1-phenyl-2-salicyloyloxy-propan-1-one

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-phenyl-2-salicyloyloxy-propan-1-one
• 英文别名: 1-Phenyl-2-salicyloyloxy-propan-1-on；(1-Oxo-1-phenylpropan-2-yl) 2-hydroxybenzoate
• 化学式: C₁₆H₁₄O₄
• 分子量: 270.285
• InChiKey: LHAJPIQNUIWDFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  sodium salicylate 、 alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 作用下， 生成 1-phenyl-2-salicyloyloxy-propan-1-one
  参考文献：
  名称：

  Weksler, Zhurnal Obshchei Khimii, 1955, vol. 25, p. 1586,1589; engl. Ausg. S. 1545, 1547

  摘要：

  DOI：

文献信息

• (Cycloalkyl) methyl silanes as external donors for polyolefin catalysts
  申请人：——

  公开号：US20020028893A1

  公开（公告）日：2002-03-07

  One aspect of the present invention relates to a catalyst system for use in olefinic polymerization, containing a solid titanium catalyst component; an organoaluminum compound having at least one aluminum-carbon bond; and an organosilicon compound comprising a (cycloalkyl)methyl group. Another aspect of the present invention relates to a method of making a catalyst for use in olefinic polymerization, involving the steps of reacting a Grignard reagent having a (cycloalkyl)methyl group with an orthosilicate to provide an organosilicon compound having a (cycloalkyl)methyl moiety; and combining the organosilicon compound with an organoaluminum compound having at least one aluminum-carbon bond and a solid titanium catalyst component to form the catalyst.

  本发明的一个方面涉及用于烯烃聚合的催化剂体系，包含固体钛催化剂组分；至少具有一个铝-碳键的有机铝化合物；以及包含一个（环烷基）甲基基团的有机硅化合物。本发明的另一个方面涉及一种制备用于烯烃聚合的催化剂的方法，包括以下步骤：将具有（环烷基）甲基基团的格氏试剂与正硅酸盐反应，以提供具有（环烷基）甲基基团的有机硅化合物；并将有机硅化合物与至少具有一个铝-碳键的有机铝化合物和固体钛催化剂组分结合，形成催化剂。
• Spherical catalyst for olefin polymerization
  申请人：Zhu Zhidong

  公开号：US20050164873A1

  公开（公告）日：2005-07-28

  Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of an olefin containing a solid titanium catalyst component having a substantially spherical shape and containing a titanium compound and a support made from a magnesium compound and an alkyl silicate. The catalyst system may further contain an organoaluminum compound and an organosilicon compound. Also disclosed are methods of making an impact copolymer involving polymerizing an olefin to provide a polyolefin matrix and polymerizing a polyolefin rubber using a solid titanium catalyst component containing a titanium compound and a support made from a magnesium compound and an alkyl silicate.

  本发明涉及催化剂系统及其制备方法和聚合物的制备方法，其中所述催化剂系统/支撑体用于含有固体钛催化剂组分的烯烃聚合，该组分具有基本球形形状，包含钛化合物和由镁化合物和烷基硅酸酯制成的支撑体。所述催化剂系统还可以包含有机铝化合物和有机硅化合物。本发明还涉及一种制备共聚物的方法，该方法包括聚合烯烃以提供聚烯烃基体和使用含有钛化合物和由镁化合物和烷基硅酸酯制成的支撑体的固体钛催化剂组分聚合聚烯烃橡胶。
• PROCESS FOR POLYMERIZING ALPHA-OLEFIN
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0303704A1

  公开（公告）日：1989-02-22

  process for polymerizing an a-olefin, which comprises conducting polymerization of the a-olefin using a catalyst formed by previously bringing a highly active titanium solid catalyst component, a catalyst component of an organo-metallic compound of a group I to III metal of the periodic table, a catalyst component of an organic halogen compound or of a transition metal compound, and a catalyst component of an organo-silicone compound or of a sterically hindered amine into contact with each other in an inert solvent in the absence of the a-olefin, or a catalyst formed by conducting preliminary polymerization of the a-olefin in the presence of the above-described catalyst wherein the final component is optional. This process polymers having excellent stereospecificity with the catalyst showing high activity, thus attaining industrial advantages.

  聚合 a-olefin 的工艺，该工艺包括使用一种催化剂进行 a-olefin 的聚合，该催化剂是通过事先将一种高活性钛固体催化剂组分、一种元素周期表第 I 至 III 族金属的有机金属化合物催化剂组分、一种有机卤素化合物或一种过渡金属化合物的催化剂组分、一种有机硅化合物或一种立体受阻胺的催化剂组分在一种惰性溶剂中相互接触而形成的、和有机硅化合物或立体受阻胺的催化剂组分在没有 a-olefin 的情况下在惰性溶剂中相互接触，或在有上述催化剂存在的情况下对 a-olefin 进行初步聚合而形成的催化剂，其中最终组分是可选的。这种工艺生产出的聚合物具有极佳的立体特异性，催化剂活性高，因而具有工业优势。
• Process for polymerising olefins and polymerisation catalyst therefor
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0350170A2

  公开（公告）日：1990-01-10

  An olefin polymerization catalyst formed from (A) a solid titanium catalyst component containing magnesium, :itanium and halogen as essential ingredients, (B) an organoaluminum compound, and (C) an organosilicon :ompound containing a cyclopentyl group, a cyclopentenyl group, a cyclopentadienyl group or a derivative derived from any of these groups. A polymerization process which comprises polymerizing or copolymerizing olefins in the presence of the olefin polymerization catalyst to form a homopolyolefin having high stereoregularity or a copolyolefin having a narrow composition distribution.

  一种烯烃聚合催化剂，由以下物质组成：(A)含有镁、钛和卤素作为基本成分的固态钛催化剂组分；(B)有机铝化合物；(C)含有环戊基、环戊烯基、环戊二烯基或由上述任一基团衍生的衍生物的有机硅化合物。 一种聚合工艺，包括在烯烃聚合催化剂存在下使烯烃聚合或共聚，以形成立体规整度高的均聚 烯烃或成分分布窄的共聚烯烃。
• Polyolefin polymer composition
  申请人：W.R. Grace & Co.-Conn.

  公开号：US11421056B2

  公开（公告）日：2022-08-23

  The present disclosure is generally directed to polyolefin polymers, such as polypropylene homopolymers, and propylene-ethylene copolymers that have improved flow properties. In one embodiment, the polymers can be produced using a solid catalyst component that includes a) dissolving a halide-containing magnesium compound in a mixture, the mixture including an epoxy compound, an organic phosphorus compound, and a hydrocarbon solvent to form a homogenous solution; b) treating the homogenous solution with an organosilicon compound during or after the dissolving step; c) treating the homogenous solution with a first titanium compound in the presence of a first non-phthalate electron donor, and an organosilicon compound, to form a solid precipitate; and d) treating the solid precipitate with a second titanium compound in the presence of a second non-phthalate electron donor to form the solid catalyst component, where the process is free of carboxylic acids and anhydrides.

  本公开内容一般涉及聚烯烃聚合物，如聚丙烯均聚物和丙烯-乙烯共聚物，这些聚合物具有更好的流动性能。在一个实施方案中，可以使用固体催化剂组分生产聚合物，包括 a) 将含卤镁化合物溶解在混合物中，混合物包括环氧化合物、有机磷化合物和烃溶剂，以形成均质溶液； b) 在溶解步骤期间或之后，用有机硅化合物处理均质溶液；c) 在第一种非邻苯二甲酸酯电子供体和有机硅化合物存在的情况下，用第一种钛化合物处理均质溶液，形成固体沉淀；以及 d) 在第二种非邻苯二甲酸酯电子供体存在的情况下，用第二种钛化合物处理固体沉淀，形成固体催化剂组分，其中该工艺不含羧酸和酸酐。