1,3-bis(perfluorophenyl)adamantane

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1,3-bis(perfluorophenyl)adamantane
• 英文别名: 1,3-Bis(2,3,4,5,6-pentafluorophenyl)adamantane；1,3-bis(2,3,4,5,6-pentafluorophenyl)adamantane
• 化学式: C₂₂H₁₄F₁₀
• 分子量: 468.337
• InChiKey: GFNCCBMPMIMCLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  六氟苯 、 1,3-金刚烷二甲酸 在 Ir(dFFppy)₂(dtbbpy)PF₆ 、 lithium carbonate 作用下， 以 二甲基亚砜 为溶剂， 反应 24.0h， 以69%的产率得到1,3-bis(perfluorophenyl)adamantane
  参考文献：
  名称：

  烷基羧酸的脱羧多氟芳基化

  摘要：

  多氟芳烃是药物发现、材料和作物保护等多个领域的有用组成部分。在此，我们报告了首次通过光氧化还原脱羧对脂肪族羧酸进行多氟芳基化。该方法具有广泛的底物范围和高官能团耐受性。此外，天然产物和药物等复杂小分子可以通过后期修饰进行修饰。

  DOI：

  10.1002/anie.202015596

文献信息

• Film forming composition, insulating film using the composition, and electronic device having the insulating film
  申请人：Hiraoka Hidetoshi

  公开号：US20070135585A1

  公开（公告）日：2007-06-14

  A film forming composition comprising a compound having a cage structure and a crosslinkable compound; an insulating film formed by using the composition; and an electronic device comprising the insulating film.
• Film, film forming composition and electronic device having the film
  申请人：Asano Akira

  公开号：US20070135603A1

  公开（公告）日：2007-06-14

  A film having, as a result of raman spectroscopy, the highest intensity peak within from 690 to 800 cm −1 in a Raman shift range of from 300 to 3100 cm −1 ; a film forming composition capable of forming, the film; and an electronic device having the film.
• Film forming composition
  申请人：Hiraoka Hidetoshi

  公开号：US20070224436A1

  公开（公告）日：2007-09-27

  A film forming composition comprises a compound having a cage structure and a thermally decomposable compound, an insulating film is formed by using the film forming composition and an electronic device comprises the insulating film.
• PRODUCTION METHOD OF INSULATING FILM, INSULATING FILM, STACKED PRODUCT AND ELECTRONIC DEVICE
  申请人：ASANO Akira

  公开号：US20080076850A1

  公开（公告）日：2008-03-27

  A production method of an insulating film includes a process of applying a film forming composition to form a film; and a process of irradiating the film with at least two kinds of high energy rays to cure the film.
• INSULATING FILM FORMATION PROCESS
  申请人：MURAMATSU Makoto

  公开号：US20080081131A1

  公开（公告）日：2008-04-03

  A production method of an insulating film includes (1) a process of applying, onto a substrate, a film forming composition comprising a compound having a cage structure to form a film and then drying the film; and (2) a process of irradiating the film with an electron beam or an electromagnetic wave having a wavelength greater than 200 nm.