双丙氨磷钠盐 | 71048-99-2

• 物质功能分类: 化学试剂 - 有机试剂 - 膦配体
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 双丙氨磷钠盐
• 中文别名: 双丙氨膦钠；双丙氨膦；2-[2-[[2-氨基-4-(羟基甲基磷酰基)丁酰基]氨基]丙酰氨基]丙酸钠
• CAS: 71048-99-2
• 化学式: C11H22N3NaO6P
• 分子量: 346.27
• InChiKey: LTQMGPNHTOPWMM-WQYNNSOESA-N

物化性质

• 熔点：
  160℃
• 沸点：
  793℃
• 闪点：
  >110°(230°F)
• 溶解度：
  PBS（pH 7.2）：10 mg/mL
• 稳定性/保质期：

  远离氧化物、日光、热和酸。

计算性质

• 辛醇/水分配系数(LogP)：
  -1.68
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  159
• 氢给体数：
  5
• 氢受体数：
  7

安全信息

• 危险等级：
  6.1

文献信息

• Herbicidal composition and weeding method
  申请人：NIHON NOHYAKU CO., LTD.

  公开号：EP0595126A1

  公开（公告）日：1994-05-04

  The present invention relates to a herbicidal composition containing as active ingredients at least one organophosphorus compound and 3-substituted phenylpyrazole derivative of the general formula (I): [wherein R is -Y¹R³, -Y²CH(R⁴)CO-OR⁵, -COOCH(R⁴)CO-Y¹R⁵ or -COOR⁶ (R³, R⁴, R⁵, R⁶, Y¹ and Y² are specified groups), R¹ is a lower alkyl group, R² is a hydrogen atom, a lower alkyl group or a lower haloalkyl group, X¹ and X², which may be the same or different, are halogen atoms, Y is -O-, -S-, -SO- or -SO₂-, and n is zero or 1]; and a weeding method using said composition.

  本发明涉及一种除草组合物，其活性成分含有至少一种有机磷化合物和通式（I）的 3-取代苯基吡唑衍生物： [其中 R 是 -Y¹R³、-Y²CH(R⁴)CO-OR⁵、-COOCH(R⁴)CO-Y¹R⁵ 或 -COOR⁶（R³、R⁴、R⁵、R⁶、Y¹ 和 Y² 是指定的基团），R¹ 是低级烷基，R² 是氢原子、X¹和 X²可以是相同或不同的卤素原子，Y 是-O-、-S-、-SO-或-SO₂-，n 是 0 或 1]；以及使用所述组合物的除草方法。
• Herbicidal compositions for tolerant or resistant rice crops
  申请人：——

  公开号：US20010031704A1

  公开（公告）日：2001-10-18

  Herbicide combinations (A)+(B), if appropriate in the presence of safeners, with an effective content of (A) broad-spectrum herbicides from the group (A1) glufosinate (salts) and related compounds (A2) glyphosate (salts) and related compounds such as sulfosate, (A3) imidazolinones such as imazethapyr, imazapyr, imazaquin, imazamox or their salts and (A4) herbicidal azoles from the group of the protoporphyrinogen oxidase inhibitors (PPO inhibitors) and (B) one or more herbicides from the group consisting of (B0) one or more structurally different herbicides from the abovementioned group (A) or (B1) foliar- and soil-acting herbicides effective against selectively in rice monocotyledonous and dicotyledonous harmful plants (residual action) or (B2) herbicides which are effective selectively in rice against dicotyledonous harmful plants and/or sedges, and/or (B3) foliar-acting herbicides which are effective selectively in rice against monocotyledonous harmful plants, and/or (B4) foliar- and soil-acting herbicides which are effective selectively in rice against monocotyledonous harmful plants, herbicides from several of groups (B0) to (B4) are suitable for controlling harmful plants in rice which consists of tolerant or resistant mutants or transgenic rice plants and the rice crops are tolerant to the herbicides (A) and (B), if appropriate in the presence of safeners, which are contained in the combination.

  除草剂组合(A)+(B)，在有安全剂存在的情况下，有效含量为 (A) 以下組別的廣譜除草劑 (A1) 草铵膦（盐类）及相关化合物 (A2) 草甘膦（盐类）及相关化合物，如磺酸盐、 (A3) 咪唑啉酮类，例如咪草烟、咪草烟、咪草喹、咪草烟或其盐类，以及 (A4) 原卟啉原氧化酶抑制剂（PPO 抑制剂）类除草唑 以及 (B) 以下組別中的一種或多種除草劑 (B0) 上述（A）组中一种或多种结构不同的除草剂，或 (B1) 对水稻单子叶和双子叶有害植物选择性有效的叶面和土壤作用除草剂（残留作用）或 (B2) 在水稻中选择性地对双子叶有害植物和/或莎草有效的除草剂，和/或 (B3) 在水稻中选择性地对单子叶有害植物有效的叶面作用除草剂，和/或 (B4) 在水稻中对单子叶有害植物有效的叶面和土壤作用除草剂、 (B0)至(B4)组中的几种除草剂 适用于控制由耐受性或抗性突变体或转基因水稻植株组成的水稻中的有害植物，且水稻作物对除草剂(A)和(B)有耐受性（如有安全剂存在则适当），这些除草剂包含在组合物中。
• HERBICIDAL COMPOSITIONS FOR TOLERANT OR RESISTANT MAIZE CROPS
  申请人：——

  公开号：US20020094934A1

  公开（公告）日：2002-07-18

  Herbicide combinations (A)+(B), if appropriate in the presence of safeners, with an effective content of (A) broad-spectrum herbicides from the group (A1) glufosinate (salts) and related compounds (A2) glyphosate (salts) and related compounds such as sulfosate, (A3) imidazolinones, (A4) herbicidal azoles from the group of the protoporphyrinogen oxidase inhibitors (PPO inhibitors) (A5) cyclohexanedione herbicides and (A6) heteroaryloxyphenoxypropionic acid herbicides and (B) one or more herbicides from the group of the compounds consisting of (B0) one or more structurally different herbicides from the abovementioned group (A) or (B1) foliar- and soil-acting herbicides against monocotyledonous and dicotyledonous harmful plants or (B2) herbicides which can be employed selectively in maize against dicots, or (B3) foliar- and soil-acting herbicides which can be employed selectively in maize, predominantly against dicotyledonous harmful plants, or herbicides from several of groups (B0) to (B3) are suitable for controlling harmful plants in maize which consists of tolerant or resistant mutants or transgenic maize plants and the maize crops are tolerant to the herbicides (A) and (B), if appropriate in the presence of safeners, which are contained in the combination.

  除草剂组合(A)+(B)，在有安全剂存在的情况下，有效含量为 (A) 以下組別的廣譜除草劑 (A1) 草铵膦（盐类）及相关化合物 (A2) 草甘膦（盐类）及相关化合物，如磺酸盐、 (A3) 咪唑啉酮类、 (A4) 原卟啉原氧化酶抑制剂（PPO 抑制剂）类除草唑 (A5) 环己二酮除草剂和 (A6) 杂芳基氧基苯氧基丙酸除草剂和 (B) 由以下化合物组成的组中的一种或多种除草剂 (B0)一种或多种结构不同于上述(A)组的除草剂或 (B1) 针对单子叶和双子叶有害植物的叶面和土壤作用除草剂，或 (B2) 可在玉米中选择性地用于防治双子叶植物的除草剂，或 (B3) 可在玉米中选择性使用的叶面和土壤作用除草剂，主要针对双子叶有害植物、 或（B0）至（B3）组中的几种除草剂 适用于控制由耐受性或抗性突变体或转基因玉米植物组成的玉米中的有害植物，且玉米作物对除草剂（A）和（B）具有耐受性（如有安全剂存在），这些除草剂包含在组合物中。
• HERBICIDAL COMPOSITIONS FOR TOLERANT OR RESISTANT CEREAL CROPS
  申请人：——

  公开号：US20030022792A1

  公开（公告）日：2003-01-30

  Herbicide combinations (A)+(B), if appropriate in the presence of safeners, with an effective content of (A) broad-spectrum herbicides from the group (A1) glufosinate (salts) and related compounds (A2) glyphosate (salts) and related compounds such as sulfosate, (A3) imidazolinones such as imazethapyr, imazapyr, imazaquin, imazamox or their salts and (A4) herbicidal azoles from the group of the protoporphyrinogen oxidase inhibitors (PPO inhibitors) and (B) one or more herbicides from the group of the compounds consisting of (B0) one or more structurally different herbicides from the abovementioned group (A) and/or (B1) foliar- and/or soil-acting herbicides which are particularly effective selectively in cereals against monocotyledonous harmful plants and/or (B2) predominantly foliar-acting herbicides which are effective selectively in cereals against monocotyledonous and dicotyledonous harmful plants and/or (B3) foliar- and soil-acting herbicides which are effective selectively in cereals against dicots and monocots and/or (B4) foliar-acting herbicides which are effective selectively in cereals against monocotyledonous and dicotyledonous harmful plants, are suitable for controlling harmful plants in cereal which consists of tolerant or resistant mutants or transgenic cereal plants and the cereal crops are tolerant to the herbicides (A) and (B), if appropriate in the presence of safeners, which are contained in the combination.

  除草剂组合(A)+(B)，在有安全剂存在的情况下，有效含量为 (A) 以下組別的廣譜除草劑 (A1) 草铵膦（盐类）及相关化合物 (A2) 草甘膦（盐类）及相关化合物，如磺酸盐、 (A3) 咪唑啉酮类，例如咪草烟、咪草烟、咪草喹、咪草烟或其盐类，以及 (A4) 原卟啉原氧化酶抑制剂（PPO 抑制剂）类除草唑，以及 (B) 由以下成分组成的化合物组中的一种或多种除草剂 (B0) 一种或多种结构不同于上述（A）组的除草剂和/或 (B1) 在谷物中对单子叶有害植物特别有效的叶面和/或土壤作用除草剂，和/或 (B2) 在谷物中对单子叶和双子叶有害植物选择性有效的以叶面作用为主的除草剂，和/或 (B3) 在谷物中对双子叶和单子叶植物选择性有效的叶面和土壤作用除草剂，和/或 (B4) 在谷物中选择性地对单子叶和双子叶有害植物有效的叶面作用除草剂，适用于控制由耐受性或抗性突变体或转基因谷物植物组成的谷物中的有害植物，且谷物作物对除草剂(A)和(B)有耐受性（如适当，在有安全剂存在的情况下），这些除草剂包含在组合物中。
• Herbicidal compositions for tolerant or resistant maize crops
  申请人：Hacker Erwin

  公开号：US20060111240A1

  公开（公告）日：2006-05-25

  Herbicide combinations (A)+(B), if appropriate in the presence of safeners, with an effective content of (A) broad-spectrum herbicides from the group (A1) glufosinate (salts) and related compounds (A2) glyphosate (salts) and related compounds such as sulfosate, (A3) imidazolinones, (A4) herbicidal azoles from the group of the protoporphyrinogen oxidase inhibitors (PPO inhibitors) (A5) cyclohexanedione herbicides and (A6) heteroaryloxyphenoxypropionic acid herbicides and (B) one or more herbicides from the group of the compounds consisting of (B0) one or more structurally different herbicides from the abovementioned group (A) or (B1) foliar- and soil-acting herbicides against monocotyledonous and dicotyledonous harmful plants or (B2) herbicides which can be employed selectively in maize against dicots, or (B3) foliar- and soil-acting herbicides which can be employed selectively in maize, predominantly against dicotyledonous harmful plants, or herbicides from several of groups (B0) to (B3) are suitable for controlling harmful plants in maize which consists of tolerant or resistant mutants or transgenic maize plants and the maize crops are tolerant to the herbicides (A) and (B), if appropriate in the presence of safeners, which are contained in the combination.

  除草剂组合物(A)+(B)，在有安全剂存在的情况下，其有效含量为：(A) 来自草铵膦(盐类)及相关化合物组的广谱除草剂(A1) 草铵膦(盐类)及相关化合物，如磺酸盐，(A2) 草甘膦(盐类)及相关化合物，如磺酸盐，(A3) 咪唑啉酮类、(A4) 原卟啉原氧化酶抑制剂（PPO 抑制剂）组中的唑类除草剂 (A5) 环己二酮除草剂和 (A6) 杂芳基氧基苯氧基丙酸除草剂，以及 (B) 由以下化合物组成的化合物组中的一种或多种除草剂 (B0) 一种或多种结构上不同于上述(A)组的除草剂，或 (B1) 叶面和土壤作用除草剂。或 (B1) 针对单子叶和双子叶有害植物的叶面和土壤作用除草剂；或 (B2) 可在玉米中选择性地用于防治双子叶植物的除草剂、或(B3)可在玉米中选择性使用的叶面和土壤作用除草剂，主要针对双子叶有害植 物，或(B0)至(B3)组中的几种除草剂适用于控制由耐受性或抗性突变体或转基因玉米植 物组成的玉米中的有害植物，且玉米作物对除草剂(A)和(B)有耐受性（如适当，在有安全 剂存在的情况下），这些除草剂包含在组合物中。