奶油酯 | 74758-93-3

• 物质功能分类: 香精与香料 - 合成香料 - 硫醚类香料
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 奶油酯
• 中文别名: 丁酸甲硫基甲醇酯；丁酸二甲硫醚酯；丁酸亚甲基甲硫酯；丁酸甲硫基甲酯；甲硫基甲醇丁酸酯
• 英文名称: Methylthiomethyl butyrate
• 英文别名: methylsulfanylmethyl butanoate
• CAS: 74758-93-3
• 化学式: C₆H₁₂O₂S
• mdl: MFCD06409994
• 分子量: 148.23
• InChiKey: PGAUNUCMBMQPFT-UHFFFAOYSA-N

物化性质

• 沸点：
  182.3±23.0 °C(Predicted)
• 密度：
  1.022±0.06 g/cm3(Predicted)
• LogP：
  1.89
• 物理描述：
  colourless to pale yellow liquid with metallic fruity odour
• 溶解度：
  very slightly soluble in water; soluble in alcohols and oils
• 折光率：
  1.454-1.464

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.833
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  3

制备方法与用途

毒性：GRAS（FEMA）。

使用限量：FEMA(mg/kg)：焙烤制品、肉制品、汤品，1～10；调味汁1～2；加工蔬菜0.5～5.0；调味香料500。

反应信息

• 作为产物：
  描述：

  丁酸 、 氯甲基甲硫醚 、 三乙胺 生成 奶油酯
  参考文献：
  名称：

  Methylthiomethyl esters as flavor additives

  摘要：

  脂肪酸的甲硫基甲酯被发现在食品中赋予或增强风味方面非常有用。它们在水果和浆果风味方面特别有用。

  公开号：

  US04332829A1

文献信息

• BITTER TASTE MODIFIERS INCLUDING SUBSTITUTED 1-BENZYL-3-(1-(ISOXAZOL-4-YLMETHYL)-1H-PYRAZOL-4-YL)IMIDAZOLIDINE-2,4-DIONES AND COMPOSITIONS THEREOF
  申请人：SENOMYX, INC.

  公开号：US20160376263A1

  公开（公告）日：2016-12-29

  The present invention includes compounds and compositions known to modify the perception of bitter taste, and combinations of said compositions and compounds with additional compositions, compounds, and products. Exemplary compositions comprise one or more of the following: cooling agents; inactive drug ingredients; active pharmaceutical ingredients; food additives or foodstuffs; flavorants, or flavor enhancers; food or beverage products; bitter compounds; sweeteners; bitterants; sour flavorants; salty flavorants; umami flavorants; plant or animal products; compounds known to be used in pet care products; compounds known to be used in personal care products; compounds known to be used in home products; pharmaceutical preparations; topical preparations; cannabis-derived or cannabis-related products; compounds known to be used in oral care products; beverages; scents, perfumes, or odorants; compounds known to be used in consumer products; silicone compounds; abrasives; surfactants; warming agents; smoking articles; fats, oils, or emulsions; and/or probiotic bacteria or supplements.

  本发明涵盖已知用于改变苦味感知的化合物和组合物，以及所述组合物和化合物与额外的组合物、化合物和产品的组合。示例组合物包括以下一种或多种：冷却剂；无活性药物成分；活性药用成分；食品添加剂或食品；调味剂或调味增强剂；食品或饮料产品；苦味化合物；甜味剂；苦味剂；酸味调味剂；咸味调味剂；鲜味调味剂；植物或动物产品；已知用于宠物护理产品中的化合物；已知用于个人护理产品中的化合物；已知用于家用产品中的化合物；制药制剂；局部制剂；大麻衍生或与大麻相关的产品；已知用于口腔护理产品中的化合物；饮料；香味、香水或除臭剂；已知用于消费品中的化合物；硅化合物；磨料；表面活性剂；发热剂；吸烟物品；脂肪、油脂或乳化剂；和/或益生菌或补充剂。
• COMPOUNDS USEFUL AS MODULATORS OF TRPM8
  申请人：Senomyx, Inc.

  公开号：US20170096418A1

  公开（公告）日：2017-04-06

  The present disclosure relates to compounds which are useful as cooling sensation compounds.

  本公开涉及作为冷感化合物有用的化合物。
• Flavoring or flavor-enhancing compositions and foodstuffs containing methylthiomethyl ester
  申请人：Polak's Frutal Works B.V.

  公开号：EP0007673A1

  公开（公告）日：1980-02-06

  Methylthiomethyl esters of aliphatic acids have been found useful in imparting or enhancing flavors in foodstuffs. They are particularly useful with respect to fruit and berry flavors.

  人们发现脂肪族酸甲硫基酯可用于赋予或增强食品风味，尤其适用于水果和浆果风味。
• Compounds useful as modulators of TRPM8
  申请人：Senomyx, Inc.

  公开号：US10392371B2

  公开（公告）日：2019-08-27

  Provided herein are compounds which are useful as cooling sensation compounds.

  本文提供的化合物可用作冷感化合物。
• Transparent liquids, in particular fabric treatment agents, comprising perfume and microcapsules with an odor modulator compound
  申请人：Henkel AG & Co. KGaA

  公开号：US10920176B2

  公开（公告）日：2021-02-16

  A liquid, transparent composition comprising microcapsules with at least one odor modulator compound, the composition also comprising at least one perfume. Even though the composition is in capsules, the transparent liquids can be produced using intense and lasting fragrances in the substrate.

  一种液态透明组合物，由含有至少一种气味调节化合物的微胶囊组成，该组合物还包括至少一种香水。即使该组合物是胶囊状的，也可以在基质中使用浓烈持久的香料来生产透明液体。