1,1'-bis(butanoyl)ferrocene

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1'-bis(butanoyl)ferrocene
• 化学式: C₁₈H₂₂FeO₂
• 分子量: 326.218
• InChiKey: BVMNCYGDHNCWOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.52
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1'-bis(butanoyl)ferrocene 在 NaBH₄/BF₃ 作用下， 以 1,4-二氧六环 为溶剂， 以75%的产率得到1,1'-二丁基-二茂铁
  参考文献：
  名称：

  Shul'pin, G. V., Journal of general chemistry of the USSR, 1981, vol. 51, p. 1854 - 1854

  摘要：

  DOI：
• 作为产物：
  描述：

  二茂铁 、 丁酰氯 在 三氯化铝 作用下， 以 二氯甲烷 为溶剂， 以93%的产率得到1,1'-bis(butanoyl)ferrocene
  参考文献：
  名称：

  A convenient synthesis of E-alkenylferrocenes

  摘要：

  Alkenylferrocenes, FcCHCHR [R = (CH2)(n)CH3, n = 0-4], and 1,1 ' -bisalkenylferrocenes, Fc(CHCHR)(2) (R = CH3, CH2CH3) were synthesized by elimination reaction from the corresponding alpha -hydroxyferrocenylalkanes using methanesulfonylchloride and triethylamine. (C) 2001 Elsevier science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00862-2

文献信息

• Ionic Conductivity Induced by Photooxidation of Ferrocene in Polymer Film Containing Organotin Compound
  作者：Tatsuo Fujinami、Nobuo Kawahara、Shizuyoshi Sakai、Masami Ogita

  DOI：10.1246/cl.1993.585

  日期：1993.4

  Ionic conductivity of poly(ethyl methacrylate) film containing photooxidizable dibutylferrocene and bromotributylstannane was induced by UV light irradiation in contact with the anion-conducting polymer film containing a cobaltocemum salt. The enhanced ionic conductivity decreased in the dark.

  通过紫外线照射含有钴盐的阴离子传导聚合物薄膜，诱导了含有可光氧化的二丁基二茂铁和溴代三丁基锡的聚甲基丙烯酸乙酯薄膜的离子传导性。增强的离子传导性在黑暗中有所降低。
• Synthesis of ferrocene-based phosphine ligands via Cu-catalyzed reductive coupling of ferrocenyl ketone-derived tosylhydrazones and H -phosphorus oxides
  作者：Li Ling、Jianfeng Hu、Yanhong Huo、Hao Zhang

  DOI：10.1016/j.tet.2016.11.054

  日期：2017.1

  Ferrocene-based phosphine oxides with various substituents at phosphorous atoms were synthesized by Cu-catalyzed reductive coupling of ferrocenyl ketone-derived tosylhydrazones and H-phosphorus oxides. Followed by the reduction of ferrocene-based phosphine oxides, 1-substituted ferrocene-based phosphine ligand 7 and 1,1'-disubstituted ferrocene-based phosphine ligand 9 were obtained. Josiphos type ligand 8 were produced after ortho-lithiation of 7 and trapping with chlorodiphenyl phosphine or chlorodicyclohexylphosphine. (C) 2016 Elsevier Ltd. All rights reserved.