Al[S2P(SH)OiPr]3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Al[S2P(SH)OiPr]3
• 英文别名: Aluminum;propan-2-yloxy-sulfanyl-sulfanylidene-sulfido-lambda5-phosphane；aluminum;propan-2-yloxy-sulfanyl-sulfanylidene-sulfido-λ5-phosphane
• 化学式: C₉H₂₄AlO₃P₃S₉
• 分子量: 588.785
• InChiKey: LOCQVTSZIJEMON-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  5.96
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  130
• 氢给体数：
  3
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  trithiophosphoric acid O-isopropyl ester 、 aluminum isopropoxide 以 苯 为溶剂， 以89%的产率得到Al[S2P(SH)OiPr]3
  参考文献：
  名称：

  Synthesis, Spectroscopic Studies, and Antifungal Activity of Tris(O-Alkyl or O-Aryltrithiophosphato) Aluminum(III)

  摘要：

  Aluminum(III) derivatives of O-alkyl or O-aryl trithiophosphate of the type Al[S2P(SH)OR](3) (R = Me, Et, Pr-i, Bu-i, Ph, CH2Ph) have been synthesized. The products were obtained as white powdery solids. The monomers are soluble in common organic solvents and were characterized by elemental analyses, molecular weight determinations, and IR and (H-1, Al-27, and P-31) NMR spectroscopic studies, which are consistent with six coordinated aluminum and bidentate behavior of the trithiophosphate moiety. The products also exhibit antifungal effectiveness against powdery mildew disease.

  DOI：

  10.1080/10426507.2012.746345

文献信息

• Synthesis, Spectroscopic Studies, and Antifungal Activity of Tris(<i>O</i>-Alkyl or <i>O</i>-Aryltrithiophosphato) Aluminum(III)
  作者：Kiran Sankhala、Alok Chaturvedi

  DOI：10.1080/10426507.2012.746345

  日期：2013.10.1

  Aluminum(III) derivatives of O-alkyl or O-aryl trithiophosphate of the type Al[S2P(SH)OR](3) (R = Me, Et, Pr-i, Bu-i, Ph, CH2Ph) have been synthesized. The products were obtained as white powdery solids. The monomers are soluble in common organic solvents and were characterized by elemental analyses, molecular weight determinations, and IR and (H-1, Al-27, and P-31) NMR spectroscopic studies, which are consistent with six coordinated aluminum and bidentate behavior of the trithiophosphate moiety. The products also exhibit antifungal effectiveness against powdery mildew disease.