1-(3-(methacryloyloxy)propyl)-3-methyl-3H-imidazol-1-ium bromide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-(3-(methacryloyloxy)propyl)-3-methyl-3H-imidazol-1-ium bromide
• 英文别名: 1-methyl-3-(2-methacryloyloxypropyl)imidazolium bromide；3-(3-Methylimidazol-3-ium-1-yl)propyl 2-methylprop-2-enoate;bromide；3-(3-methylimidazol-3-ium-1-yl)propyl 2-methylprop-2-enoate;bromide
• 化学式: Br*C₁₁H₁₇N₂O₂
• 分子量: 289.172
• InChiKey: XNDVMWZPBPIGML-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.17
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  35.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-甲基咪唑 、 3-bromopropyl methacrylate 在 对苯二酚 作用下， 反应 72.0h， 生成 1-(3-(methacryloyloxy)propyl)-3-methyl-3H-imidazol-1-ium bromide
  参考文献：
  名称：

  AUCL 4 -响应性的自组装用于获得复合金纳米颗粒和聚合物胶束具有受控形态的离子液体嵌段共聚物†

  摘要：

  双亲水性离子液体嵌段共聚物（ILBC），聚（乙二醇） -嵌段-聚[1-甲基-3-（2-甲基丙烯酰氧基丙基溴）]（PEG 113 - b -PMMPImB 24），通过RAFT聚合反应合成的PEG-CTA作链转移剂制备1-甲基-3-（2-甲基丙烯酰氧基丙基咪唑鎓溴）。与AUCL直接交互4 -在水溶液中，自组装的PEG胶束113 - b -PMMPImB 24诱导通过ILBC的阴离子响应特性。然后，通过AUCL的减少依次获得高分子胶粒包封的金纳米颗粒（的GNP）的复合材料4 -原位。在AUCL的下摩尔比4 -至咪唑鎓，与AUCL聚合物胶束的明显囊泡结构4 -形成，并与所述的GNP复合材料和在聚合物囊泡壁的GNP的分布似乎是均匀的尺寸。通过增加AuCl 4-的含量，也可以获得具有高度堆积的GNP的球形胶束。。这些结果表明，胶束核心中PIL的独特化学和物理性质可以控制胶束形态和GNP在狭窄空间中的分布。

  DOI：

  10.1039/c4nj00128a

文献信息

• Single molecule filter and single molecule electrograph, and process for making and using same
  申请人：NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY

  公开号：US10067118B2

  公开（公告）日：2018-09-04

  A single molecule filter includes: a membrane including: a first surface; a second surface; and a membrane aperture disposed in the membrane and traversing the membrane from the first surface to the second surface, the membrane aperture provided to communicate a single molecule across the membrane; and a nanotube disposed on the membrane and including: a first end disposed on the first surface of the membrane; a second end disposed distal to the first surface; and a tubular aperture extending along the nanotube from the first end to the second end, the tubular aperture provided to communicate the single molecule from the second end of the nanotube to the membrane aperture.

  一种单分子过滤器包括：膜，其中包括：第一表面；第二表面；以及设置在膜中并从第一表面穿过膜到第二表面的膜孔，膜孔用于将单分子穿过膜；以及设置在膜上的纳米管，其中包括：设置在膜的第一表面上的第一端；设置在第一表面远端的第二端；以及沿纳米管从第一端延伸到第二端的管状孔，管状孔用于将单分子穿过膜；以及设置在膜上的纳米管，其中包括设置在膜的第一表面上的第一端；设置在第一表面远端的第二端；以及从第一端到第二端沿纳米管延伸的管状孔，管状孔用于将单分子从纳米管的第二端传输到膜孔。
• Aggregation of nanoparticles in aqueous solutions of ionic liquids
  作者：Hossein Sajjadi、Ali Modaressi、Pierre Magri、Urszula Domańska、Michèle Sindt、Jean-Luc Mieloszynski、Fabrice Mutelet、Marek Rogalski

  DOI：10.1016/j.molliq.2013.04.025

  日期：2013.10

  In this work we were concerned with interactions between ionic liquids (IL) and nanoparticles (NPs) dispersed in aqueous solutions leading to the formation of NP clusters of finite size. The NPs used were Al2O3 (d = 80 nm), TiO2 (d < 100 nm), and Fe3O4 (d < 100 nm). ILs were 1-butyl-3-methylimidazolium bromide ([BMIM][Br]) and 1-methacryloyloxypropyl-3-methylimidazolium bromide, [mcpmim][Br]. The latter compound was a new IL synthesized in our laboratory. It was demonstrated that ILs actively participate in the formation of NP aggregates suspended in aqueous solution filling the inter-particle space. The aggregates saturated with IL were used as extractors making it possible for the elimination of compounds dissolved in water. Results of the extraction of anthracene and salicylic acid from aqueous solutions were presented. (C) 2013 Elsevier B.V. All rights reserved.
• STABLE SUSPENSIONS OF CARBON NANOPARTICLES FOR NANO-ENHANCED PDC, LBL COATINGS, AND COOLANTS
  申请人：Mazyar Oleg A.

  公开号：US20130165353A1

  公开（公告）日：2013-06-27

  A nanocomposite comprises a matrix; and a nanoparticle comprising an ionic polymer disposed on the surface of the nanoparticle, the nanoparticle being dispersed in and/or disposed on the matrix. A method of making a nanocomposite, comprises combining a nanoparticle and an ionic liquid; polymerizing the ionic liquid to form an ionic polymer; disposing the ionic polymer on the nanoparticle; and combining the nanoparticle with the ionic polymer and a matrix to form the nanocomposite.
• SINGLE MOLECULE FILTER AND SINGLE MOLECULE ELECTROGRAPH, AND PROCESS FOR MAKING AND USING SAME
  申请人：NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY

  公开号：US20160033451A1

  公开（公告）日：2016-02-04

  A single molecule filter includes: a membrane including: a first surface; a second surface; and a membrane aperture disposed in the membrane and traversing the membrane from the first surface to the second surface, the membrane aperture provided to communicate a single molecule across the membrane; and a nanotube disposed on the membrane and including: a first end disposed on the first surface of the membrane; a second end disposed distal to the first surface; and a tubular aperture extending along the nanotube from the first end to the second end, the tubular aperture provided to communicate the single molecule from the second end of the nanotube to the membrane aperture.
• [EN] STABLE SUSPENSIONS OF CARBON NANOPARTICLES FOR NANO-ENHANCED PDC, LBL COATINGS, AND COOLANTS<br/>[FR] SUSPENSIONS STABLES DE NANOPARTICULES DE CARBONE POUR PDC NANO-AMÉLIORÉ, DES REVÊTEMENTS LBL ET DES LIQUIDES DE REFROIDISSEMENT
  申请人：BAKER HUGHES INC

  公开号：WO2013096540A1

  公开（公告）日：2013-06-27

  A nanocomposite comprises a matrix; and a nanoparticle comprising an ionic polymer disposed on the surface of the nanoparticle, the nanoparticle being dispersed in and/or disposed on the matrix. A method of making a nanocomposite, comprises combining a nanoparticle and an ionic liquid; polymerizing the ionic liquid to form an ionic polymer; disposing the ionic polymer on the nanoparticle; and combining the nanoparticle with the ionic polymer and a matrix to form the nanocomposite.