四丙基高氯酸铵 - CAS号 15780-02-6

物化性质

熔点：

238-240 °C
密度：

1.1057 (rough estimate)

计算性质

辛醇/水分配系数(LogP)：

-1.31
重原子数：

18
可旋转键数：

8
环数：

0.0
sp3杂化的碳原子比例：

1.0
拓扑面积：

74.3
氢给体数：

0
氢受体数：

4

安全信息

危险等级：

5.1
危险品标志：

O,Xi
安全说明：

S17,S26,S37/39
危险类别码：

R8,R36/37/38
海关编码：

2923900090
危险品运输编号：

UN 1479
包装等级：

III
危险类别：

5.1

SDS

SDS：9507a690f81480e39b01b249d131294a

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Name:	Tetrapropylammonium Perchlorate Material Safety Data Sheet
Synonym:	1-Propanaminium, N,N,N-Tripropyl-, Perchlorate
CAS:	15780-02-6

Section 1 - Chemical Product MSDS Name:Tetrapropylammonium Perchlorate Material Safety Data Sheet
Synonym:1-Propanaminium, N,N,N-Tripropyl-, Perchlorate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
15780-02-6	1-Propanaminium, N,N,N-Tripropyl-, Per	ca 100	239-874-5

Hazard Symbols: O
Risk Phrases: 8

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Contact with combustible material may cause fire.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Contact professional fire-fighters immediately. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 15780-02-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: almost white
Odor: ammonia-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 240-242C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H28ClNO4
Molecular Weight: 285.80

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable. Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents, strong oxidants.
Incompatibilities with Other Materials:
Reducing agents, finely powdered metals, organic materials, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, oxides of chlorine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 15780-02-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Propanaminium, N,N,N-Tripropyl-, Perchlorate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: OXIDIZING SOLID, N.O.S.*
Hazard Class: 5.1
UN Number: 1479
Packing Group: III
IMO
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: III
RID/ADR
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 15780-02-6: No information available.
Canada
CAS# 15780-02-6 is listed on Canada's DSL List.
CAS# 15780-02-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 15780-02-6 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

四丙基高氯酸铵可用作电解液来制备超级电容器。超级电容器是一种介于充电电池和传统电容器之间的新型能源器件，兼具电容与电池的双重功能。相比普通电池，它的功率密度更高；相较于传统物理电容，其能量密度更大。与普通电容器及电池相比，超级电容器体积更小、容量更大、充电速度更快、循环寿命更长、放电效率更高、工作温度范围更宽广、可靠性更好且无污染无需维护。因此，它是一种新型、高效、实用的能量储存装置，在电力、铁路、交通、医疗、军工和通讯等领域有着极其广泛的应用前景。

反应信息

作为反应物：

描述：

nitrosyl(3,7-dimethyl-3',7'-dihydro-2,2',8,8',12,13,17,18-octaethylporphyrinato)cobalt(II) 、四丙基高氯酸铵以二氯甲烷为溶剂，生成 nitrosyl(3,7-dimethyl-3',7'-dihydro-2,2',8,8',12,13,17,18-octaethylporphyrinato)cobalt(II) perchlorate

参考文献：

名称：

卟啉、二氢卟酚和异菌绿素的钴 (II) 亚硝基阳离子自由基。亚硝酸盐和亚硫酸盐还原酶模型以及对 A1u 血红素自由基的影响

摘要：

L'oxydation de complexes «nitrosyle» de Cobalt(II) de different porphyrines Fournit des radicaux π-cationiques de Co(II) NO. Les especes oxydees sont caracterisees parelectrochimie, spectroscopie visible, IR et RPE。Ce sont des especes 介绍了 dans desases qui catalysent des reductions de亚硝酸盐 en NH 3 ou oxyde Nique（亚硝酸盐还原酶）。在 a d'autre part recemment identifie l'isobacteriochlorine de coco dans des 亚硫酸盐还原酶

DOI：

10.1021/ja00311a073
作为产物：

描述：

四丙基溴化铵在 sodium perchlorate 作用下，生成四丙基高氯酸铵

参考文献：

名称：

4-甲基-戊丹-2-一†中高氯酸季铵盐和苦味酸盐的电导率和解离常数†

摘要：

在25° C下研究了14个离子载体在4-甲基-戊烷-2-酮中的离解，即7个对称的（C 1至C 7）和5个不对称的季铵高氯酸根盐和2个四烷基苦味酸铵（均具有线性烃链）。 C（εr = 12.92）使用电导法。季铵阳离子，CT的缔合常数的值+，与CLO 4 -变化从（7.4±0.3）·10 3 L·摩尔-1为四甲基铵至（2.4±0.1）·10 3 L·摩尔-1用于四己基和四庚基铵；对Ct +的大小有明显的依赖性，特别是对于对称阳离子而言，是显而易见的。限制摩尔电导率的值Λ 0 / S·摩尔-1 ·厘米2变化从122.8至90.0（±0.7）。Λ的情节0相对于总的van der阳离子的范德华体积，的倒数立方根V的Ct -1/3，靠近线性高达四戊和十六，而对于较大的阳离子（以21至28个碳原子）在Λ 0值留下几乎是恒定的。同时，具有相同V Ct值的对称和不对称阳离子具有相同的迁移率。

DOI：

10.1021/je9008969
作为试剂：

描述：

三甲基氯硅烷、苯甲酸苯酯在四丙基高氯酸铵作用下，以乙腈为溶剂，以64%的产率得到苯甲醛

参考文献：

名称：

Elektroreduktion organischer Verbindungen. 22. Darstellung aromatischer Aldehyde durch Elektroreduktion von Estern und Amiden in Gegenwart von Chlortrimethylsilan

摘要：

The electroreduction of aromatic esters 1 and amides 9 in dry acetonitrile in the presence of chlorotrimethylsilane 2 affords aldehydes 3 in moderate to good yields depending on the aromatic substituents. The formation of 3 and characteristic by-products is discussed.

DOI：

10.1002/prac.19933350304

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文献信息

Process for the preparation of an indole derivative

申请人：F. Hoffmann-La Roche AG

公开号：EP2011783A1

公开（公告）日：2009-01-07

A process for the preparation of indole derivatives of formula (I): which are useful as intermediates in the preparation of i.a. pharmaceutically active compounds.

一种制备式(I)吲哚衍生物的方法：这些衍生物在制备具有药用活性的化合物中起中间体作用。
[EN] DITHIENYLPYRROLE-BASED BIOSENSORS AND METHODS FOR THEIR PREPARATION AND USE<br/>[FR] BIOCAPTEURS À BASE DE DITHIÉNYLPYRROLE ET LEURS PROCÉDÉS DE PRÉPARATION ET D'UTILISATION

申请人：UNIV JIANGNAN

公开号：WO2014101193A1

公开（公告）日：2014-07-03

Dithienylpyrrole compounds, compositions containing dithienylpyrrole polymers, and methods for making the compounds and compositions are disclosed herein. The compositions containing dithienylpyrrole polymers, can for example, be used as conducting polymers in biosensors for detecting analytes in a sample.

本文披露了二噻吩吡咯化合物，含有二噻吩吡咯聚合物的组合物，以及制备这些化合物和组合物的方法。含有二噻吩吡咯聚合物的组合物，例如可用作生物传感器中的导电聚合物，用于检测样品中的分析物。
Sulfonium salt, curable composition, ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate

申请人：Tsuchimura Tomotaka

公开号：US20070197677A1

公开（公告）日：2007-08-23

A sulfonium salt is provided that has a cation represented by Formula (II) (R 1′ to R 13′ in Formula (II) independently denote a hydrogen atom or a substituent, and may be bonded to each other to form a ring, provided that at least one of R 1′ to R 8′ denotes a halogen atom or a haloalkyl group). There are also provided a curable composition that includes the sulfonium salt, and an ink composition that includes the curabie composition. Furthermore, there are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.

提供一种具有由化学式（II）表示的阳离子的硫铵盐（其中，化学式（II）中的R1'到R13'独立地表示氢原子或取代基，并且它们可以结合在一起形成环，前提是R1'到R8'中至少有一个表示卤素原子或卤代烷基）。还提供了包括该硫铵盐的可固化组合物，以及包括该可固化组合物的油墨组合物。此外，还提供了一种采用该油墨组合物的喷墨记录方法，以及生产平版印刷版的工艺，其中该工艺包括将油墨组合物排放到亲水性支撑体上。本发明还包括由此获得的印刷材料和平版印刷版。
Electrode for active oxygen species and sensor using the electrode

申请人：Yuasa Makoto

公开号：US20050077192A1

公开（公告）日：2005-04-14

An electrode for active oxygen species comprising a conductive component with a polymer membrane of a metal porphyrin complex formed on the surface is disclosed. The electrode for active oxygen species can detect active oxygen species such as superoxide anion radicals, hydrogen peroxide, and .OH and other active radical species (NO, ONOO—, etc.) in any environment including in vivo environment as well as in vitro environment. The electrode thus can be used for specifying various diseases and examining active oxygen species in food or in water such as tap water and sewage water.

本发明公开了一种活性氧物种电极，其包括一个导电组件和形成在其表面上的金属卟啉复合物聚合物膜。该活性氧物种电极可以检测任何环境中的活性氧物种，包括体内环境和体外环境中的超氧阴离子自由基、过氧化氢和.OH等活性自由基物种（NO、ONOO-等）。因此，该电极可用于指定各种疾病，并检查食品或水中的活性氧物种，如自来水和污水。
Ink composition, inkjet recording method, printed material, method for producing planographic printing plate, and planographic printing plate

申请人：Tsuchimura Tomotaka

公开号：US20060178449A1

公开（公告）日：2006-08-10

An ink composition comprising a triarylsulfonium salt polymerization initiator containing at least one aryl skeleton having an electron attractive group as a substituent, a polymerizable compound, a sensitizing dye, and a colorant.

一种墨水组合物，包括三芳基硫鎓盐聚合引发剂，其中至少有一个含有电子吸引基团的芳基骨架作为取代基，可聚合化合物，敏化染料和着色剂。

四丙基高氯酸铵 | 15780-02-6

物质功能分类

分子结构分类

物化性质

计算性质

安全信息

SDS

制备方法与用途

反应信息

文献信息

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