bis-(4-methyl-pent-3-enyl)-ether

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis-(4-methyl-pent-3-enyl)-ether
• 英文别名: Bis-(4-methyl-pent-3-enyl)-aether；2-Methyl-5-(4-methylpent-3-enoxy)pent-2-ene；2-methyl-5-(4-methylpent-3-enoxy)pent-2-ene
• 化学式: C₁₂H₂₂O
• 分子量: 182.306
• InChiKey: FFFNKNYOBKPALK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-环丙基-1-甲基乙醇 在 硫酸 作用下， 生成 bis-(4-methyl-pent-3-enyl)-ether
  参考文献：
  名称：

  Faworskaja et al., Zhurnal Obshchei Khimii, 1953, vol. 23, p. 1878,1882; engl. Ausg. S. 1985, 1989

  摘要：

  DOI：

文献信息

• OPTICALLY ACTIVE BISOXAZOLINE COMPOUND, ASYMMETRIC CATALYST, AND METHOD FOR PRODUCING OPTICALLY ACTIVE CYCLOPROPANE COMPOUND USING SAID CATALYST
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2781522A1

  公开（公告）日：2014-09-24

  An optically active bisoxazoline compound represented by formula (1): wherein R1, R2 and R3 each independently represent an alkyl group having 1 to 8 carbon atoms, a phenyl group or a benzyl group, n represents an integer of 0 to 3 and * represents an asymmetric center.

  由式 (1) 代表的光学活性双噁唑啉化合物： 其中 R1、R2 和 R3 各自独立地代表具有 1 至 8 个碳原子的烷基、苯基或苄基，n 代表 0 至 3 的整数，* 代表不对称中心。
• Process for production of optically active cyclopropanecarboxylate compound
  申请人：Itagaki Makoto

  公开号：US20090048450A1

  公开（公告）日：2009-02-19

  A process for production of an optically active cyclopropanecarboxylate compound represented by the formula (5): wherein R 6 , R 7 , R 8 and R 9 represent a C1-C6 alkyl group or the like and R 10 represents a C1-C6 alkyl group, which comprises reacting an olefin represented by the formula (3): wherein R 6 , R 7 , R 8 and R 9 are as described above, with a diazoacetic acid ester represented by the formula (4): N 2 CHCO 2 R 10 (4) wherein R 10 is as described above, in the presence of an asymmetric copper complex obtained by mixing (A) at least one monovalent or divalent copper compound, (B) at least one optically active bisoxazoline compound represented by the formula (1): wherein R 1 and R 2 represent a C1-C6 alkyl group or the like; R 3 represents a tert-butyl group or the like; and R 4 and R 5 are the same and represent C1-C3 alkyl groups or the like, and (C) at least one boron compound represented by the formula (2): wherein A represents a trityl group or the like, X represents a fluorine atom or the like, and n represents an integer of 1 to 5.
• US7671210B2
  申请人：——

  公开号：US7671210B2

  公开（公告）日：2010-03-02
• US7705165B2
  申请人：——

  公开号：US7705165B2

  公开（公告）日：2010-04-27