(4-叔丁基-2-羟基环己基)2-甲基丙-2-烯酸酯 | 128840-36-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: (4-叔丁基-2-羟基环己基)2-甲基丙-2-烯酸酯
• 中文别名: 4-叔-丁基-2-羟基环己基甲丙烯酰酸酯
• 英文名称: 2-Propenoic acid, 2-methyl-, 4-(1,1-dimethylethyl)-2-hydroxycyclohexyl ester
• 英文别名: (4-tert-butyl-2-hydroxycyclohexyl) 2-methylprop-2-enoate
• CAS: 128840-36-8
• 化学式: C₁₄H₂₄O₃
• 分子量: 240.34
• InChiKey: JZUCDZZFJRODNS-UHFFFAOYSA-N

物化性质

• 沸点：
  319.0±35.0 °C(Predicted)
• 密度：
  1.00±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Polymerizable siloxane-quaternary amine copolymers
  申请人：Schorzman Derek

  公开号：US20080001318A1

  公开（公告）日：2008-01-03

  The present invention relates to polymeric compositions useful in the manufacture of biocompatible medical devices. More particularly, the present invention relates to certain cationic monomers capable of polymerization to form polymeric compositions having desirable physical characteristics useful in the manufacture of ophthalmic devices. Such properties include the ability to extract the polymerized medical devices with water. This avoids the use of organic solvents as is typical in the art. The polymer compositions comprise polymerized silicon-containing monomers end-capped with polymerizable cationic hydrophilic groups.

  本发明涉及用于制造生物相容性医疗器械的聚合物组合物。更具体地说，本发明涉及某些阳离子单体，其能够聚合形成具有理想物理特性的聚合物组合物，用于制造眼科器械。这些特性包括能够用水提取聚合的医疗器械，避免了在艺术中通常使用的有机溶剂。聚合物组合物包括聚合硅含量单体，其末端带有聚合阳离子亲水基团。
• SYNTHESIS OF CATIONIC SILOXANE PREPOLYMERS
  申请人：Stanbro Jason K.

  公开号：US20080182956A1

  公开（公告）日：2008-07-31

  This application is directed toward an improved method of synthesizing cationic siloxane prepolymers as well as a specific cationic siloxane prepolymer having improved compatibility with monofunctional siloxanyl methacrylate monomers and medical devices containing the cationic siloxane prepolymer.

  这个应用程序旨在改进阳离子硅氧烷预聚物的合成方法，以及具有与单官能硅氧烷基甲基丙烯酸酯单体相容性改善的特定阳离子硅氧烷预聚物和含有阳离子硅氧烷预聚物的医疗器械。
• Cyclohexene Oxide Compound Having Cyclohexyl Group or Long-Chain Alkyl Group, and Use Thereof
  申请人：Kato Hisao

  公开号：US20080108725A1

  公开（公告）日：2008-05-08

  An object of the present invention is to provide a cyclohexene oxide compound that gives a cured resin having a low refractive index and excellent transparency, curability, mold release properties, and mechanical properties, and that can be used as a component of an actinic radiation curing composition and/or heat curing composition. The present invention is a cyclohexene oxide compound having a cyclohexyl group or a long-chain alkyl group, represented by Formula (1) below (in Formula (1), A denotes a cyclohexyl group, Formula (2) below, or an optionally branched alkyl group having 8 to 16 carbons) (in Formula (2), R 1 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons and R 2 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons).

  本发明的目的是提供一种环己烯氧化物化合物，该化合物能够产生具有低折射率和优异透明度、可固化性、模具脱模性和机械性能的固化树脂，并可用作光敏辐射固化组合物和/或热固化组合物的组分。本发明是一种具有环己基或长链烷基的环己烯氧化物化合物，由下式（1）表示（在式（1）中，A表示环己基、下式（2）或具有8至16个碳的可选支链烷基）（在式（2）中，R1表示氢原子或具有1至4个碳的可选支链烷基，R2表示氢原子或具有1至4个碳的可选支链烷基）。
• CYCLOHEXENE OXIDE COMPOUND HAVING CYCLOHEXYL GROUP OR LONG-CHAIN ALKYL GROUP AND USE THEREOF
  申请人：TOAGOSEI CO., LTD.

  公开号：EP1798251A1

  公开（公告）日：2007-06-20

  An object of the present invention is to provide a cyclohexene oxide compound that gives a cured resin having a low refractive index and excellent transparency, curability, mold release properties, and mechanical properties, and that can be used as a component of an actinic radiation curing composition and/or heat curing composition. The present invention is a cyclohexene oxide compound having a cyclohexyl group or a long-chain alkyl group, represented by Formula (1) below (in Formula (1), A denotes a cyclohexyl group, Formula (2) below, or an optionally branched alkyl group having 8 to 16 carbons) (in Formula (2), R1 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons and R2 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons).

  本发明的目的是提供一种环己烯氧化物化合物，它能使固化树脂具有低折射率和优异的透明度、固化性、脱模性能和机械性能，并可用作光辐射固化组合物和/或热固化组合物的组分。 本发明是一种具有环己基或长链烷基的环己烯氧化物化合物，如下式（1）所示 式（1）中，A 表示下式（2）中的环己基或具有 8 至 16 个碳原子的任选支链烷基）。 式（2）中，R1 表示氢原子或碳原子数为 1 至 4 的任选支链烷基，R2 表示氢原子或碳原子数为 1 至 4 的任选支链烷基）。
• Process for making cationic hydrophilic siloxanyl monomers
  申请人：BAUSCH & LOMB INCORPORATED

  公开号：EP2287169A1

  公开（公告）日：2011-02-23

  The present invention relates to polymeric compositions useful in the manufacture of biocompatible medical devices. More particularly, the present invention relates to certain cationic monomers capable of polymerization to form polymeric compositions having desirable physical characteristics useful in the manufacture of ophthalmic devices. Such properties include the ability to extract the polymerized medical devices with water. This avoids the use of organic solvents as is typical in the art. The polymeric compositions comprise polymerized cationic hydrophilic siloxanyl monomers prepared by the process disclosed herein.

  本发明涉及用于制造生物相容性医疗器械的聚合物组合物。更具体地说，本发明涉及某些阳离子单体，这些单体能够聚合形成具有理想物理特性的聚合物组合物，用于制造眼科设备。这些特性包括能够用水萃取聚合的医疗器械。这就避免了使用本领域常见的有机溶剂。聚合物组合物包括通过本文公开的工艺制备的聚合阳离子亲水硅氧烷单体。