二(十三烷基)富马酸酯 | 6864-32-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 二(十三烷基)富马酸酯
• 英文名称: Ditridecyl fumarate
• 英文别名: ditridecyl (E)-but-2-enedioate
• CAS: 6864-32-0
• 化学式: C₃₀H₅₆O₄
• 分子量: 480.8
• InChiKey: DFKBFBPHOGVNGQ-OCEACIFDSA-N

物化性质

• 沸点：
  230 °C(Press: 0.40 Torr)
• 密度：
  0.9050 g/cm3(Temp: 23 °C)
• 保留指数：
  3406

计算性质

• 辛醇/水分配系数(LogP)：
  12.5
• 重原子数：
  34
• 可旋转键数：
  28
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38
• 海关编码：
  2917190090

反应信息

• 作为反应物：
  描述：

  2-氯-1-(氯甲基)乙基氨基甲酸酯 、 二(十三烷基)富马酸酯 生成 1,3-dichloropropan-2-yl carbamate;ditridecyl (E)-but-2-enedioate
  参考文献：
  名称：

  Unsaturated polyoxyalkylene adduct/fumarate diester reaction product for

  摘要：

  聚氧烷表面活性剂用于制备细胞泡沫，可以通过在自由基聚合条件下反应（1）不饱和聚氧烷加合物和（2）酯化的不饱和二元酸成分来制备，其中不饱和二酯成分（2）可以完全或部分包含富马酸二酯。

  公开号：

  US04529745A1
• 作为产物：
  描述：

  反丁烯二酰氯 、 十三烷醇 、 三乙胺 以80%的产率得到
  参考文献：
  名称：

  DYMICKY, M.;BUCHANAN, R. L., ORG. PREP. AND PROCED. INT., 1985, 17, N 2, 121-131

  摘要：

  DOI：

文献信息

• Unsaturated polyoxyalkylene adduct/fumarate diester reaction product for cellular foam stabilization
  申请人：Sloss Industries Corporation

  公开号：EP0124111A2

  公开（公告）日：1984-11-07

  Polyoxyalkylene surfactants for cellular foams can be prepared by reacting under free radical polymerization conditions (1) an unsaturated polyoxyalkylene adduct and (2) an esterified unsaturated dibasic acid ingredient, wherein unsaturated diester ingredient (2) either completely or partially comprises a fumarate diester.

  用于蜂窝泡沫的聚氧亚烷基表面活性剂可通过在自由基聚合条件下使（1）不饱和聚氧亚烷基加合物和（2）酯化的不饱和二元酸成分反应制备，其中不饱和二元酸成分（2）完全或部分包括富马酸二元酯。
• Modified polyphenylene ether resins having improved processability and oxidative stability
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0257486A1

  公开（公告）日：1988-03-02

  The processability and resistance to oxidative degradation of polyphenylene ether resins, alone, or in combination with a styrene resin, is improved by includ­ing a modifier comprising an alpha, beta-unsaturated carboxylic acid or derivative. In an embodiment, the formation of a composition comprising a poly(2,6-di­methyl-1,4-phenylene ether) and 2 parts per hundred of dibutyl maleate results in a 26 percent improvement in spiral flow, and a 30 percent reduction in oxygen uptake at 115°C. enhancing the utility of polyphenylene ether resins as extrusion and injection molding materials.

  通过加入包含α、β-不饱和羧酸或衍生物的改性剂，可改善聚苯醚树脂单独或与苯乙烯树脂组合的加工性和抗氧化降解性。 在一个实施方案中，形成一种包含聚（2,6-二甲基-1,4-亚苯基醚）和百分之二马来酸二丁酯的组合物，可使螺旋流动性提高 26%，115°C 下的吸氧量降低 30%，从而提高了聚苯醚树脂作为挤出和注塑成型材料的实用性。
• Flow improvers and cloud point depressants
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0306290A1

  公开（公告）日：1989-03-08

  Additives suitable for improving the flow and/or depressing the cloud point of crude oils, lubricating oils and especially fuel oils are polymers containing defined alkyl groups of at least 8 carbon atoms chain length. Such polymers are either (a) of a mixture of monomers having only two alkyl groups one being at least 3 carbon atoms longer than the other or (b) of a mixture of monomers having only three alkyl groups each differing by at least 3 carbon atoms and the middle alkyl group being half the combined length of the other two. Alternatively, the polymer may be derived from a monomer having the two defined alkyl groups (a) or the three defined alkyl groups (b).

  适用于改善原油、润滑油，特别是燃料油的流动性和/或降低浊点的添加剂是含有至少 8 个碳原子链长的确定烷基的聚合物。这种聚合物可以是 (a) 单体的混合物，其中只有两个烷基，其中一个比另一个至少长 3 个碳原子；或者 (b) 单体的混合物，其中只有三个烷基，每个烷基至少相差 3 个碳原子，中间的烷基是另外两个烷基总长度的一半。或者，聚合物可以由具有两个定义的烷基（a）或三个定义的烷基（b）的单体衍生而来。
• Polymeric material for liquid crystal/polymer composite film, liquid crystal/polymer composite film, record display medium, and use thereof
  申请人：DAI NIPPON PRINTING CO., LTD.

  公开号：EP0790289A1

  公开（公告）日：1997-08-20

  A record display medium is provided which can offer a high display contrast and is less likely to cause a lowering of contrast or disappearance of display even in low temperature and high temperature regions. A polymeric material for a liquid crystal/polymer composite film comprising a liquid crystal present in a polymer matrix, a liquid crystal/polymer composite film using the material, and use of the record display medium are also provided. The polymeric material for a liquid crystal/polymer composite film comprising a liquid crystal present in a polymer matrix has a glass transition temperature of 150°C or above and is insoluble in water.

  本发明提供了一种记录显示介质，它能提供较高的显示对比度，即使在低温和高温区域也不易导致对比度降低或显示消失。本发明还提供了一种用于液晶/聚合物复合膜的聚合物材料，该材料包括存在于聚合物基质中的液晶、使用该材料的液晶/聚合物复合膜以及该记录显示介质的用途。用于液晶/聚合物复合膜的聚合物材料包含在聚合物基体中的液晶，其玻璃化转变温度为 150°C 或以上，并且不溶于水。
• Method of preparing vinyl chloride-based copolymer and vinyl chloride-based copolymer prepared thereby
  申请人：LG CHEM, LTD.

  公开号：US10287377B2

  公开（公告）日：2019-05-14

  The present invention relates to a method of preparing a vinyl chloride-based copolymer having excellent plasticity and processability, a vinyl chloride-based copolymer prepared thereby, a thermoplastic resin composition including the vinyl chloride-based copolymer, and a thermoplastic resin molded article prepared from the composition. Since the preparation method may improve copolymerizability with a vinyl chloride-based monomer by continuously adding or dividedly adding an unsaturated fatty acid ester mixture used as a comonomer during the time of specific polymerization conversion rate, the unreacted unsaturated fatty acid ester mixture may be reduced, and, as a result, the conversion rate of the vinyl chloride-based copolymer may be significantly improved. Thus, plasticity and processability of a vinyl chloride-based copolymer prepared by the above method may be significantly improved.

  本发明涉及一种具有优异可塑性和加工性的氯乙烯基共聚物的制备方法、由此制备的氯乙烯基共聚物、包括氯乙烯基共聚物的热塑性树脂组合物以及由该组合物制备的热塑性树脂模塑制品。由于该制备方法可通过在特定聚合转化率期间连续添加或分次添加用作共聚单体的不饱和脂肪酸酯混合物来改善与氯乙烯基单体的共聚性，因此可减少未反应的不饱和脂肪酸酯混合物，从而显著提高氯乙烯基共聚物的转化率。因此，通过上述方法制备的氯乙烯基共聚物的可塑性和加工性可得到明显改善。