chryseno[2,1-b:8,7-b']dithiophene

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: chryseno[2,1-b:8,7-b']dithiophene
• 英文别名: 6,18-dithiahexacyclo[11.11.0.02,10.05,9.014,22.017,21]tetracosa-1(13),2(10),3,5(9),7,11,14(22),15,17(21),19,23-undecaene
• 化学式: C₂₂H₁₂S₂
• 分子量: 340.469
• InChiKey: TXBADXAIMMDKBJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  三甲基氯化锡 、 chryseno[2,1-b:8,7-b']dithiophene 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 2.5h， 以41%的产率得到
  参考文献：
  名称：

  通过杂原子掺杂的去对称化对带状持久性环亚芳基的手性特性进行控制

  摘要：

  在分子圆柱体的设计中设计了去对称化策略，以最大化与圆偏振光相关的不对称因子。尽管先前通过具有平行的磁和电跃迁偶极矩的手性带持久性环亚芳基实现了有机分子的最高不对称因子，但我们注意到两个矩的不平衡幅度对于更高的不对称因子是有害的。在这项研究中，通过立体选择性交叉偶联大环化排列掺杂和未掺杂的面板，使分子圆柱体去对称化。去对称化通过减少全局最小值处的电跃迁矩成功地平衡了两个矩，但未能最大化不对称因子。结构研究表明，不对称因子对细微的结构波动敏感，而旋转强度不受影响。这项研究对于手性光学材料的开发具有重要意义。

  DOI：

  10.1002/anie.202106992

文献信息

• Organic thin-film transistor and method for manufacturing the same, material for organic thin-film transistor, composition for organic thin-film transistor, compound, and organic semiconductor film
  申请人：FUJIFILM Corporation

  公开号：US10283719B2

  公开（公告）日：2019-05-07

  An object of the present invention is to provide a compound which, when used for organic semiconductor films in organic thin-film transistors, makes the organic thin-film transistors exhibit a high carrier mobility, a material for an organic thin-film transistor for which the compound is used, a composition for an organic thin-film transistor, an organic thin-film transistor and a method for manufacturing the same, and an organic semiconductor film. An organic thin-film transistor of the present invention contains a compound represented by General Formula (1) in an organic semiconductor film (organic semiconductor layer) thereof.

  本发明的目的是提供一种化合物，当用于有机薄膜晶体管中的有机半导体薄膜时，使有机薄膜晶体管表现出高载流子迁移率，所用的有机薄膜晶体管的材料，有机薄膜晶体管的组成，有机薄膜晶体管和其制造方法，以及有机半导体薄膜。本发明的有机薄膜晶体管在其有机半导体薄膜（有机半导体层）中含有通式（1）所表示的化合物。
• NOVEL ORGANIC POLYMER AND METHOD FOR PRODUCING SAME
  申请人：THE UNIVERSITY OF TOKYO

  公开号：EP3438150A1

  公开（公告）日：2019-02-06

  Provided are a novel organic polymer useful for forming an organic semiconductor and a use of the novel organic polymer. A compound represented by the following formula (Ia) is subjected to a coupling reaction to give an organic polymer: wherein a ring A and a ring B represent an aromatic hydrocarbon ring or an aromatic heterocyclic ring, n denotes an integer of 0 or 1 to 6, R1 to R2+n represent a substituent (such as an alkyl group), a1 to a (2+n) denote an integer of 0 to 2, a ring C represents a benzene ring ortho-fused sequentially and nonlinearly to an adjacent benzene ring depending on the number of n, X represents a hydrogen atom, a halogen atom, a lithium atom, or -MgX1 (wherein X1 represents a halogen atom).

  本文提供了一种可用于形成有机半导体的新型有机聚合物及其用途。将下式 (Ia) 所代表的化合物进行偶联反应，得到一种有机聚合物： 其中环 A 和环 B 代表芳香烃环或芳香杂环，n 表示 0 或 1 至 6 的整数，R1 至 R2+n 代表取代基（如烷基），a1 至 a（2+n）表示 0 至 2 的整数、环 C 代表与相邻苯环依次非线性正交融合的苯环，取决于 n 的数目，X 代表氢原子、卤素原子、锂原子或 -MgX1（其中 X1 代表卤素原子）。
• ORGANIC SEMICONDUCTOR ELEMENT, ORGANIC SEMICONDUCTOR COMPOSITION, ORGANIC SEMICONDUCTOR FILM, METHOD FOR PRODUCING ORGANIC SEMICONDUCTOR FILM, AND POLYMER USED THEREFOR
  申请人：FUJIFILM Corporation

  公开号：EP3745484A1

  公开（公告）日：2020-12-02

  Provided are an organic thin film transistor element comprising an organic semiconductor layer containing a specific polymer which has a repeating unit including a structure represented by a specific formula, an organic semiconductor film suitable as the organic semiconductor layer and a method of manufacturing the same, and a polymer and a composition suitable as a constituent material of the organic semiconductor film.

  本发明提供了一种有机薄膜晶体管元件，该元件由含有特定聚合物的有机半导体层、适合作为有机半导体层的有机半导体薄膜及其制造方法、以及适合作为有机半导体薄膜组成材料的聚合物和组合物构成。
• Organic semiconductor element, polymer, organic semiconductor composition, and organic semiconductor film
  申请人：FUJIFILM Corporation

  公开号：US10971686B2

  公开（公告）日：2021-04-06

  Provided are an organic semiconductor element including an organic semiconductor film that includes a polymer having a repeating unit represented by the following Formula (1), the polymer, and an organic semiconductor composition and an organic semiconductor film including the polymer. In the formula, Z represent a 5-membered aromatic heterocycle. RC1 and RC2 each independently represent a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, or an aromatic heterocyclic group. n1 and n2 each independently represent 0 or 1. RC3 to RC10 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, or an aromatic heterocyclic group.

  本发明提供了一种有机半导体元件，包括有机半导体薄膜，该有机半导体薄膜包括具有下式（1）表示的重复单元的聚合物、该聚合物、有机半导体组合物以及包括该聚合物的有机半导体薄膜。 式中，Z 代表 5 元芳香杂环。n1 和 n2 各自独立地代表 0 或 1。RC3 至 RC10 各自独立地代表氢原子、卤素原子、烷基、烯基、炔基、芳香烃基团或芳香杂环基团。
• Organic semiconductor element, organic semiconductor composition, organic semiconductor film, method of manufacturing organic semiconductor film, and polymer using the same
  申请人：FUJIFILM Corporation

  公开号：US11011706B2

  公开（公告）日：2021-05-18

  Provided are an organic thin film transistor element comprising an organic semiconductor layer containing a specific polymer which has a repeating unit including a structure represented by a specific formula, an organic semiconductor film suitable as the organic semiconductor layer and a method of manufacturing the same, and a polymer and a composition suitable as a constituent material of the organic semiconductor film.

  本发明提供了一种有机薄膜晶体管元件，该元件由含有特定聚合物的有机半导体层、适合作为有机半导体层的有机半导体薄膜及其制造方法、以及适合作为有机半导体薄膜组成材料的聚合物和组合物构成。