4,4-Dimethoxy-5-[(2,2-dimethoxy)ethyl]-2,3,5-trichlorocyclopent-2-en-1-one

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,4-Dimethoxy-5-[(2,2-dimethoxy)ethyl]-2,3,5-trichlorocyclopent-2-en-1-one
• 英文别名: 2,3,5-trichloro-4,4-dimethoxy-5-(2,2-dimethoxyethyl)cyclopent-2-enone；2,3,5-trichloro-5-(2,2-dimethoxyethyl)-4,4-dimethoxycyclopent-2-en-1-one
• 化学式: C₁₁H₁₅Cl₃O₅
• 分子量: 333.596
• InChiKey: QKQDJDYCSACYCV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  甲醇 、 4,4-Dimethoxy-5-[2-(1,2,4-trioxolan-3-yl)methyl]-2,3,5-trichlorocyclopent-2-en-1-one 在 盐酸 作用下， 反应 12.0h， 以60%的产率得到4,4-Dimethoxy-5-[(2,2-dimethoxy)ethyl]-2,3,5-trichlorocyclopent-2-en-1-one
  参考文献：
  名称：

  Some aspects of selective ozonolysis of 5-allyl(allenyl)-4,4-dimethoxy-2,3,5-trichlorocyclopent-2-enones and their 3-morpholino derivatives

  摘要：

  Ozonolysis of the title cyclopentenones proceeds selectively with the participation of exocyclic multiple bonds. In the case of 5-allyl derivatives, the corresponding ozonides were isolated along with the expected products.

  DOI：

  10.1007/bf02494561

文献信息

• Vostrikov; Torosyan; Akbutina, Russian Journal of Organic Chemistry, 1999, vol. 35, # 4, p. 628 - 629
  作者：Vostrikov、Torosyan、Akbutina、Vyrypaev、Miftakhov

  DOI：——

  日期：——
• Some aspects of selective ozonolysis of 5-allyl(allenyl)-4,4-dimethoxy-2,3,5-trichlorocyclopent-2-enones and their 3-morpholino derivatives
  作者：N. S. Vostrikov、S. A. Torosyan、F. A. Akbutina、E. M. Vyrypaev、L. V. Spirikhin、M. S. Miftakhov

  DOI：10.1007/bf02494561

  日期：1999.2

  Ozonolysis of the title cyclopentenones proceeds selectively with the participation of exocyclic multiple bonds. In the case of 5-allyl derivatives, the corresponding ozonides were isolated along with the expected products.