5-Phenoxythiophen-2-amine

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-Phenoxythiophen-2-amine
• 英文别名: 5-phenoxythiophen-2-amine
• 化学式: C₁₀H₉NOS
• 分子量: 191.25
• InChiKey: AOUUXKLBTOTGNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.5
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• ELECTROLYTE SOLUTION CONTAINING MAGNESIUM IONS
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：EP3439097A1

  公开（公告）日：2019-02-06

  An object of the present invention is to provide a highly practical electrolytic solution which has a high oxidative decomposition potential, enables the dissolution and precipitation of magnesium to stably repeatedly proceed, and is easy to prepare. The present invention relates to an electrolytic solution for a magnesium battery comprising: a compound represented by the general formula (I), a Lewis acid or a compound represented by the general formula (A), and a solvent; and to the compound represented by the general formula (I). In the formula (I), two X's each independently represent a halogeno group, and R1 represents an alkyl group having 1 to 6 carbon atoms; an alkoxy group having 1 to 6 carbon atoms; a phenoxy group; a -OMgX group (X is the same as X described above); an aryl group having 6 to 18 carbon atoms which has, as a substituent, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a vinyl group, a phenyl group, a phenoxy group, a halogeno group or a -B(OMgX)2 group (X is the same as X described above) or is unsubstituted; or a monocyclic or bicyclic heterocyclic group which has, as a substituent, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a vinyl group, a phenyl group, a phenoxy group, a halogeno group, or a -B(OMgX)2 group (X is the same as X described above) or is unsubstituted. In the general formula (A), four R6's each independently represent an alkyl group having 1 to 6 carbon atoms, a perfluoroalkyl group having 1 to 6 carbon atoms, a phenyl group, or a perfluorophenyl group.

  本发明的目的是提供一种实用性很强的电解溶液，它具有很高的氧化分解电位，能使镁的溶解和沉淀稳定地反复进行，并且易于制备。本发明涉及一种用于镁电池的电解溶液，包括：通式（I）代表的化合物、路易斯酸或通式（A）代表的化合物和溶剂；以及通式（I）代表的化合物。在式 (I) 中，两个 X 各自独立地代表卤代基团，R1 代表具有 1 至 6 个碳原子的烷基；具有 1 至 6 个碳原子的烷氧基；苯氧基；-OMgX 基团（X 与上述 X 相同）；具有 6 至 18 个碳原子的芳基，其取代基为具有 1 至 6 个碳原子的烷基、具有 1 至 6 个碳原子的烷氧基、乙烯基、苯基、苯氧基、卤素基或-B(OMgX)2 基（X 与上述 X 相同），或未被取代；或单环或双环杂环基团，其取代基为具有 1 至 6 个碳原子的烷基、具有 1 至 6 个碳原子的烷氧基、乙烯基、苯基、苯氧基、卤素基团或-B(OMgX)2 基团（X 与上述 X 相同）或未被取代的基团。在通式（A）中，四个 R6 各自独立地代表具有 1 至 6 个碳原子的烷基、具有 1 至 6 个碳原子的全氟烷基、苯基或全氟苯基。