(Z)-4-(trifluoromethyl)benzyl 3-[tris(trimethylsilyl)silyl]propenoate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (Z)-4-(trifluoromethyl)benzyl 3-[tris(trimethylsilyl)silyl]propenoate
• 英文别名: [4-(trifluoromethyl)phenyl]methyl (Z)-3-tris(trimethylsilyl)silylprop-2-enoate
• 化学式: C₂₀H₃₅F₃O₂Si₄
• 分子量: 476.834
• InChiKey: DIOPFTBVAFKZAJ-PFONDFGASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.54
• 重原子数：
  29.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  4-(三氟甲基)苄醇 在 三氟化硼乙醚 作用下， 反应 24.0h， 生成 (Z)-4-(trifluoromethyl)benzyl 3-[tris(trimethylsilyl)silyl]propenoate
  参考文献：
  名称：

  A mild and efficient Si (111) surface modification via hydrosilylation of activated alkynes

  摘要：

  报道了一种新的硅表面改性方法，通过室温下的氢化硅烷化实现有机基团的引入。将氢终止的硅（111）表面与活化炔（如丙酸酯、丙炔酸、丁-3-炔-2-酮、丙腈和苯基乙炔）在室温下反应24至40小时，得到改性的表面。通过XPS分析，覆盖率估计为31-56%。这种表面改性方法温和、高效且程序简单。预期这些改性后的新型表面具有有趣的应用。

  DOI：

  10.1039/b511535c

文献信息

• Modification and chemical transformation of Si(111) surface
  作者：Yang Liu、Shoko Yamazaki、Suguru Izuhara

  DOI：10.1016/j.jorganchem.2006.09.048

  日期：2006.12

  Modification of hydrogen-terminated Si(111) surfaces by hydrosilylation of activated alkenes and further chemical transformation of the modified surfaces is reported. A Si(111)-H surface was reacted with activated alkenes such as acrylate esters, acrylonitrile, and maleic anhydride under mild conditions to give modified surfaces with terminal functional groups. A modified surface with a terminal ester group was reduced by LiAlH4 to give a hydroxy-terminated surface, and the hydroxy-terminated surface was transformed to a bromo-terminated surface. XPS analysis revealed that the brominated surface ( Si(111)-CH2CH2CH2Br) had 32% coverage with the 3-bromopropyl group. Ester and amide formation reactions were carried out on hydroxy- and carboxy-terminated Si surfaces by reaction with tert-butoxycarbonyl glycine, glycine tort-butyl ester, 2,2,2-trifluoroethanol and 4-trifluoromethylbenzyl alcohol in the presence of carbodiimide. XPS characterization indicated that the esters and amide were successfully formed with coverage ranging from 16% to 58%. Coverage ratios of octadecyl ester modified surfaces were also estimated by combination of surface reduction and gas chromatography analysis to be 25-35%. (c) 2006 Elsevier B.V. All rights reserved.
• A mild and efficient Si (111) surface modification via hydrosilylation of activated alkynes
  作者：Yang Liu、Shoko Yamazaki、Shinichi Yamabe、Yoshihiro Nakato

  DOI：10.1039/b511535c

  日期：——

  A new Si surface modification with organic groups via hydrosilylation at room temperature is reported. A hydrogen-terminated Si (111) surface was reacted with activated alkynes such as propiolate esters, propiolic acid, but-3-yne-2-one, propiolonitrile and phenylacetylene at room temperature for 24–40 h to give modified surfaces. The coverage ratio was estimated to be 31–56% by XPS analysis. This surface modification method is mild, highly efficient and procedurally simple. The novel surfaces modified with various organic functional groups are expected to have interesting utilities.

  报道了一种新的硅表面改性方法，通过室温下的氢化硅烷化实现有机基团的引入。将氢终止的硅（111）表面与活化炔（如丙酸酯、丙炔酸、丁-3-炔-2-酮、丙腈和苯基乙炔）在室温下反应24至40小时，得到改性的表面。通过XPS分析，覆盖率估计为31-56%。这种表面改性方法温和、高效且程序简单。预期这些改性后的新型表面具有有趣的应用。