hexacarbazolylphenyl

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: hexacarbazolylphenyl
• 英文别名: 9-[2,3,4,5,6-Penta(carbazol-9-yl)phenyl]carbazole
• 化学式: C₇₈H₄₈N₆
• 分子量: 1069.28
• InChiKey: BYNBVANNOUTMHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.4
• 重原子数：
  84
• 可旋转键数：
  6
• 环数：
  19.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  29.6
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  六氟苯 、 咔唑 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.5h， 以56%的产率得到hexacarbazolylphenyl
  参考文献：
  名称：

  Fine tailoring the steric configuration of initial building blocks to construct ultramicroporous polycarbazole networks with high CO2 uptake and selectivity of CO2 over N2

  摘要：

  Three carbazole based building blocks with similar propeller-like steric configuration are designed and synthesized. The polycarbazole networks P-4, 4'-biscarbazolyl-phenyl (P-BCz), P-tetracarbazolyl-p-difluorobenzene (P-TCz) and P-hexacarbazolyl-phenyl (P-HCz) are obtained with high surface areas and uniform ultramicropores. The aggregation morphologies of networks vary from regular spherical particles, ribbon-like structure to large lamellar structure as the number of carbazole increased around the benzene ring. The networks P-TCz, with four carbazole decorating on the benzene ring, have the largest surface area and highest gas uptake ability among the three networks. However, the CO2 and CH4 isosteric enthalpies increased linearly with increasing the number of carbazole. The networks P-HCz with six carbazole show the excellent CO2/N-2 separative capacity (107 at 273 K, and 127 at 298 K), which is among the highest reported about CO2 separation using organic pore networks. Fine designing and tailoring the topological structure of monomer can control the adsorption properties and optimize the gas uptake performance. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2015.06.011

文献信息

• Organic electroluminescent element
  申请人：Kaminaga Kuniyuki

  公开号：US10431749B2

  公开（公告）日：2019-10-01

  Disclosed is an organic electroluminescent element which is excellent with respect to luminous efficiency and driving voltage and rarely undergoes initial luminance drop. Specifically disclosed is an organic electroluminescent element which comprises, on a substrate, a pair of electrodes composed of an anode and a cathode and a light-emitting layer arranged between the electrodes, and additionally comprises at least one organic layer arranged between the light-emitting layer and the cathode, where in the light-emitting layer contains, for example, a compound (A-1), and the at least one layer arranged between the light-emitting layer and the cathode contains, for example, a compound (e-4).

  本发明公开了一种有机电致发光元件，它在发光效率和驱动电压方面都非常出色，而且很少出现初始亮度下降的情况。具体地说，本发明公开了一种有机电致发光元件，它包括位于基板上的一对由阳极和阴极组成的电极以及位于电极之间的发光层，此外还包括位于发光层和阴极之间的至少一层有机层，其中发光层含有例如化合物（A-1），而位于发光层和阴极之间的至少一层含有例如化合物（e-4）。
• ORGANIC ELECTRIC FIELD LIGHT EMITTING ELEMENT AND PRODUCTION THEREFOR
  申请人：Yabe Masayoshi

  公开号：US20090066223A1

  公开（公告）日：2009-03-12

  A composition for an organic electroluminescent device is a composition for forming an organic light emitting layer of an organic electroluminescent device by wet coating process. The composition contains a phosphorescent material, a charge transport material, and a solvent, in which the phosphorescent material and the charge transport material are each an unpolymerized organic compound, and the first oxidation potential of the phosphorescent material E D + , the first reduction potential of the phosphorescent material E D − , the first oxidation potential of the charge transporting material E T + , and the first reduction potential of the charge transporting material E T − satisfy the following condition: E T − +0.1≦E D −
• US7422802B2
  申请人：——

  公开号：US7422802B2

  公开（公告）日：2008-09-09
• US9365767B2
  申请人：——

  公开号：US9365767B2

  公开（公告）日：2016-06-14
• US9640769B2
  申请人：——

  公开号：US9640769B2

  公开（公告）日：2017-05-02