or potatoes treated with CIPC. Sensory detection threshold levels for the alternative inhibitors were measured in a model potato system. The residual levels of the sprout inhibitors were within the detection threshold range for 1,8-cineole (0.02-0.04 ppm), but not for salicylaldehyde (0.09-0.10 ppm) or 1,4-dimethylnaphthalene (0.80-1.40 ppm). The presence of the residual sprout inhibitors and/or the influence of sprout inhibitors on potato metabolism during storage contributed to observed differences in sensory quality of stored potatoes.

  DOI：

  10.1007/bf02874765

文献信息

• Sulfonanilides. I. Monoalkyl- and Arylsulfonamidophenethanolamines^1,2
  作者：Robert H. Uloth、Jerry R. Kirk、William A. Gould、A. A. Larsen

  DOI：10.1021/jm00319a023

  日期：1966.1
• Comparison of sensory differences of stored Russet Burbank potatoes treated with CIPC and alternative sprout inhibitors
  作者：Terri D. Boylston、Joseph R. Powers、Karen M. Weiler、Jian Yang

  DOI：10.1007/bf02874765

  日期：2001.3

  The sensory properties of Russet Burbank potatoes treated with three naturally occurring volatile compounds, as alternatives to CIPC for sprout inhibition, were evaluated. Potatoes from the 1995 and 1996 crop years were treated with salicylaldehyde, 1,8-cineole, 1,4-dimethylnaphthalene, or CIPC prior to dormancy break during storage and stored for up to 16 wk. Sensory differences between potatoes treated with alternative sprout inhibitors and CIPC-treated or untreated potatoes and inhibitor concentration were determined at 2-wk intervals. Potatoes treated with 1,8-cineole or salicylaldehyde, but not I,4-dimethylnaphthalene, were significantly different from the untreated potatoes or potatoes treated with CIPC. Sensory detection threshold levels for the alternative inhibitors were measured in a model potato system. The residual levels of the sprout inhibitors were within the detection threshold range for 1,8-cineole (0.02-0.04 ppm), but not for salicylaldehyde (0.09-0.10 ppm) or 1,4-dimethylnaphthalene (0.80-1.40 ppm). The presence of the residual sprout inhibitors and/or the influence of sprout inhibitors on potato metabolism during storage contributed to observed differences in sensory quality of stored potatoes.