Treatment of Pri2P(O)Cl with Me3SiNHOSiMe3 gives Pri2P(O)NHOSiMe3, which is desilylated by methanol giving Pri2P(O)NHOH. The O-p-nitrobenzenesulphonyl derivative of this rearranges with KOBut in ButOH, an isopropyl group migrating from P to N and the phosphonamidate PriP(O)(OBut)NHPri being formed quantitatively. Rearrangement also occurs in other alcohols (MeOH, EtOH, PriOH), but not quite as cleanly
用Me 3 SiNHOSiMe 3处理Pr i 2 P(O)Cl产生Pr i 2 P(O)NHOSiMe 3,其被
甲醇甲
硅烷基化,得到Pr i 2 P(O)NHOH。所述ø - p此重排用的甲部衍
生物-nitrobenzenesulphonyl吨在卜吨OH,异丙基迁移从P到N和
镨的
磷酰胺酯我P(O)(OBU吨)NHPr我被定量地形成。重排也发生在其他的醇(
甲醇,
乙醇,
镨我OH),但不是很干净。在卜Ť NH2所述phOSphinoylhydrazine
镨我2 P(O)NHNHBu吨形成以及重排产物,
镨我P(O)(NHBu吨)NHPr我。与Me 3 SiNHOSiMe 3相似地制备的Et 2 P(O)NHOH和Pr i MeP(O)NHOH的对
硝基苯磺酰基衍
生物也与Bu t OH-KOBu t进行了定量重排。在后一种情况下,两个烷基(Pr i和Me)的迁移能力几乎相同。