双(2-乙氧基乙基)癸二酸酯 | 624-10-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 双(2-乙氧基乙基)癸二酸酯
• 英文名称: decanedioic acid bis-(2-ethoxy-ethyl ester)
• 英文别名: Decandisaeure-bis-(2-aethoxy-aethylester)；bis(2-ethoxyethyl) sebacate；Bis-(2-ethoxy-ethyl)-sebacat；Bis(2-ethoxyethyl)sebacate；bis(2-ethoxyethyl) decanedioate
• CAS: 624-10-2
• 化学式: C₁₈H₃₄O₆
• mdl: MFCD00041927
• 分子量: 346.464
• InChiKey: UVRXDBUBNLXONB-UHFFFAOYSA-N

物化性质

• 熔点：
  -1 °C
• 沸点：
  401.18°C (rough estimate)
• 密度：
  1.0722 (rough estimate)
• 溶解度：
  6.35e-04 M
• 保留指数：
  2270;2270
• 稳定性/保质期：
  在常温常压下保持稳定，应避免与不相容的材料以及强氧化剂接触。

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  24
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.888
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S39
• 危险类别码：
  R36
• 海关编码：
  2918990090
• 储存条件：
  密封储存，应存放在阴凉干燥的库房中。

SDS

Name:	Bis(2-Ethoxyethyl) Sebacate 93% (GC) Material Safety Data Sheet
Synonym:	None known
CAS:	624-10-2

Section 1 - Chemical Product MSDS Name:Bis(2-Ethoxyethyl) Sebacate 93% (GC) Material Safety Data Sheet
Synonym:None known

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
624-10-2	Bis(2-Ethoxyethyl) Sebacate	93	210-829-1

Hazard Symbols: XI
Risk Phrases: 36

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 624-10-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: -1 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 93 deg C (> 199.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C18H34O6
Molecular Weight: 346.45

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 624-10-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Bis(2-Ethoxyethyl) Sebacate - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36 Irritating to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 39 Wear eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 624-10-2: No information available.
Canada
CAS# 624-10-2 is listed on Canada's NDSL List.
CAS# 624-10-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 624-10-2 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为产物：
  描述：

  乙二醇乙醚 、 癸二酸 在 对甲苯磺酸 、 苯 作用下， 生成 双(2-乙氧基乙基)癸二酸酯
  参考文献：
  名称：

  Tuttle; Kester, 1946, vol. 24, # 4, p. 163

  摘要：

  DOI：

文献信息

• [EN] ASYMMETRIC CYCLIC DIESTER COMPOUNDS<br/>[FR] COMPOSÉS DIESTERS CYCLIQUES ASYMÉTRIQUES
  申请人：FERRO CORP

  公开号：WO2011071674A1

  公开（公告）日：2011-06-16

  Compounds useful as plasticizers and the synthesis thereof are disclosed. In general, the invention includes mixed alkyl/aryl asymmetric cyclic diesters where the aryl and alkyl ester moieties are attached to a cyclic structure at vicinal carbons. The invention also includes synthetic processes of making such compounds. Blends of these asymmetric cyclic diesters with other plasticizers are demonstrated to be of use in plasticizing polymers.

  本文披露了作为增塑剂有用的化合物及其合成方法。一般来说，该发明包括混合烷基/芳基不对称环状二酯，其中芳基和烷基酯基连接到环状结构的邻位碳上。该发明还包括制备这类化合物的合成过程。这些不对称环状二酯与其他增塑剂的混合物被证明在增塑聚合物中具有用途。
• Asymmetric Cyclic Diester Compounds
  申请人：Bradshaw John D.

  公开号：US20090312470A1

  公开（公告）日：2009-12-17

  Compounds useful as plasticizers and the synthesis thereof are disclosed. In general, the invention includes mixed alkyl/aryl diesters where the aryl and alkyl ester moieties are attached to a cyclic structure at vicinal carbons. The invention also includes synthetic processes of making such compounds.

  本发明揭示了作为增塑剂有用的化合物及其合成方法。总的来说，该发明包括混合的烷基/芳基二酯，其中芳基和烷基酯基团附着在环状结构上的邻位碳上。该发明还包括制备此类化合物的合成过程。
• Copper aluminum borate
  申请人：AMOCO CORPORATION

  公开号：EP0194828A2

  公开（公告）日：1986-09-17

  Copper aluminum borate which is reducible under Temperature Programmed Reduction at a temperature no more than 350°C and/or has a surface area of at least 5 m2/g and a pore volume of at least 0.04 cc per gram.

  硼酸铝铜，可在温度不超过 350°C 的温度下进行温度还原，和/或表面积至少为 5 平方米/克，孔隙体积至少为 0.04 毫升/克。
• Method for forming electrophotographic image and electrographic device
  申请人：——

  公开号：US20030138718A1

  公开（公告）日：2003-07-24

  A method for forming an electrophotographic image and a device for forming an image on a transfer material by the steps for charging, exposing, developing and transferring, and recovering the toner remained untransferred in the step for cleaning by recovering, wherein the toner used in the step for developing has a total surface area ratio Z of additive, which is calculated by Z=(Ht·Wt)/(H·W), satisfies 0.5≦Z≦1.5, the electrophotographic photoconductor used comprises at least a photosensitive layer and a filler-containing protective layer provided on a conductive support in that order, and the angle of repose of the toner to the protective layer surface of the electrophotographic photoconductor is 30° or less.

  一种通过充电、曝光、显影和转印步骤在转印材料上形成电子照相图像的方法和在转印材料上形成图像的装置，以及通过回收清洁步骤回收未转印的墨粉，其中在显影步骤中使用的墨粉具有添加剂的总表面积比Z，其计算公式为Z&等于;(Ht-Wt)/(H-W)，满足0.5≦Z≦1.5，所用的电子照相光电导体至少包括一个感光层和一个含填料的保护层，保护层依次设置在导电支架上，墨粉与电子照相光电导体的保护层表面的倾角为30°或更小。
• Electrophotographic photoreceptor, method for manufacturing the photoreceptor, and image forming method and apparatus using the photoreceptor
  申请人：——

  公开号：US20040048178A1

  公开（公告）日：2004-03-11

  An electrophotographic photoreceptor including an electroconductive substrate; a photosensitive layer located overlying the electroconductive substrate and including a resin; and a surface layer including a filler and a binder resin, wherein the surface layer and the photosensitive layer have a continuous structure, and wherein the surface layer satisfies the following relationship: &sgr;≦D/5, wherein D represents an average of maximum thicknesses of the surface layer in units of micrometers in 20 segments of 5 &mgr;m wide when a portion of a cross section of the photoreceptor of 100 &mgr;m wide is divided into the 20 segments, and &sgr; represents a standard deviation of the 20 maximum thicknesses.

  一种电子照相感光器，包括导电基板；位于导电基板之上并包括树脂的感光层；以及包括填料和粘结剂树脂的表面层，其中表面层和感光层具有连续结构，并且其中表面层满足以下关系：&sgr;≦D/5，其中，D 表示将感光层 100 &mgr;m 宽的横截面的一部分分成 20 段时，20 段 5 &mgr;m 宽的表面层最大厚度的平均值（单位：微米），&sgr;表示 20 段最大厚度的标准偏差。

表征谱图