4-pentafluorobenzyloxybenzyl alcohol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-pentafluorobenzyloxybenzyl alcohol
• 英文别名: 4-(2,3,4,5,6-Pentafluorobenzyloxy)benzyl alcohol；[4-[(2,3,4,5,6-pentafluorophenyl)methoxy]phenyl]methanol
• 化学式: C₁₄H₉F₅O₂
• 分子量: 304.216
• InChiKey: TZUNQAJUXKQIJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  对羟基苯甲醇 、 α-溴-2,3,4,5,6-五氟甲基苯酸酯 在 18-冠醚-6 、 sodium carbonate 作用下， 以 丙酮 为溶剂， 反应 72.0h， 以82%的产率得到4-pentafluorobenzyloxybenzyl alcohol
  参考文献：
  名称：

  Synthesis and surface properties of a fluorinated polyether

  摘要：

  A new polyether consisting of alternate fluorinated/non-fluorinated phenylene units in the backbone has been synthesized via polycondensation of an AB monomer. At room temperature, the polymer film exhibits a low surface energy that is comparable to poly(tetrafluoroethylene) (PTFE). However, as the temperature is raised above a particular level, the surface energy of the polymer films starts to increase. Morphological measurements suggest that a smooth thin polymer film can be formed by solvent casting, but it spontaneously dewets the substrate surface when thermally annealed.(C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(02)00063-5