6-acetoxy-3-ethoxy-2-methyl-2-cyclohexenone

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6-acetoxy-3-ethoxy-2-methyl-2-cyclohexenone
• 英文别名: 2-Cyclohexen-1-one, 6-(acetyloxy)-3-ethoxy-2-methyl-；(4-ethoxy-3-methyl-2-oxocyclohex-3-en-1-yl) acetate
• 化学式: C₁₁H₁₆O₄
• 分子量: 212.246
• InChiKey: LQKLTDMHSPLCRX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-乙氧基-2-甲基-2-环己烯-1-酮 、 manganese triacetate 、 苯 反应 12.0h， 以59%的产率得到6-acetoxy-3-ethoxy-2-methyl-6-phenyl-2-cyclohexenone
  参考文献：
  名称：

  Manganese(III) acetate based tandem oxidation of various α and β-alkoxy α,β-unsaturated ketones

  摘要：

  We described the unusual results of manganese(III) acetate based tandem oxidation of various alpha and beta-alkoxy alpha,beta-unsaturated ketones to afford the corresponding alpha'-acetoxy-alpha'-phenyl substituted oxidation products in good yields. The tandem oxidation to monoacetoxylation ratio can be tuned by the amount of manganese(III) acetate. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(02)01350-9

文献信息

• Manganese(III) acetate based tandem oxidation of various α and β-alkoxy α,β-unsaturated ketones
  作者：Cihangir Tanyeli、Devrim Özdemirhan、Bengü Sezen

  DOI：10.1016/s0040-4020(02)01350-9

  日期：2002.12

  We described the unusual results of manganese(III) acetate based tandem oxidation of various alpha and beta-alkoxy alpha,beta-unsaturated ketones to afford the corresponding alpha'-acetoxy-alpha'-phenyl substituted oxidation products in good yields. The tandem oxidation to monoacetoxylation ratio can be tuned by the amount of manganese(III) acetate. (C) 2002 Elsevier Science Ltd. All rights reserved.