2,4 dihydroxyphenyl-[6'-O-(3-hydroxy,3'-phenyl propanoyl)]-O-β-D-allopyranoside

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,4 dihydroxyphenyl-[6'-O-(3-hydroxy,3'-phenyl propanoyl)]-O-β-D-allopyranoside
• 英文别名: [(2R,3S,4R,5R,6S)-6-(2,4-dihydroxyphenoxy)-3,4,5-trihydroxyoxan-2-yl]methyl 3-hydroxy-3-phenylpropanoate
• 化学式: C₂₁H₂₄O₁₀
• 分子量: 436.416
• InChiKey: OZEKAUPQBXEBSZ-SLOQVBGBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  31
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  166
• 氢给体数：
  6
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  2,4 dihydroxyphenyl-[6'-O-(3-hydroxy,3'-phenyl propanoyl)]-O-β-D-allopyranoside 在 barium dihydroxide 作用下， 以 水 为溶剂， 反应 1.0h， 以2 mg的产率得到3-羟基-3-苯丙酸
  参考文献：
  名称：

  Polyphenolic Glycosides from African Proteaceae

  摘要：

  The phytochemical investigation of members of the genus Protea afforded a series of polyphenolic compounds (1-5) that were identified by 1D and 2D NMR experiments. Of these, 2-5 are new compounds. Chemical syntheses of 1-3 were performed in order to confirm the structures and to prepare additional material for biological evaluation.

  DOI：

  10.1021/np9902237

文献信息

• Polyphenolic Glycosides from African Proteaceae
  作者：L. Verotta、F. Orsini、F. Pelizzoni、G. Torri、C. B. Rogers

  DOI：10.1021/np9902237

  日期：1999.11.1

  The phytochemical investigation of members of the genus Protea afforded a series of polyphenolic compounds (1-5) that were identified by 1D and 2D NMR experiments. Of these, 2-5 are new compounds. Chemical syntheses of 1-3 were performed in order to confirm the structures and to prepare additional material for biological evaluation.