quercetin 3-O-β-D-(3-O-acetyl)glucopyranosyl-7-O-α-L-rhamnopyranoside

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: quercetin 3-O-β-D-(3-O-acetyl)glucopyranosyl-7-O-α-L-rhamnopyranoside
• 英文别名: Sinocrassoside B6；[(2S,3R,4S,5R,6R)-2-[2-(3,4-dihydroxyphenyl)-5-hydroxy-4-oxo-7-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxychromen-3-yl]oxy-3,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl] acetate
• 化学式: C₂₉H₃₂O₁₇
• 分子量: 652.563
• InChiKey: YJEABCJJBPAPGH-HKJJUKGTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  46
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  272
• 氢给体数：
  9
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  quercetin 3-O-β-D-(3-O-acetyl)glucopyranosyl-7-O-α-L-rhamnopyranoside 在 水 、 potassium hydroxide 作用下， 以 1,4-二氧六环 为溶剂， 反应 1.0h， 生成 槲皮素 3-葡糖苷 7-鼠李糖苷
  参考文献：
  名称：

  Further acylated flavonol bisdesmosides fromSinocrassula indica

  摘要：

  Further investigation on the whole herbs of Sinocrassula indica (Crassulaceae) led to the isolation of four new acylated flavonol bisdesmosides, sinocrassosides A(13) (1), B-6 (2), B-7 (3), and D-4 (4), together with kaempferol 3-O--d-(6-O-acetyl)glucopyranosyl-7-O--l-rhamnopyranoside (5). Their structures were established by spectral and chemical methods.

  DOI：

  10.1080/10286020.2013.800973

文献信息

• Further acylated flavonol bisdesmosides from<i>Sinocrassula indica</i>
  作者：Hai-Hui Xie、Masayuki Yoshikawa

  DOI：10.1080/10286020.2013.800973

  日期：2013.8

  Further investigation on the whole herbs of Sinocrassula indica (Crassulaceae) led to the isolation of four new acylated flavonol bisdesmosides, sinocrassosides A(13) (1), B-6 (2), B-7 (3), and D-4 (4), together with kaempferol 3-O--d-(6-O-acetyl)glucopyranosyl-7-O--l-rhamnopyranoside (5). Their structures were established by spectral and chemical methods.