(11R,17S)-11,17-dimethylhentriacontane

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: (11R,17S)-11,17-dimethylhentriacontane
• 化学式: C₃₃H₆₈
• 分子量: 464.903
• InChiKey: ONSSOFXWXSGWSM-SAIUNTKASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.5
• 重原子数：
  33
• 可旋转键数：
  28
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (11R,17S)-11,17-dimethylhentriacont-7,13-diene 在 palladium on activated charcoal 氢气 作用下， 以 乙酸乙酯 为溶剂， 以80%的产率得到(11R,17S)-11,17-dimethylhentriacontane
  参考文献：
  名称：

  Synthesis of (11R,17S)-11,17-dimethylhentriacontane: a communication pheromone of ant Camponotus vagus

  摘要：

  The convergent synthesis in high enantiomeric and diastereoisomeric purity of (11R,17S)-11, 17-dimethylhentriacontane, a communication pheromone of ant Camponotus vagus is described. The stereogenic centres were introduced from commercially available (R)-citronellol and (R)-citronellal. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0957-4166(96)00234-0

文献信息

• Synthesis of (11R,17S)-11,17-dimethylhentriacontane: a communication pheromone of ant Camponotus vagus
  作者：Delphine Pempo、Jacques Viala、Jean-Luc Parrain、Maurice Santelli

  DOI：10.1016/0957-4166(96)00234-0

  日期：1996.7

  The convergent synthesis in high enantiomeric and diastereoisomeric purity of (11R,17S)-11, 17-dimethylhentriacontane, a communication pheromone of ant Camponotus vagus is described. The stereogenic centres were introduced from commercially available (R)-citronellol and (R)-citronellal. Copyright (C) 1996 Elsevier Science Ltd