2-(4-nitrophenyl)pyrrolidino[3',4':1,2][60]fullerene

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2-(4-nitrophenyl)pyrrolidino[3',4':1,2][60]fullerene
• 化学式: C₆₈H₈N₂O₂
• 分子量: 884.824
• InChiKey: OXWYGTDIFCIBRQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.5
• 重原子数：
  72
• 可旋转键数：
  1
• 环数：
  34.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  57.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,4,6-三硝基氯苯 、 2-(4-nitrophenyl)pyrrolidino[3',4':1,2][60]fullerene 反应 0.25h， 以56%的产率得到N-(2,4,6-trinitrophenyl)-2-(4-nitrophenyl)fulleropyrrolidine
  参考文献：
  名称：

  微波辐照下无相转移催化剂无溶剂合成N-芳基富勒吡咯烷衍生物

  摘要：

  在没有相转移催化剂的情况下，在微波辐射下，通过 N-未取代的富勒吡咯烷和硝基氯苯的直接无溶剂反应合成了几种 N-芳基富勒吡咯烷衍生物。它们的结构已通过紫外-可见光、傅里叶变换-红外、1H NMR 和质谱法证实。

  DOI：

  10.1080/00397910903007061
• 作为产物：
  描述：

  对硝基苯甲醛 、 足球烯 、 聚甘氨酸 以 邻二氯苯 为溶剂， 反应 1.17h， 以15%的产率得到2-(4-nitrophenyl)pyrrolidino[3',4':1,2][60]fullerene
  参考文献：
  名称：

  Cycloadditions to [60]fullerene using microwave irradiation: A convenient and expeditious procedure

  摘要：

  Several Diels-Alder and 1,3-dipolar cycloadditions to C-60 were performed, under microwave irradiation, in a modified domestic microwave oven and a focused microwave reactor. Reactions proceed within minutes to afford the respective cycloadducts in similar or increased yields related to the described methods by conventional heating. This methodology simplifies the procedure and overcomes the drawbacks resulting from the long reaction times required under classical heating conditions. (C) 1997, Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(96)01150-7

文献信息

• Cycloadditions to [60]fullerene using microwave irradiation: A convenient and expeditious procedure
  作者：Pilar de la Cruz、Antonio de la Hoz、Fernando Langa、Beatriz Illescas、Nazario Martin

  DOI：10.1016/s0040-4020(96)01150-7

  日期：1997.2

  Several Diels-Alder and 1,3-dipolar cycloadditions to C-60 were performed, under microwave irradiation, in a modified domestic microwave oven and a focused microwave reactor. Reactions proceed within minutes to afford the respective cycloadducts in similar or increased yields related to the described methods by conventional heating. This methodology simplifies the procedure and overcomes the drawbacks resulting from the long reaction times required under classical heating conditions. (C) 1997, Elsevier Science Ltd.
• Solvent-Free Synthesis of <i>N</i>-Arylfulleropyrrolidine Derivatives Without Using Phase-Transfer Catalyst Under Microwave Irradiation
  作者：Bo Jin、Ru-Fang Peng、Wen-Ning Yang、Kai Wang、Bang-Qun Yuan、Shi-Jin Chu

  DOI：10.1080/00397910903007061

  日期：2010.2.2

  Several N-arylfulleropyrrolidine derivatives were synthesized via the direct solvent-free reactions of N-unsubstituted fulleropyrrolidines and nitrochlorobenzenes under microwave irradiation in the absence of phase-transfer catalysts. Their structures were confirmed by ultraviolet–visble, Fourier transform–infrared, 1H NMR, and mass spectrometry.

  在没有相转移催化剂的情况下，在微波辐射下，通过 N-未取代的富勒吡咯烷和硝基氯苯的直接无溶剂反应合成了几种 N-芳基富勒吡咯烷衍生物。它们的结构已通过紫外-可见光、傅里叶变换-红外、1H NMR 和质谱法证实。