N-(2-(1-butylpentyl)-3-butylheptyl)-N'-(1-hexylheptyl)-perylene-3,4:9,10-bis(dicarboximide)

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N-(2-(1-butylpentyl)-3-butylheptyl)-N'-(1-hexylheptyl)-perylene-3,4:9,10-bis(dicarboximide)
• 英文别名: 7-(3-Butyl-2-nonan-5-ylheptyl)-18-tridecan-7-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• 化学式: C₅₇H₇₆N₂O₄
• 分子量: 853.241
• InChiKey: RMBGLDGNRPVQJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.9
• 重原子数：
  63
• 可旋转键数：
  27
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5-bromononane 在 咪唑 、 lithium aluminium tetrahydride 、 sodium 、 ferric nitrate 作用下， 以 乙醚 、 氨 为溶剂， 反应 22.0h， 生成 N-(2-(1-butylpentyl)-3-butylheptyl)-N'-(1-hexylheptyl)-perylene-3,4:9,10-bis(dicarboximide)
  参考文献：
  名称：

  Persistent Fluorescence of Perylene Dyes by Steric Inhibition of Aggregation

  摘要：

  The control of the self-organisation of dye molecules in solution by bulky peripheral groups has been demonstrated. Consequently, fluorescent dyes could be prepared with a persistent fluorescence, even at very high concentrations because of a complete suppression of aggregation. Fluorescence quantum yields of unity were found. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(00)00452-x

文献信息

• Persistent Fluorescence of Perylene Dyes by Steric Inhibition of Aggregation
  作者：Heinz Langhals、Rami Ismael、Oktay Yürük

  DOI：10.1016/s0040-4020(00)00452-x

  日期：2000.7

  The control of the self-organisation of dye molecules in solution by bulky peripheral groups has been demonstrated. Consequently, fluorescent dyes could be prepared with a persistent fluorescence, even at very high concentrations because of a complete suppression of aggregation. Fluorescence quantum yields of unity were found. (C) 2000 Elsevier Science Ltd. All rights reserved.