CpMnH(CO)3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: CpMnH(CO)3
• 化学式: C₈H₆MnO₃
• 分子量: 205.072
• InChiKey: LCJBUNGHIBUPAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  CpMnH(CO)3 、 (tert-butyl(diphenylphosphaneyl)amino)dimethylaluminum 生成
  参考文献：
  名称：

  Amphoteric ligands. 2. Formation and structure of a novel carbon-hydrogen-bond-containing product from hydridomanganese pentacarbonyl and an amphoteric ligand

  摘要：

  DOI：

  10.1021/ja00388a099
• 作为产物：
  描述：

  三羰基(η-环戊二烯基)合锰 、 氟磺酸 以 二氯甲烷 、 氟磺酸 为溶剂， 生成 CpMnH(CO)3
  参考文献：
  名称：

  Basicity of metal carbonyl complexes communication 17. Protonation of manganese and rhenium cyclopentadienylcarbonyl complexes

  摘要：

  DOI：

  10.1007/bf01157349

文献信息

• Oxygen Binding to [Pd(L)(L′)] (L= NHC, L′ = NHC or PR₃, NHC = <i>N</i>-Heterocyclic Carbene). Synthesis and Structure of a Paramagnetic <i>trans</i>-[Pd(NHC)₂(η¹-O₂)₂] Complex
  作者：Xiaochen Cai、Subhojit Majumdar、George C. Fortman、Catherine S. J. Cazin、Alexandra M. Z. Slawin、Charles Lhermitte、Rajeev Prabhakar、Meaghan E. Germain、Taryn Palluccio、Steven P. Nolan、Elena V. Rybak-Akimova、Manuel Temprado、Burjor Captain、Carl D. Hoff

  DOI：10.1021/ja1103348

  日期：2011.2.9

  The reactivity of a number of two-coordinate [Pd(L)(L')] (L = N-heterocyclic carbene (NHC) and L' = NHC or PR3) complexes with O-2 has been examined. Stopped-flow kinetic studies show that O-2 binding to [Pd(IPr)(P(p-tolyl)(3))] to form cis-[Pd(IPr)(P(p-tolyl)(3))-(eta(2)-O-2)] occurs in a rapid, second-order process. The enthalpy of O-2 binding to the Pd(0) center has been determined by solution calorimetry to be -26.2(1.9) kcal/mol. Extension of this work to the bis-NHC complex [Pd(IPr)(2)], however, did not lead to the formation of the expected diamagnetic complex cis-[Pd(IPr)(2)(eta(2)-O-2)] but to paramagnetic trans-[(Pd(IPr)(2)(eta(1)-O-2)(2)], which has been fully characterized. Computational studies addressing the energetics of O-2 binding have been performed and provide insight into reactivity changes as steric pressure is increased.
• Basicity of metal carbonyl complexes communication 17. Protonation of manganese and rhenium cyclopentadienylcarbonyl complexes
  作者：A. G. Ginzburg、P. V. Petrovskii、V. N. Setkina、D. N. Kursanov

  DOI：10.1007/bf01157349

  日期：1985.1
• Amphoteric ligands. 2. Formation and structure of a novel carbon-hydrogen-bond-containing product from hydridomanganese pentacarbonyl and an amphoteric ligand
  作者：David L. Grimmett、Jay A. Labinger、John N. Bonfiglio、Steven T. Masuo、Eileen Shearin、Joel S. Miller

  DOI：10.1021/ja00388a099

  日期：1982.12