5-isopropyldibenzo[b,f]azepine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯氮卓类
• 英文名称: 5-isopropyldibenzo[b,f]azepine
• 英文别名: 11-Propan-2-ylbenzo[b][1]benzazepine
• 化学式: C₁₇H₁₇N
• 分子量: 235.329
• InChiKey: SDLIQEZDTKGCNQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-溴甲基苯 、 5-isopropyldibenzo[b,f]azepine 在 PdCl(C₃H₅)(dppb) 、 potassium acetate 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 15.0h， 以84%的产率得到5-isopropyl-10-(m-tolyl)dibenzo[b,f]azepine
  参考文献：
  名称：

  通过钯催化的CH键断裂可方便地获得C10和C11（二）芳基化的二苯并[b，f] a

  摘要：

  据报道，条件允许通过连续的钯催化反应使二苯并[ b，f ] a庚烷发生C10-和C11-芳基化。使用芳基溴化物作为芳基来源，二苯并[ b，f ]氮杂环庚烷的C10芳基化反应具有很高的选择性。然后，使用苯磺酰氯作为芳基源，在C11位进行第二次芳基化反应，得到不对称的C10，C11二芳基化二苯并[ b，f ]氮杂。两种反应均能耐受芳基源上的各种取代基。

  DOI：

  10.1002/adsc.201801366
• 作为产物：
  描述：

  2-碘代丙烷 、 亚氨基芪 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 18.0h， 以72%的产率得到5-isopropyldibenzo[b,f]azepine
  参考文献：
  名称：

  通过钯催化的CH键断裂可方便地获得C10和C11（二）芳基化的二苯并[b，f] a

  摘要：

  据报道，条件允许通过连续的钯催化反应使二苯并[ b，f ] a庚烷发生C10-和C11-芳基化。使用芳基溴化物作为芳基来源，二苯并[ b，f ]氮杂环庚烷的C10芳基化反应具有很高的选择性。然后，使用苯磺酰氯作为芳基源，在C11位进行第二次芳基化反应，得到不对称的C10，C11二芳基化二苯并[ b，f ]氮杂。两种反应均能耐受芳基源上的各种取代基。

  DOI：

  10.1002/adsc.201801366

文献信息

• SILYL-BIARYL PHOSPHORAMIDITES AND METHODS OF MAKING
  申请人：Board of Regents, The University of Texas System

  公开号：US20220002328A1

  公开（公告）日：2022-01-06

  The present disclosure provides compounds that may be used as ligands in metal-catalyzed reactions, in particular 3,3′-bisilyl biaryl phosphoramidite compounds and processes for preparing the same.

  本公开提供了可用作金属催化反应中配体的化合物，特别是3,3'-双硅基联苯磷酰胺化合物以及其制备方法。
• NOVEL COMPOUNDS FOR ORGANIC ELECTRONIC MATERIAL AND ORGANIC ELECTRONIC DEVICE USING THE SAME
  申请人：Shin Hyo-Nim

  公开号：US20120104940A1

  公开（公告）日：2012-05-03

  The present invention relates to novel compounds for organic electronic material, and organic electronic devices and organic solar cells using the same. The compounds for organic electronic material may be included in a hole transport layer, electron transport layer or hole injection layer, or may be used as host or dopant. With good luminous efficiency and excellent life property of the material, they may be used to manufacture OLEDs having very good operation life.

  本发明涉及用于有机电子材料的新化合物，以及使用它们的有机电子器件和有机太阳能电池。这些用于有机电子材料的化合物可以包含在空穴输运层、电子输运层或空穴注入层中，也可以用作宿主或掺杂剂。由于该材料具有良好的发光效率和优异的寿命特性，它们可以用于制造具有非常好的操作寿命的OLED。
• Novel organic electroluminescent compounds and organic electroluminescent device using the same
  申请人：Shin Hyo Nim

  公开号：US20090260686A1

  公开（公告）日：2009-10-22

  The present invention relates to novel organic electroluminescent compounds, and organic electroluminescent devices employing the same as electroluminescent material. Specifically, the organic electroluminescent compounds according to the invention are characterized in that they are represented by Chemical Formula (1): wherein, A and B independently represent CR 7 or N, provided that both A and B cannot be CR 7 or N at the same time; and X is O or S. Since the organic electroluminescent compounds according to the invention have good luminous efficiency and excellent color purity and life property of material, OLED's having very good operation life can be manufactured therefrom.
• Novel compounds for electronic material and organic electronic device using the same
  申请人：Lee Mi Ae

  公开号：US20090288707A1

  公开（公告）日：2009-11-26

  The present invention relates to novel compounds for electronic material, and organic electroluminescent devices or organic solar cells comprising the same. Specifically, the compounds for electronic material according to the invention are characterized in that they are represented by Chemical Formula ( 1 ): Since the compounds for electronic material, when being applied to an organic electroluminescent device, show good luminous efficiency and excellent life property of material, OLED's having very good operation life can be manufactured therefrom.
• Novel organic electroluminescent compounds and organic electroluminescent device using the same
  申请人：Eum Sung Jin

  公开号：US20100033083A1

  公开（公告）日：2010-02-11

  Provided are novel organic electroluminescent compounds, and organic electroluminescent devices and organic solar cells employing the same. Specifically, the organic electroluminescent compounds according to the invention are characterized in that they are represented by Chemical Formula (1): wherein, A, B, C and D independently represent CR 5 or N, provided that A, B, C and D cannot represent CR 5 all at the same time. Since the organic electroluminescent compounds according to the invention have good luminous efficiency and excellent color purity and life property of material, OLED's having very good operation life can be manufactured therefrom.