γ-terpinyl methyl ether

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: γ-terpinyl methyl ether
• 英文别名: 1-(Methoxymethyl)-4-propan-2-ylcyclohexa-1,4-diene；1-(methoxymethyl)-4-propan-2-ylcyclohexa-1,4-diene
• 化学式: C₁₁H₁₈O
• 分子量: 166.263
• InChiKey: JMPXWFHQYIWTFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  甲醇 、 beta-pinene 在 Iron(III) nitrate nonahydrate 、 氧气 作用下， 55.0 ℃ 、100.0 kPa 条件下， 反应 8.0h， 生成 松油烯 、 γ-松油烯 、 α-terpinyl methyl ether 、 γ-terpinyl methyl ether 、 myrtenol methyl ether
  参考文献：
  名称：

  A novel Fe(III) salt-catalyzed monoterpene aerobic oxidation in methyl alcohol

  摘要：

  The Fe(III)-catalyzed aerobic oxidation of monoterpenes in CH3OH has been developed, in which simple Fe(III) salts are used as catalysts in the absence of stabilizing ligands. Remarkably, Fe(NO3)(3) catalyst efficiently promotes the oxidation of monoterpenes under air or dioxygen. The highest TON and TOF reached 476 and 162 h(-1), respectively. In general, reactions with 1.0-9.0 mol% of catalyst reached high conversions (ca. 90-99%) and high oxidation products selectivity (ca. 80%). Notably, alpha-pinene and beta-pinene were selectively oxidized into only allylic product, myrtenol methyl ether. The significant breakthroughs of this simple oxidative process are the use of inexpensive Fe(III) salts as catalysts and environmentally-friendly oxidants (air or dioxygen). (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2013.08.018

文献信息

• A novel Fe(III) salt-catalyzed monoterpene aerobic oxidation in methyl alcohol
  作者：Fabiano Gomes Ferreira de Paula、Lilian Berllini、Márcio José da Silva

  DOI：10.1016/j.catcom.2013.08.018

  日期：2013.12

  The Fe(III)-catalyzed aerobic oxidation of monoterpenes in CH3OH has been developed, in which simple Fe(III) salts are used as catalysts in the absence of stabilizing ligands. Remarkably, Fe(NO3)(3) catalyst efficiently promotes the oxidation of monoterpenes under air or dioxygen. The highest TON and TOF reached 476 and 162 h(-1), respectively. In general, reactions with 1.0-9.0 mol% of catalyst reached high conversions (ca. 90-99%) and high oxidation products selectivity (ca. 80%). Notably, alpha-pinene and beta-pinene were selectively oxidized into only allylic product, myrtenol methyl ether. The significant breakthroughs of this simple oxidative process are the use of inexpensive Fe(III) salts as catalysts and environmentally-friendly oxidants (air or dioxygen). (C) 2013 Elsevier B.V. All rights reserved.