全氟辛酸 | 16517-11-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 全氟辛酸
• 中文别名: 全氟十八酸
• 英文名称: perfluorooctadecanoic acid
• 英文别名: perfluoroheptadecacarboxylic acid；pentatriacontafluoro-octadecanoic acid；perfluorostearic acid；Pentatriacontafluor-octadecansaeure；2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-pentatriacontafluorooctadecanoic acid
• CAS: 16517-11-6
• 化学式: C₁₈HF₃₅O₂
• 分子量: 914.149
• InChiKey: ZTSDOGSKTICNPQ-UHFFFAOYSA-N

物化性质

• 熔点：
  162-164°C
• 沸点：
  235°C 100mm
• 密度：
  1.786±0.06 g/cm3(Predicted)
• 闪点：
  235°C/100mm
• 溶解度：
  DMSO（非常轻微，加热）
• 稳定性/保质期：
  常温常压下稳定，避免与氧化物和碱接触。

计算性质

• 辛醇/水分配系数(LogP)：
  11.6
• 重原子数：
  55
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  37

安全信息

• TSCA：
  Yes
• 危险等级：
  8
• 危险品标志：
  C
• 安全说明：
  S26,S36/37/39,S45
• 危险类别码：
  R34
• 包装等级：
  II
• 危险类别：
  8

上下游信息

• 下游产品

  中文名称	英文名称	CAS号	化学式	分子量
  全氟庚酸	perfluoroheptanoic acid	375-85-9	C7HF13O2	364.063

反应信息

• 作为反应物：
  描述：

  全氟辛酸 在 吡啶 、 草酰氯 作用下， 以 苯 为溶剂， 反应 24.0h， 生成 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-Pentatriacontafluoro-octadecanoic acid propylamide
  参考文献：
  名称：

  N-Alkyl Perfluoroalkanamides as Low Molecular-Mass Organogelators

  摘要：

  A new class of low molecular-mass organogelators (LMOGs), N-alkyl perfluoroalkanamides, F(CF2)(n)CONH(CH2)(m)H, is described. The molecules are designed to exploit the incompatibilities of their three molecular parts, and the results demonstrate that this strategy can be used to tune molecular aggregation and gel stability. The gelating properties of these LMOGs have been examined in a wide variety of organic liquids (including alkanes, alcohols, toluene, n-perfluorooctane, CCl4, and DMSO) as a function of the N-alkyl and perfluoroalkyl chain lengths by X-ray diffraction, polarizing optical microscopy, infrared spectroscopy, differential scanning calorimetry, and small-angle neutron scattering (SANS). The gels are thermally reversible and require generally very low concentrations (<2 wt %) of LMOG. Several of the gels are stable for very long periods at room temperature. The incompatibility of the fluorocarbon and hydrocarbon segments causes the LMOGs to aggregate, probably into lamellae within the fibrils that constitute the basic unit of the gel networks. The SANS studies show that the cross-sections of fibers in the gel networks of LMOGs with shorter perfluoroalkyl chains are much larger than those with longer ones. Comparisons with the gelating properties of some analogous esters (F(CF2)(n)CO2(CH2)(m)H) and diblock perfluoroalkylalkanes (F(CF2)(n)(CH2)(m)H) indicate that additional ordering within the aggregate units is enforced by the intermolecular H bonding among amide groups that is evidenced by IR spectroscopy. Analyses of these results and structure/solvent correlations are provided.

  DOI：

  10.1021/ja0362407
• 作为产物：
  描述：

  硬脂酸 在 氢氟酸 作用下， 生成 全氟辛酸
  参考文献：
  名称：

  Fluorocarbon vinyl esters and polymers

  摘要：

  公开号：

  US02592069A1

文献信息

• PROCESS FOR PRODUCING ESTER COMPOUND
  申请人：Imazeki Shigeaki

  公开号：US20100324314A1

  公开（公告）日：2010-12-23

  PROBLEM To provide an environmentally-friendly method for producing industrially an ester compound. SOLUTION The present invention is a method for producing an ester compound which comprises subjecting a carboxylic acid and an alcohol to dehydration-condensation reaction using an involatile acid catalyst and then removing the residual acid catalyst by bringing a weak basic substance into contact with the residual acid catalyst.

  问题提供一种生产工业酯化合物的环保方法。 解决方案是一种生产酯化合物的方法，包括将羧酸和醇经过脱水缩合反应，使用一种不挥发的酸催化剂，然后通过将弱碱性物质与残留的酸催化剂接触来去除残留的酸催化剂。
• Structure and Thermal Behavior of Layered Silver Perfluorocarboxylates
  作者：Seung Joon Lee、Sang Woo Han、Hyouk Jin Choi、Kwan Kim

  DOI：10.1021/jp0255841

  日期：2002.8.1

  The structure and thermal behavior of silver perfluorocarboxylates (AgCO2(CF2)nCF3, n = 10, 12, 14, and 16) have been investigated by using various analytical tools. The X-ray diffraction patterns were composed of a series of peaks that could be indexed to (0k0) reflections of a layered structure. The adjacent layers were presumed to overlap by as much as 94% of the terminal CF3 groups. Diffuse reflectance

  已经使用各种分析工具研究了全氟羧酸银（AgCO2(CF2)nCF3，n = 10、12、14 和 16）的结构和热行为。X 射线衍射图案由一系列峰组成，这些峰可以索引为层状结构的 (0k0) 反射。假定相邻层重叠多达 94% 的末端 CF3 基团。漫反射红外傅里叶变换光谱表明羧酸基团与银的结合态为桥接态。热分析表明链熔化过程在~560 K 开始，没有任何中间预熔化事件，但在链熔化过程之后立即进行热分解反应。更重要的是，发现发生结构坍塌的温度比氢烷羧酸银（如硬脂酸银）高约 100 K。增强的热稳定性似乎与碳氟化合物的高刚性有关……
• Perfluorocarbon-stabilized silver nanoparticles manufactured from layered silver carboxylates
  作者：Seung Joon Lee、Sang Woo Han、Kwan Kim

  DOI：10.1039/b111607j

  日期：2002.2.27

  Perfluorocarboxylate-stabilized silver nanoparticles have been prepared uniformly via the thermal decomposition of layered silver perfluorocarboxylates (AgCO2(CF2)nCF3, n = 10, 12, 14 and 16).

  通过热分解分层银全氟羧酸盐（AgCO2(CF2)nCF3，n = 10、12、14和16），均匀制备了全氟羧酸盐稳定的银纳米颗粒。
• 一种不饱和氟碳化合物及其制备方法和应用
  申请人：广东广山新材料股份有限公司

  公开号：CN109456193B

  公开（公告）日：2022-04-26

  本发明提供一种不饱和氟碳化合物及其制备方法和应用。所述不饱和氟碳化合物制备得到的材料具有优异的介电性能以及机械性能，且制备工艺简单，原料价格低廉，可有效减少投资，降低成本。
• COMPOSITIONS, METHODS, AND SYSTEMS COMPRISING FLUOROUS-SOLUBLE POLYMERS
  申请人：Swager Timothy M.

  公开号：US20120177578A1

  公开（公告）日：2012-07-12

  The present invention generally relates to compositions, methods, and systems comprising polymers that are fluorous-soluble and/or organize at interfaces between a fluorous phase and a non-fluorous phase. In some embodiments, emulsions or films are provided comprising a polymer. The polymers, emulsions, and films can be used in many applications, including for determining, treating, and/or imaging a condition and/or disease in a subject. The polymer may also be incorporated into various optoelectronic device such as photovoltaic cells, organic light-emitting diodes, organic field effect transistors, or the like. In some embodiments, the polymers comprise pi-conjugated backbones, and in some cases, are highly emissive.

  本发明通常涉及包含聚合物的组合物、方法和系统，该聚合物是可以在氟化物相和非氟化物相之间界面上溶解或组织的。在某些实施例中，提供了包含聚合物的乳液或薄膜。这些聚合物、乳液和薄膜可以用于许多应用，包括用于确定、治疗和/或成像受试者的状况和/或疾病。该聚合物也可以被纳入各种光电器件中，如光伏电池、有机发光二极管、有机场效应晶体管等。在某些实施例中，该聚合物包括π-共轭骨架，并且在某些情况下，具有高发光性。