二(十三烷基)亚磷酸氢酯 | 36432-46-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 中文名称: 二(十三烷基)亚磷酸氢酯
• 英文名称: phosphonic acid ditridecyl ester
• 英文别名: Phosphonsaeure-ditridecylester；Ditridecylphosphonat；1-Tridecoxyphosphonoyloxytridecane
• CAS: 36432-46-9
• 化学式: C₂₆H₅₅O₃P
• 分子量: 446.695
• InChiKey: BDZYUTQMWUWPLZ-UHFFFAOYSA-N

物化性质

• 沸点：
  515.5±19.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  30
• 可旋转键数：
  26
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  十三烷醇 在 三氯化磷 作用下， 生成 二(十三烷基)亚磷酸氢酯
  参考文献：
  名称：

  连续制备亚磷酸二烷基酯的方法

  摘要：

  DOI：

  10.1021/ie50575a033

文献信息

• RESIN COMPOSITION AND APPLICATION THEREOF
  申请人：Kureha Corporation

  公开号：US20150225545A1

  公开（公告）日：2015-08-13

  The object of the present invention is to provide a resin composition that contains a near-infrared absorbent in which heat-induced discoloration is suppressed, and the resin composition is a resin composition made from a near-infrared absorbent, an antioxidant, and a resin, wherein the near-infrared absorbent is a particulate made from copper phosphonate represented by Formula (1) (wherein, R1 is a group represented by —CH2CH2-R11, and R11 indicates a hydrogen atom, an alkyl group, or an alkyl fluoride group)), and the antioxidant is at least one type selected from hindered phenol-based antioxidants and phosphorous-based antioxidants having not less than one structure represented by Formula (2) (wherein, R2 to R4 indicate alkyl groups and R5 to R8 indicate hydrogen atoms or alkyl groups.) bonded to a phosphorous atom in the molecule, and not having a structure represented by Formula (3) (wherein, R indicates an alkyl group.) bonded to the phosphorous atom in the molecule.

  本发明的目的是提供一种含有近红外吸收剂的树脂组合物，其中抑制热引起的变色，所述树脂组合物由近红外吸收剂、抗氧化剂和树脂组成，所述近红外吸收剂是由式（1）表示的磷酸铜颗粒制成（其中R1是表示为—CH2CH2-R11的基团，R11表示氢原子、烷基或烷基氟化物基团），所述抗氧化剂是至少选择一种基于受阻酚的抗氧化剂和磷酸盐的抗氧化剂，其分子中具有不少于一个式（2）表示的结构（其中R2至R4表示烷基，R5至R8表示氢原子或烷基），并且不具有式（3）表示的结构（其中R表示烷基）与分子中的磷原子结合。
• Derivatives of triazoles as load-carrying additives for gear oils
  申请人：MOBIL OIL CORPORATION

  公开号：EP0001491A1

  公开（公告）日：1979-04-18

  Load-carrying properties of gear oils are increased by the addition of triazole derivatives obtained by reacting benzotriazole or an alkylbenzotriazole with alkylphosphates. alkylphosphonates or primary fatty amines, a napthenyl oxazoline or an alkenylsuccinyl mono- or bis-oxazoline.

  通过添加苯并三唑或烷基苯并三唑与烷基磷酸盐、烷基膦酸盐或伯胺、环烷基噁唑啉或烯基琥珀酰基单噁唑啉或双噁唑啉反应而得到的三唑衍生物，可提高齿轮油的承载性能。
• Oil additive concentrates and lubricants of enhanced performance capabilities
  申请人：ETHYL PETROLEUM ADDITIVES LIMITED

  公开号：EP0531585A1

  公开（公告）日：1993-03-17

  Additive concentrates, lubricating oil compositions and the use thereof are described. The compositions comprise one or more of each of the following oil-soluble additive components: a) a Mannich base ashless dispersant; b) a metal-free sulphur-containing antiwear and/or extreme pressure agent; c) a metal-free phosphorus-containing and nitrogen-containing antiwear and/or extreme pressure agent; and optionally but preferably, d) an amine salt of a carboxylic acid. Oils containing such additive components exhibit excellent performance under heavy duty service such as in the planetary spur gear test. In addition, such oils exhibit good demulsibility in the ASTM D1401 test procedure and good clean gear performance in the CRC L-60 test.

  本文描述了添加剂浓缩物、润滑油组合物及其用途。这些组合物包含以下每种油溶性添加剂成分中的一种或多种：a) 曼尼希基无灰分散剂；b) 不含金属的含硫抗磨剂和/或极压剂；c) 不含金属的含磷和含氮抗磨剂和/或极压剂；以及可选但最好是 d) 羧酸胺盐。含有此类添加剂成分的机油在重负荷工作（如行星直齿轮试验）中表现出卓越的性能。此外，此类润滑油在 ASTM D1401 试验程序中表现出良好的抗乳化性，在 CRC L-60 试验中表现出良好的清洁齿轮性能。
• Ashless dispersants formed form substituted acylating agents and their production and use
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0545653A1

  公开（公告）日：1993-06-09

  Succinic ester-amides are formed by (A) reacting (i) at least one substantially aliphatic polymer of at least one lower olefin, and (ii) an acidic reactant or a mixture of two or more acidic reactants represented by the general formula         R-CO-CH = CH-CO-R′ wherein R and R′ are independently -OH, -O-lower alkyl, a halogen atom, or taken together are a single oxygen atom; the process being characterized in that: a) the substantially aliphatic polymer is comprised predominantly or entirely of polyisobutene, at least 50% of the polyisobutene content of such polymer having an end group represented by the formula b) the mole ratio of said acidic reactant(s) : said polymer(s) is at least 1 : 1; c) the reaction mixture is maintained under superatmospheric pressure during at least a substantial portion of the reaction period; and d) said acylating agent is characterized by having an average total tar rating as determined by the method described in the specification hereof that is at least 25% lower than the average total tar rating of a corresponding product made in the same way under the same reaction conditions using a polyisobutene containing up to 10% of the above-depicted end group; and (B) reacting such acylating agent with at least one alcohol (preferably a polyhydric alcohol) and amine (preferably a polyamine having at least one primary amino group). Combinations of succinimides, succinic esters, and succinic ester-amides formed using such acylating agents are used in combination with other additives in forming lubricant compositions.

  琥珀酸酯酰胺是通过以下反应形成的：(A)(i)至少一种低级烯烃的实质上脂肪族聚合物，和(ii)一种酸性反应剂或两种或两种以上酸性反应剂的混合物，其通式为 R-CO-CH = CH-CO-R′ 其中 R 和 R′独立地为-OH、-O-低级烷基、卤素原子或合在一起为单个氧原子；该工艺的特征在于 a) 基本脂肪族聚合物主要或全部由聚异丁烯组成，该聚合物中至少 50% 的聚异丁烯含量具有由式表示的端基 b) 所述酸性反应剂与所述聚合物的摩尔比至少为 1:1； c) 至少在反应期间的大部分时间内，反应混合物保持在超大气压下；以及 d) 所述酰化剂的特点是，其平均总焦油等级（按本说明书所述方法测定）比在相同反应条件下用含有最多 10%上述端基的聚异丁烯以相同方法制得的相应产品的平均总焦油等级至少低 25%；以及 (A) 所述酸性反应剂与所述聚合物的摩尔比至少为 1:1。 (B) 使这种酰化剂与至少一种醇（最好是多羟基醇）和胺（最好是具有至少一个伯氨基 的多胺）反应。使用此类酰化剂形成的琥珀酰亚胺、琥珀酸酯和琥珀酸酯-酰胺组合可与其他添加剂一起用于形成润滑剂组合物。
• Polyvinyl chloride based resin composition and products derived therefrom
  申请人：SEKISUI AMERICA CORPORATION

  公开号：EP0708143A1

  公开（公告）日：1996-04-24

  A blended polyvinyl chloride based resin composition consisting essentially of 100 parts by weight of a vinyl chloride resin has a chlorine content of from about 50 to about 73 percent by weight, from about 5 to about 12 parts by weight of a flame-retarding agent and from about 1 to about 30 parts by weight of a graft polymer. The blended vinyl chloride based resin composition and products derived therefrom exhibit improved flame-retarding and heat tolerance properties. The blended resin composition and its products also exhibit improved vacum moldability and increased impact resistance. In particular, the blended resin composition and its products emit substantially less smoke and less toxic fumes containing hydrogen chloride. A method to produce the blended vinyl chloride based resin composition including a method of processing moldings by thermoforming is also disclosed.

  一种以聚氯乙烯为基础的混合树脂组合物主要由 100 重量份的氯乙烯树脂、约 5 至约 12 重量份的阻燃剂和约 1 至约 30 重量份的接枝聚合物组成，其氯含量约为 50%至约 73%。混合的氯乙烯基树脂组合物及其产品具有更好的阻燃性和耐热性。混合树脂组合物及其产品还具有更好的真空模塑性和更强的抗冲击性。特别是，混合树脂组合物及其产品排放的烟雾和含有氯化氢的有毒烟雾大大减少。此外，还公开了一种生产氯乙烯基混合树脂组合物的方法，包括一种通过热成型加工模具的方法。

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