2,4,6-tris(3-(1H-pyrazol-1-yl)phenyl)-1,3,5-triazine | 352196-01-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2,4,6-tris(3-(1H-pyrazol-1-yl)phenyl)-1,3,5-triazine
• 英文别名: 2,4,6-tris[3-(pyrazol-1-yl)phenyl]-1,3,5-triazine；2,4,6-tris(m-(1-pyrazolyl)phenyl)-1,3,5-triazine；2,4,6-tris(3-pyrazol-1-ylphenyl)-1,3,5-triazine
• CAS: 352196-01-1
• 化学式: C₃₀H₂₁N₉
• 分子量: 507.557
• InChiKey: NZWMBNNEHOHXAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  39
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  92.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3-(1H-吡唑-1-基)苯甲腈 在 哌啶 、 yttrium(III) trifluoroacetate 作用下， 反应 24.0h， 以26%的产率得到2,4,6-tris(3-(1H-pyrazol-1-yl)phenyl)-1,3,5-triazine
  参考文献：
  名称：

  Solvent-free preparation of tris-pyrazolyl-1,3,5-triazines

  摘要：

  Tris-pyrazolyl-1,3,5-triazines have been prepared by cyclotrimerization of aromatic nitriles in solvent-free conditions. The interesting structures of these compounds make them candidates for application in coordination chemistry and crystal engineering. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(01)00340-4

文献信息

• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20190058144A1

  公开（公告）日：2019-02-21

  An organic light-emitting device including a first electrode, a second electrode facing the first electrode, and an organic layer disposed between the first electrode and the second electrode, wherein the organic layer includes an emission layer, wherein the emission layer includes an electron transport host, a hole transport host, and a dopant, wherein the dopant includes an organometallic compound, and wherein the organometallic compound does not comprise iridium, wherein the organic light-emitting device satisfies predetermined parameters described in the specification.

  一种有机发光器件，包括第一电极、面向第一电极的第二电极，以及设置在第一电极和第二电极之间的有机层，其中有机层包括发射层，发射层包括电子传输主体、空穴传输主体和掺杂剂，掺杂剂包括有机金属化合物，且该有机金属化合物不包括铱，其中有机发光器件满足规范中描述的预定参数。
• ORGANIC LIGHT-EMITTING DEVICE AND METHOD OF MANUFACTURING THE SAME
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20190165292A1

  公开（公告）日：2019-05-30

  An organic light-emitting device including a first electrode, a second electrode, an emission layer disposed between the first electrode and the second electrode, a hole transport region disposed between the first electrode and the emission layer, and an electron transport region disposed between the emission layer and the second electrode, wherein the emission layer includes a host and a dopant, wherein the dopant is an iridium-free organometallic compound, and wherein a dopant concentration profile of the emission layer satisfies predetermined parameters disclosed in the specification.

  一种有机发光器件，包括第一电极、第二电极、设置在第一电极和第二电极之间的发射层、设置在第一电极和发射层之间的空穴传输区域，以及设置在发射层和第二电极之间的电子传输区域，其中发射层包括主体和掺杂剂，其中掺杂剂为无铱有机金属化合物，且发射层的掺杂剂浓度分布满足规定的参数。
• CONDENSED CYCLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME, AND DISPLAY APPARATUS INCLUDING THE ORGANIC LIGHT-EMITTING DEVICE
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20200190113A1

  公开（公告）日：2020-06-18

  A condensed cyclic compound is represented by Formula 1. An organic light-emitting device includes: a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode and comprising an emission layer, the organic layer including the condensed cyclic compound represented by Formula 1. A display apparatus includes: a thin-film transistor comprising a source electrode, a drain electrode, and an active layer; and the organic light-emitting device.

  一种紧缩环化合物由化学式1表示。一种有机发光器件包括：第一电极；第二电极；以及位于第一电极和第二电极之间的有机层，包括一个发射层，该有机层包括由化学式1表示的紧缩环化合物。一种显示装置包括：包括源电极、漏极和有源层的薄膜晶体管；以及该有机发光器件。
• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE ORGANOMETALLIC COMPOUND, AND APPARATUS INCLUDING THE ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20200283463A1

  公开（公告）日：2020-09-10

  Provided are an organometallic compound, an organic light-emitting device including the organometallic compound, and an apparatus including the organic light-emitting device. The organometallic compound may be represented by the formula M 11 M 12 (L 11 ) n11 (L 12 ) n12 , wherein M 11 and M 12 are each independently selected from a Period 1 transition metal, a Period 2 transition metal, and a Period 3 transition metal; L 11 is a ligand represented by Formula 1-1 shown below, L 12 is selected from a monodentate ligand and a bidentate ligand, n11 is 1, and n12 is selected from 0, 1, 2, 3, and 4.

  提供了一种有机金属化合物、包括该有机金属化合物的有机发光器件以及包括该有机发光器件的装置。该有机金属化合物可以由公式M11M12(L11)n11(L12)n12表示，其中M11和M12各自独立地选自第1周期过渡金属、第2周期过渡金属和第3周期过渡金属；L11是由下式1-1表示的配体，L12选自单齿配体和双齿配体，n11为1，n12选自0、1、2、3和4。
• Peripheral modification of 1,3,5-triazine based electron-transporting host materials for sky blue, green, yellow, red, and white electrophosphorescent devices
  作者：Hsiao-Fan Chen、Ting-Chih Wang、Shih-Wei Lin、Wen-Yi Hung、Hung-Chi Dai、Hao-Chih Chiu、Ken-Tsung Wong、Meng-Huan Ho、Ting-Yi Cho、Chieh-Wei Chen、Chung-Chun Lee

  DOI：10.1039/c2jm31904g

  日期：——

  A systematic comparison of the physical properties and the dual-role (host and electron transport) applications of star-shaped 1,3,5-triazine-based ET-type hosts (T2T, 3N-T2T, 3P-T2T, and oCF3-T2T) with differential peripheral groups was reported. The introduction of N-heterocyclic polar peripheries onto a 1,3,5-triazine core gave evident benefits to the electron injection/transport properties, rendering efficient PhOLEDs with a simpler device configuration feasible. Among these hosts, 3P-T2T can serve both as a promising host and electron-transport material for various Ir-based electrophosphorescence devices. These PhOLEDs configured with the same device structure exhibited low operation voltages with a maximum ηext of 8%, 15.7%, 16.9%, 16.4% and 10.8% for sky blue (FIrpic), green [(PPy)2Ir(acac)], yellow [(Bt)2Ir(acac)], red [(Mpq)2Ir(acac)] and white [FIrpic + 0.5 wt%(Mpq)2Ir(acac)], respectively.

  报告对具有不同外围基团的星形 1,3,5-三嗪基 ET 型宿主（T2T、3N-T2T、3P-T2T 和 oCF3-T2T）的物理性质和双重作用（宿主和电子传输）应用进行了系统比较。在 1,3,5-三嗪核心上引入 N-杂环极性外围基团对电子注入/传输特性有明显的好处，从而使具有更简单器件配置的高效 PhOLED 成为可能。在这些宿主中，3P-T2T 既是一种有前途的宿主材料，也是各种基于 Ir 的电致磷光器件的电子传输材料。这些具有相同器件结构的 PhOLED 显示出较低的工作电压，天蓝色（FIrpic）、绿色[(PPy)2Ir(acac)]、黄色[(Bt)2Ir(acac)]、红色[(Mpq)2Ir(acac)]和白色[FIrpic + 0.5 wt%(Mpq)2Ir(acac)]的最大 ηext 分别为 8%、15.7%、16.9%、16.4% 和 10.8%。