2-[3-(triethoxysilyl)propylcarbamoyloxy]nicotinic acid

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-[3-(triethoxysilyl)propylcarbamoyloxy]nicotinic acid
• 英文别名: 2-(3-Triethoxysilylpropylcarbamoyloxy)pyridine-3-carboxylic acid；2-(3-triethoxysilylpropylcarbamoyloxy)pyridine-3-carboxylic acid
• 化学式: C₁₆H₂₆N₂O₇Si
• 分子量: 386.477
• InChiKey: JYBOCPRRLJUFMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.31
• 重原子数：
  26
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  116
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2-羟基烟酸 、 异氰酸丙基三乙氧基硅烷 以 四氢呋喃 为溶剂， 反应 12.0h， 生成 2-[3-(triethoxysilyl)propylcarbamoyloxy]nicotinic acid
  参考文献：
  名称：

  Designing a family of luminescent hybrid materials by 3-(triethoxysilyl)-propyl isocyanate grafted 2-hydroxynicotinic acid bridge molecules

  摘要：

  The study concentrates on the syntheses of modified 2-hydroxynicotinic acid by 3-(triethoxysilyl)-propyl isocyanate (TESPIC) and the preparation of their corresponding organic-inorganic molecular-based hybrid material with the two components equipped with covalent bonds. The bridging unit is a derivative of 2-hydroxynicotinic acid which is utilized to coordinate to Tb3+, Eu3+ or Zn2+ and further occurred hydrolysis and polycondensation processes by functional triethoxysilyl groups. Ultraviolet absorption, phosphorescence spectra, and luminescence spectra were applied to characterize the photophysical properties of the obtained hybrid material and the above spectroscopic data present that the triplet energy of modified 2-hydroxynicotinic acid efficiently initiates the antenna effect and matches with the emissive energy level of metal ions. As a result, the intramolecular energy transfer process completed within these molecular-based hybrids and strong green or red emissions of Ln(3+) have been obtained. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.12.061

文献信息

• Designing a family of luminescent hybrid materials by 3-(triethoxysilyl)-propyl isocyanate grafted 2-hydroxynicotinic acid bridge molecules
  作者：Qian-Ming Wang、Bing Yan

  DOI：10.1016/j.jorganchem.2005.12.061

  日期：2006.8

  The study concentrates on the syntheses of modified 2-hydroxynicotinic acid by 3-(triethoxysilyl)-propyl isocyanate (TESPIC) and the preparation of their corresponding organic-inorganic molecular-based hybrid material with the two components equipped with covalent bonds. The bridging unit is a derivative of 2-hydroxynicotinic acid which is utilized to coordinate to Tb3+, Eu3+ or Zn2+ and further occurred hydrolysis and polycondensation processes by functional triethoxysilyl groups. Ultraviolet absorption, phosphorescence spectra, and luminescence spectra were applied to characterize the photophysical properties of the obtained hybrid material and the above spectroscopic data present that the triplet energy of modified 2-hydroxynicotinic acid efficiently initiates the antenna effect and matches with the emissive energy level of metal ions. As a result, the intramolecular energy transfer process completed within these molecular-based hybrids and strong green or red emissions of Ln(3+) have been obtained. (c) 2006 Elsevier B.V. All rights reserved.